ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge

Autores
Bianchi, Ana Elisa; Fernandez, Mariela Alejandra; Pantanetti, Mariano; Viña, Raul Oscar; Torriani, I.; Torres Sanchez, Rosa Maria; Punte, Graciela Maria
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work we investigate the microstructure and properties of organo-montmorillonites (OMts) synthesized by intercalation of a Patagonian Mt with different surfactant/CEC ratios (0.5, 1 and 2) of octadecyl trimethylammonium (ODTMA+) and hexadecyl trimethylammonium (HDTMA+) cations. X-ray diffraction (XRD) patterns showed that
in all OMt samples d001 value increases with respect to raw Mt (1.258 nm). Small angle andwide angle X-ray scattering (SAXS andWAXS) curves, particle apparent diameters (determined by laser), zeta potential values and scanning electron microscopy (SEM) images, showed the presence of assorted d001 values (which depend on storage conditions), aggregate formation and charge reversal (which varied with loading and cation length) for samples obtained with 1 and 2 CEC. However, for samples intercalatedwith 0.5 CEC, we found evidence of smaller aggregate formation, no charge reversal, and similar d001 and zeta potential values (both higher than those of Mt). Findings reported here will help attain better conditions to functionalize highly charged Mt making them suitable to be used as nanocomposite precursors for different applications.

Fil: Bianchi, Ana Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Física la Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Fil: Fernandez, Mariela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Fil: Pantanetti, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina
Fil: Viña, Raul Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Física la Plata; Argentina
Fil: Torriani, I.. Universidade Estadual de Campinas. Departamento de Física da Matéria Condensada; Brasil
Fil: Torres Sanchez, Rosa Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina
Fil: Punte, Graciela Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Física la Plata; Argentina
Materia
Montmorillonite
Organo-Montmorillonite
Saxs
Zeta Potential
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5287
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/5287
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface chargeBianchi, Ana ElisaFernandez, Mariela AlejandraPantanetti, MarianoViña, Raul OscarTorriani, I.Torres Sanchez, Rosa MariaPunte, Graciela MariaMontmorilloniteOrgano-MontmorilloniteSaxsZeta Potentialhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1In this work we investigate the microstructure and properties of organo-montmorillonites (OMts) synthesized by intercalation of a Patagonian Mt with different surfactant/CEC ratios (0.5, 1 and 2) of octadecyl trimethylammonium (ODTMA+) and hexadecyl trimethylammonium (HDTMA+) cations. X-ray diffraction (XRD) patterns showed that<br />in all OMt samples d001 value increases with respect to raw Mt (1.258 nm). Small angle andwide angle X-ray scattering (SAXS andWAXS) curves, particle apparent diameters (determined by laser), zeta potential values and scanning electron microscopy (SEM) images, showed the presence of assorted d001 values (which depend on storage conditions), aggregate formation and charge reversal (which varied with loading and cation length) for samples obtained with 1 and 2 CEC. However, for samples intercalatedwith 0.5 CEC, we found evidence of smaller aggregate formation, no charge reversal, and similar d001 and zeta potential values (both higher than those of Mt). Findings reported here will help attain better conditions to functionalize highly charged Mt making them suitable to be used as nanocomposite precursors for different applications.<br />Fil: Bianchi, Ana Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Física la Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; ArgentinaFil: Fernandez, Mariela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; ArgentinaFil: Pantanetti, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); ArgentinaFil: Viña, Raul Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Física la Plata; ArgentinaFil: Torriani, I.. Universidade Estadual de Campinas. Departamento de Física da Matéria Condensada; BrasilFil: Torres Sanchez, Rosa Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); ArgentinaFil: Punte, Graciela Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Física la Plata; ArgentinaElsevier2013-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5287Bianchi, Ana Elisa; Fernandez, Mariela Alejandra; Pantanetti, Mariano; Viña, Raul Oscar; Torriani, I.; et al.; ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge; Elsevier; Applied Clay Science; 83-84; 9-2013; 280–2850169-1317enginfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0169131713002779?np=yinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.clay.2013.08.032info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:25:31Zoai:ri.conicet.gov.ar:11336/5287instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:25:32.225CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge
title ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge
spellingShingle ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge
Bianchi, Ana Elisa
Montmorillonite
Organo-Montmorillonite
Saxs
Zeta Potential
title_short ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge
title_full ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge
title_fullStr ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge
title_full_unstemmed ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge
title_sort ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge
dc.creator.none.fl_str_mv Bianchi, Ana Elisa
Fernandez, Mariela Alejandra
Pantanetti, Mariano
Viña, Raul Oscar
Torriani, I.
Torres Sanchez, Rosa Maria
Punte, Graciela Maria
author Bianchi, Ana Elisa
author_facet Bianchi, Ana Elisa
Fernandez, Mariela Alejandra
Pantanetti, Mariano
Viña, Raul Oscar
Torriani, I.
Torres Sanchez, Rosa Maria
Punte, Graciela Maria
author_role author
author2 Fernandez, Mariela Alejandra
Pantanetti, Mariano
Viña, Raul Oscar
Torriani, I.
Torres Sanchez, Rosa Maria
Punte, Graciela Maria
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Montmorillonite
Organo-Montmorillonite
Saxs
Zeta Potential
topic Montmorillonite
Organo-Montmorillonite
Saxs
Zeta Potential
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work we investigate the microstructure and properties of organo-montmorillonites (OMts) synthesized by intercalation of a Patagonian Mt with different surfactant/CEC ratios (0.5, 1 and 2) of octadecyl trimethylammonium (ODTMA+) and hexadecyl trimethylammonium (HDTMA+) cations. X-ray diffraction (XRD) patterns showed that<br />in all OMt samples d001 value increases with respect to raw Mt (1.258 nm). Small angle andwide angle X-ray scattering (SAXS andWAXS) curves, particle apparent diameters (determined by laser), zeta potential values and scanning electron microscopy (SEM) images, showed the presence of assorted d001 values (which depend on storage conditions), aggregate formation and charge reversal (which varied with loading and cation length) for samples obtained with 1 and 2 CEC. However, for samples intercalatedwith 0.5 CEC, we found evidence of smaller aggregate formation, no charge reversal, and similar d001 and zeta potential values (both higher than those of Mt). Findings reported here will help attain better conditions to functionalize highly charged Mt making them suitable to be used as nanocomposite precursors for different applications.<br />
Fil: Bianchi, Ana Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Física la Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Fil: Fernandez, Mariela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Fil: Pantanetti, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina
Fil: Viña, Raul Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Física la Plata; Argentina
Fil: Torriani, I.. Universidade Estadual de Campinas. Departamento de Física da Matéria Condensada; Brasil
Fil: Torres Sanchez, Rosa Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro Tecnológico de Recursos Minerales y Cerámica (i); Argentina
Fil: Punte, Graciela Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Física la Plata; Argentina
description In this work we investigate the microstructure and properties of organo-montmorillonites (OMts) synthesized by intercalation of a Patagonian Mt with different surfactant/CEC ratios (0.5, 1 and 2) of octadecyl trimethylammonium (ODTMA+) and hexadecyl trimethylammonium (HDTMA+) cations. X-ray diffraction (XRD) patterns showed that<br />in all OMt samples d001 value increases with respect to raw Mt (1.258 nm). Small angle andwide angle X-ray scattering (SAXS andWAXS) curves, particle apparent diameters (determined by laser), zeta potential values and scanning electron microscopy (SEM) images, showed the presence of assorted d001 values (which depend on storage conditions), aggregate formation and charge reversal (which varied with loading and cation length) for samples obtained with 1 and 2 CEC. However, for samples intercalatedwith 0.5 CEC, we found evidence of smaller aggregate formation, no charge reversal, and similar d001 and zeta potential values (both higher than those of Mt). Findings reported here will help attain better conditions to functionalize highly charged Mt making them suitable to be used as nanocomposite precursors for different applications.<br />
publishDate 2013
dc.date.none.fl_str_mv 2013-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5287
Bianchi, Ana Elisa; Fernandez, Mariela Alejandra; Pantanetti, Mariano; Viña, Raul Oscar; Torriani, I.; et al.; ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge; Elsevier; Applied Clay Science; 83-84; 9-2013; 280–285
0169-1317
url http://hdl.handle.net/11336/5287
identifier_str_mv Bianchi, Ana Elisa; Fernandez, Mariela Alejandra; Pantanetti, Mariano; Viña, Raul Oscar; Torriani, I.; et al.; ODTMA+ and HDTMA+ organo-montmorillonites characterization: New insight byWAXS, SAXS and surface charge; Elsevier; Applied Clay Science; 83-84; 9-2013; 280–285
0169-1317
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0169131713002779?np=y
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.clay.2013.08.032
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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