Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes

Autores
Fernandez, Mariela Alejandra; Alba, Maria Dolores; Torres Sanchez, Rosa Maria
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Smectite is a family of clay minerals that have important applications. In the majority of these clay minerals, the hydrated interlayer cations play a crucial role on the properties of the clay. Moreover, many studies have revealed that both thermal and grinding treatments affect the MMT structure and that interlayer cations play an important role in the degradation of the structure, primarily after mechanical treatment. In this study, the effects of these treatments on MMTs homoionized with mono (Na+, Li+ or K+) or polyvalent (Ca2+ or Al3+) cations were analyzed by the combination of a set of techniques that can reveal the difference of bulk phenomena from those produced on the surface of the particles. The thermal and mechanical (in an oscillating mill) treatments affected the framework composition and structure of the MMT, and the thermal treatment caused less drastic changes that the mechanical one. The effect of the interlayer cations is primarily due to the oxidation state and, to the size of the cations, which also influenced the disappearance of aluminum in the MMT tetrahedral sheet. These treatments caused a decrease in the surface area and an increase in the particle agglomeration and the isoelectric point. Both treatments caused the leaching of the framework aluminum. Furthermore, the mechanical treatment induced structural defects, such as the breakup of the particles, which favored the dehydroxylation and the increase of the isoelectric points of the montmorillonites.
Fil: Fernandez, Mariela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina
Fil: Alba, Maria Dolores. Instituto Ciencia de los Materiales de Sevilla; España
Fil: Torres Sanchez, Rosa Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina
Materia
Montmorillonite
Homoionized Montmorillonite
Mechanical And Thermal Treatments
Rmn
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/3404
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/3404
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changesFernandez, Mariela AlejandraAlba, Maria DoloresTorres Sanchez, Rosa MariaMontmorilloniteHomoionized MontmorilloniteMechanical And Thermal TreatmentsRmnhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Smectite is a family of clay minerals that have important applications. In the majority of these clay minerals, the hydrated interlayer cations play a crucial role on the properties of the clay. Moreover, many studies have revealed that both thermal and grinding treatments affect the MMT structure and that interlayer cations play an important role in the degradation of the structure, primarily after mechanical treatment. In this study, the effects of these treatments on MMTs homoionized with mono (Na+, Li+ or K+) or polyvalent (Ca2+ or Al3+) cations were analyzed by the combination of a set of techniques that can reveal the difference of bulk phenomena from those produced on the surface of the particles. The thermal and mechanical (in an oscillating mill) treatments affected the framework composition and structure of the MMT, and the thermal treatment caused less drastic changes that the mechanical one. The effect of the interlayer cations is primarily due to the oxidation state and, to the size of the cations, which also influenced the disappearance of aluminum in the MMT tetrahedral sheet. These treatments caused a decrease in the surface area and an increase in the particle agglomeration and the isoelectric point. Both treatments caused the leaching of the framework aluminum. Furthermore, the mechanical treatment induced structural defects, such as the breakup of the particles, which favored the dehydroxylation and the increase of the isoelectric points of the montmorillonites.Fil: Fernandez, Mariela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); ArgentinaFil: Alba, Maria Dolores. Instituto Ciencia de los Materiales de Sevilla; EspañaFil: Torres Sanchez, Rosa Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); ArgentinaElsevier2013-02-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/3404Fernandez, Mariela Alejandra; Alba, Maria Dolores; Torres Sanchez, Rosa Maria; Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes; Elsevier; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 423; 4-2-2013; 1-100927-7757enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0927775713000617info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2013.01.040info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:26:56Zoai:ri.conicet.gov.ar:11336/3404instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:26:56.845CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes
title Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes
spellingShingle Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes
Fernandez, Mariela Alejandra
Montmorillonite
Homoionized Montmorillonite
Mechanical And Thermal Treatments
Rmn
title_short Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes
title_full Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes
title_fullStr Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes
title_full_unstemmed Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes
title_sort Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes
dc.creator.none.fl_str_mv Fernandez, Mariela Alejandra
Alba, Maria Dolores
Torres Sanchez, Rosa Maria
author Fernandez, Mariela Alejandra
author_facet Fernandez, Mariela Alejandra
Alba, Maria Dolores
Torres Sanchez, Rosa Maria
author_role author
author2 Alba, Maria Dolores
Torres Sanchez, Rosa Maria
author2_role author
author
dc.subject.none.fl_str_mv Montmorillonite
Homoionized Montmorillonite
Mechanical And Thermal Treatments
Rmn
topic Montmorillonite
Homoionized Montmorillonite
Mechanical And Thermal Treatments
Rmn
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Smectite is a family of clay minerals that have important applications. In the majority of these clay minerals, the hydrated interlayer cations play a crucial role on the properties of the clay. Moreover, many studies have revealed that both thermal and grinding treatments affect the MMT structure and that interlayer cations play an important role in the degradation of the structure, primarily after mechanical treatment. In this study, the effects of these treatments on MMTs homoionized with mono (Na+, Li+ or K+) or polyvalent (Ca2+ or Al3+) cations were analyzed by the combination of a set of techniques that can reveal the difference of bulk phenomena from those produced on the surface of the particles. The thermal and mechanical (in an oscillating mill) treatments affected the framework composition and structure of the MMT, and the thermal treatment caused less drastic changes that the mechanical one. The effect of the interlayer cations is primarily due to the oxidation state and, to the size of the cations, which also influenced the disappearance of aluminum in the MMT tetrahedral sheet. These treatments caused a decrease in the surface area and an increase in the particle agglomeration and the isoelectric point. Both treatments caused the leaching of the framework aluminum. Furthermore, the mechanical treatment induced structural defects, such as the breakup of the particles, which favored the dehydroxylation and the increase of the isoelectric points of the montmorillonites.
Fil: Fernandez, Mariela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina
Fil: Alba, Maria Dolores. Instituto Ciencia de los Materiales de Sevilla; España
Fil: Torres Sanchez, Rosa Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina
description Smectite is a family of clay minerals that have important applications. In the majority of these clay minerals, the hydrated interlayer cations play a crucial role on the properties of the clay. Moreover, many studies have revealed that both thermal and grinding treatments affect the MMT structure and that interlayer cations play an important role in the degradation of the structure, primarily after mechanical treatment. In this study, the effects of these treatments on MMTs homoionized with mono (Na+, Li+ or K+) or polyvalent (Ca2+ or Al3+) cations were analyzed by the combination of a set of techniques that can reveal the difference of bulk phenomena from those produced on the surface of the particles. The thermal and mechanical (in an oscillating mill) treatments affected the framework composition and structure of the MMT, and the thermal treatment caused less drastic changes that the mechanical one. The effect of the interlayer cations is primarily due to the oxidation state and, to the size of the cations, which also influenced the disappearance of aluminum in the MMT tetrahedral sheet. These treatments caused a decrease in the surface area and an increase in the particle agglomeration and the isoelectric point. Both treatments caused the leaching of the framework aluminum. Furthermore, the mechanical treatment induced structural defects, such as the breakup of the particles, which favored the dehydroxylation and the increase of the isoelectric points of the montmorillonites.
publishDate 2013
dc.date.none.fl_str_mv 2013-02-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/3404
Fernandez, Mariela Alejandra; Alba, Maria Dolores; Torres Sanchez, Rosa Maria; Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes; Elsevier; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 423; 4-2-2013; 1-10
0927-7757
url http://hdl.handle.net/11336/3404
identifier_str_mv Fernandez, Mariela Alejandra; Alba, Maria Dolores; Torres Sanchez, Rosa Maria; Effects of thermal and mechanical treatments on montmorillonite homoionized with mono- and polyvalent cations: Insight into the surface and structural changes; Elsevier; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 423; 4-2-2013; 1-10
0927-7757
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0927775713000617
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2013.01.040
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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