Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices

Autores
Bengoa, Leandro Nicolás; González Gil, R. M.; Gómez-romero, Pedro
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
As the interest in alternative Li-based energy storage technologies increased during the last years, zinc emerged as a promising candidate. Despite several advantages over Li, Zn cycling stability is still a major issue. In this article, the use of near-neutral electrolytes (non-expensive 2 M ZnSO4) with the addition of different additives (dimethylsulfoxide and tetratethylammonium chloride) is proposed as a solution. The Zn deposition/dissolution electrochemistry has been evaluated and the cycling stability was determined in Zn//Zn symmetric coin-cells. Hybrid supercapacitors were also assembled and tested in a range of 0.2 V–1.8 V for 2000 cycles, using activated carbon electrodes as cathode and Zn foil as anode. The results show that dimethylsulfoxide strongly inhibits the Zn deposition process, evidenced by a decrease in the cathodic current density, as well as in the dissolution peak. DMSO affects the deposition mechanism, whereas tetratethylammonium chloride reduces the exchange current density, consistent with the adsorption of tetraethylammonium ions on the Zn surface. A synergy between both additives leading to further inhibition of Zn2+ reduction is observed allowing cycling up to 250 hours for Zn//Zn devices. In addition, the performance of hybrid supercapacitors has also improved showing better capacity and extended cycle life.
Fil: Bengoa, Leandro Nicolás. Institut Catalá de Nanociencia I Nanotecnología; España. Barcelona Institute Of Science And Technology.; España. Universitat Autònoma de Barcelona; España. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: González Gil, R. M.. Institut Catalá de Nanociencia I Nanotecnología; España. Barcelona Institute Of Science And Technology.; España. Universitat Autònoma de Barcelona; España
Fil: Gómez-romero, Pedro. Institut Catalá de Nanociencia I Nanotecnología; España. Consejo Superior de Investigaciones Científicas; España. Barcelona Institute Of Science And Technology.; España. Universitat Autònoma de Barcelona; España
Materia
ZINC
ELECTROCHEMISTRY
ANODE
BATTERY
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/261591
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/261591
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage DevicesBengoa, Leandro NicolásGonzález Gil, R. M.Gómez-romero, PedroZINCELECTROCHEMISTRYANODEBATTERYhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1As the interest in alternative Li-based energy storage technologies increased during the last years, zinc emerged as a promising candidate. Despite several advantages over Li, Zn cycling stability is still a major issue. In this article, the use of near-neutral electrolytes (non-expensive 2 M ZnSO4) with the addition of different additives (dimethylsulfoxide and tetratethylammonium chloride) is proposed as a solution. The Zn deposition/dissolution electrochemistry has been evaluated and the cycling stability was determined in Zn//Zn symmetric coin-cells. Hybrid supercapacitors were also assembled and tested in a range of 0.2 V–1.8 V for 2000 cycles, using activated carbon electrodes as cathode and Zn foil as anode. The results show that dimethylsulfoxide strongly inhibits the Zn deposition process, evidenced by a decrease in the cathodic current density, as well as in the dissolution peak. DMSO affects the deposition mechanism, whereas tetratethylammonium chloride reduces the exchange current density, consistent with the adsorption of tetraethylammonium ions on the Zn surface. A synergy between both additives leading to further inhibition of Zn2+ reduction is observed allowing cycling up to 250 hours for Zn//Zn devices. In addition, the performance of hybrid supercapacitors has also improved showing better capacity and extended cycle life.Fil: Bengoa, Leandro Nicolás. Institut Catalá de Nanociencia I Nanotecnología; España. Barcelona Institute Of Science And Technology.; España. Universitat Autònoma de Barcelona; España. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: González Gil, R. M.. Institut Catalá de Nanociencia I Nanotecnología; España. Barcelona Institute Of Science And Technology.; España. Universitat Autònoma de Barcelona; EspañaFil: Gómez-romero, Pedro. Institut Catalá de Nanociencia I Nanotecnología; España. Consejo Superior de Investigaciones Científicas; España. Barcelona Institute Of Science And Technology.; España. Universitat Autònoma de Barcelona; EspañaWiley2024-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/261591Bengoa, Leandro Nicolás; González Gil, R. M.; Gómez-romero, Pedro; Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices; Wiley; ChemElectroChem; 11; 6; 2-2024; 1-92196-0216CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/celc.202300517info:eu-repo/semantics/altIdentifier/doi/10.1002/celc.202300517info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:42:42Zoai:ri.conicet.gov.ar:11336/261591instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:42:43.213CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices
title Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices
spellingShingle Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices
Bengoa, Leandro Nicolás
ZINC
ELECTROCHEMISTRY
ANODE
BATTERY
title_short Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices
title_full Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices
title_fullStr Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices
title_full_unstemmed Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices
title_sort Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices
dc.creator.none.fl_str_mv Bengoa, Leandro Nicolás
González Gil, R. M.
Gómez-romero, Pedro
author Bengoa, Leandro Nicolás
author_facet Bengoa, Leandro Nicolás
González Gil, R. M.
Gómez-romero, Pedro
author_role author
author2 González Gil, R. M.
Gómez-romero, Pedro
author2_role author
author
dc.subject.none.fl_str_mv ZINC
ELECTROCHEMISTRY
ANODE
BATTERY
topic ZINC
ELECTROCHEMISTRY
ANODE
BATTERY
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv As the interest in alternative Li-based energy storage technologies increased during the last years, zinc emerged as a promising candidate. Despite several advantages over Li, Zn cycling stability is still a major issue. In this article, the use of near-neutral electrolytes (non-expensive 2 M ZnSO4) with the addition of different additives (dimethylsulfoxide and tetratethylammonium chloride) is proposed as a solution. The Zn deposition/dissolution electrochemistry has been evaluated and the cycling stability was determined in Zn//Zn symmetric coin-cells. Hybrid supercapacitors were also assembled and tested in a range of 0.2 V–1.8 V for 2000 cycles, using activated carbon electrodes as cathode and Zn foil as anode. The results show that dimethylsulfoxide strongly inhibits the Zn deposition process, evidenced by a decrease in the cathodic current density, as well as in the dissolution peak. DMSO affects the deposition mechanism, whereas tetratethylammonium chloride reduces the exchange current density, consistent with the adsorption of tetraethylammonium ions on the Zn surface. A synergy between both additives leading to further inhibition of Zn2+ reduction is observed allowing cycling up to 250 hours for Zn//Zn devices. In addition, the performance of hybrid supercapacitors has also improved showing better capacity and extended cycle life.
Fil: Bengoa, Leandro Nicolás. Institut Catalá de Nanociencia I Nanotecnología; España. Barcelona Institute Of Science And Technology.; España. Universitat Autònoma de Barcelona; España. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: González Gil, R. M.. Institut Catalá de Nanociencia I Nanotecnología; España. Barcelona Institute Of Science And Technology.; España. Universitat Autònoma de Barcelona; España
Fil: Gómez-romero, Pedro. Institut Catalá de Nanociencia I Nanotecnología; España. Consejo Superior de Investigaciones Científicas; España. Barcelona Institute Of Science And Technology.; España. Universitat Autònoma de Barcelona; España
description As the interest in alternative Li-based energy storage technologies increased during the last years, zinc emerged as a promising candidate. Despite several advantages over Li, Zn cycling stability is still a major issue. In this article, the use of near-neutral electrolytes (non-expensive 2 M ZnSO4) with the addition of different additives (dimethylsulfoxide and tetratethylammonium chloride) is proposed as a solution. The Zn deposition/dissolution electrochemistry has been evaluated and the cycling stability was determined in Zn//Zn symmetric coin-cells. Hybrid supercapacitors were also assembled and tested in a range of 0.2 V–1.8 V for 2000 cycles, using activated carbon electrodes as cathode and Zn foil as anode. The results show that dimethylsulfoxide strongly inhibits the Zn deposition process, evidenced by a decrease in the cathodic current density, as well as in the dissolution peak. DMSO affects the deposition mechanism, whereas tetratethylammonium chloride reduces the exchange current density, consistent with the adsorption of tetraethylammonium ions on the Zn surface. A synergy between both additives leading to further inhibition of Zn2+ reduction is observed allowing cycling up to 250 hours for Zn//Zn devices. In addition, the performance of hybrid supercapacitors has also improved showing better capacity and extended cycle life.
publishDate 2024
dc.date.none.fl_str_mv 2024-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/261591
Bengoa, Leandro Nicolás; González Gil, R. M.; Gómez-romero, Pedro; Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices; Wiley; ChemElectroChem; 11; 6; 2-2024; 1-9
2196-0216
CONICET Digital
CONICET
url http://hdl.handle.net/11336/261591
identifier_str_mv Bengoa, Leandro Nicolás; González Gil, R. M.; Gómez-romero, Pedro; Understanding the Role of Additives on The Electrochemistry and Performance of Zn Energy Storage Devices; Wiley; ChemElectroChem; 11; 6; 2-2024; 1-9
2196-0216
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/celc.202300517
info:eu-repo/semantics/altIdentifier/doi/10.1002/celc.202300517
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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