A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes

Autores
Raviolo, Sofia; Bracamonte, Maria Victoria; Calderon, Cecilia Andrea; Cometto, Fernando Pablo; Luque, Guillermina Leticia
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The demand for more efficient energy storage devices has become increasingly important in order to face the ongoing energy transition. In this regard, it is equally important to attain the production of these devices with the lowest possible environmental impact. In light of this, the use of waste materials and low-polluting methods has become a strategic priority. In this study, brewers’ spent grains were utilized as raw material to produce anodic electrodes for lithium-ion batteries (LIBs). The synthesis process involves only two pyrolysis steps at low temperatures without any chemical treatment, reducing energy investment and waste generation. The result is a porous biocarbon structure—with mixed graphitic and amorphous characteristics—decorated with silica nanoparticles. The presence of silica greatly enhances storage capacity. The obtained biocarbon based electrodes exhibites a capacity of 455 mAh g−1 after 100 cycles, surpassing the standard anode material commonly used in commercial LIBs.
Fil: Raviolo, Sofia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Bracamonte, Maria Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Teórica y Computacional; Argentina
Fil: Calderon, Cecilia Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Cometto, Fernando Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Luque, Guillermina Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
ANODE
BIOCARBON
BREWING SPENT GRAINS
LITHIUM-ION BATTERY
SILICA
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/219003
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodesRaviolo, SofiaBracamonte, Maria VictoriaCalderon, Cecilia AndreaCometto, Fernando PabloLuque, Guillermina LeticiaANODEBIOCARBONBREWING SPENT GRAINSLITHIUM-ION BATTERYSILICAhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The demand for more efficient energy storage devices has become increasingly important in order to face the ongoing energy transition. In this regard, it is equally important to attain the production of these devices with the lowest possible environmental impact. In light of this, the use of waste materials and low-polluting methods has become a strategic priority. In this study, brewers’ spent grains were utilized as raw material to produce anodic electrodes for lithium-ion batteries (LIBs). The synthesis process involves only two pyrolysis steps at low temperatures without any chemical treatment, reducing energy investment and waste generation. The result is a porous biocarbon structure—with mixed graphitic and amorphous characteristics—decorated with silica nanoparticles. The presence of silica greatly enhances storage capacity. The obtained biocarbon based electrodes exhibites a capacity of 455 mAh g−1 after 100 cycles, surpassing the standard anode material commonly used in commercial LIBs.Fil: Raviolo, Sofia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Bracamonte, Maria Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Teórica y Computacional; ArgentinaFil: Calderon, Cecilia Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Cometto, Fernando Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Luque, Guillermina Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaJohn Wiley and Sons Inc2023-06-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/219003Raviolo, Sofia; Bracamonte, Maria Victoria; Calderon, Cecilia Andrea; Cometto, Fernando Pablo; Luque, Guillermina Leticia; A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes; John Wiley and Sons Inc; Energy Technology; 11; 9; 08-6-2023; 1-212194-42882194-4296CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/ente.202300342info:eu-repo/semantics/altIdentifier/doi/10.1002/ente.202300342info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:35:35Zoai:ri.conicet.gov.ar:11336/219003instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:35:35.734CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes
title A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes
spellingShingle A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes
Raviolo, Sofia
ANODE
BIOCARBON
BREWING SPENT GRAINS
LITHIUM-ION BATTERY
SILICA
title_short A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes
title_full A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes
title_fullStr A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes
title_full_unstemmed A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes
title_sort A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes
dc.creator.none.fl_str_mv Raviolo, Sofia
Bracamonte, Maria Victoria
Calderon, Cecilia Andrea
Cometto, Fernando Pablo
Luque, Guillermina Leticia
author Raviolo, Sofia
author_facet Raviolo, Sofia
Bracamonte, Maria Victoria
Calderon, Cecilia Andrea
Cometto, Fernando Pablo
Luque, Guillermina Leticia
author_role author
author2 Bracamonte, Maria Victoria
Calderon, Cecilia Andrea
Cometto, Fernando Pablo
Luque, Guillermina Leticia
author2_role author
author
author
author
dc.subject.none.fl_str_mv ANODE
BIOCARBON
BREWING SPENT GRAINS
LITHIUM-ION BATTERY
SILICA
topic ANODE
BIOCARBON
BREWING SPENT GRAINS
LITHIUM-ION BATTERY
SILICA
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The demand for more efficient energy storage devices has become increasingly important in order to face the ongoing energy transition. In this regard, it is equally important to attain the production of these devices with the lowest possible environmental impact. In light of this, the use of waste materials and low-polluting methods has become a strategic priority. In this study, brewers’ spent grains were utilized as raw material to produce anodic electrodes for lithium-ion batteries (LIBs). The synthesis process involves only two pyrolysis steps at low temperatures without any chemical treatment, reducing energy investment and waste generation. The result is a porous biocarbon structure—with mixed graphitic and amorphous characteristics—decorated with silica nanoparticles. The presence of silica greatly enhances storage capacity. The obtained biocarbon based electrodes exhibites a capacity of 455 mAh g−1 after 100 cycles, surpassing the standard anode material commonly used in commercial LIBs.
Fil: Raviolo, Sofia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Bracamonte, Maria Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Teórica y Computacional; Argentina
Fil: Calderon, Cecilia Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Cometto, Fernando Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Luque, Guillermina Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description The demand for more efficient energy storage devices has become increasingly important in order to face the ongoing energy transition. In this regard, it is equally important to attain the production of these devices with the lowest possible environmental impact. In light of this, the use of waste materials and low-polluting methods has become a strategic priority. In this study, brewers’ spent grains were utilized as raw material to produce anodic electrodes for lithium-ion batteries (LIBs). The synthesis process involves only two pyrolysis steps at low temperatures without any chemical treatment, reducing energy investment and waste generation. The result is a porous biocarbon structure—with mixed graphitic and amorphous characteristics—decorated with silica nanoparticles. The presence of silica greatly enhances storage capacity. The obtained biocarbon based electrodes exhibites a capacity of 455 mAh g−1 after 100 cycles, surpassing the standard anode material commonly used in commercial LIBs.
publishDate 2023
dc.date.none.fl_str_mv 2023-06-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/219003
Raviolo, Sofia; Bracamonte, Maria Victoria; Calderon, Cecilia Andrea; Cometto, Fernando Pablo; Luque, Guillermina Leticia; A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes; John Wiley and Sons Inc; Energy Technology; 11; 9; 08-6-2023; 1-21
2194-4288
2194-4296
CONICET Digital
CONICET
url http://hdl.handle.net/11336/219003
identifier_str_mv Raviolo, Sofia; Bracamonte, Maria Victoria; Calderon, Cecilia Andrea; Cometto, Fernando Pablo; Luque, Guillermina Leticia; A green solution to energy storage: Brewers’ Spent Grains Biocarbon–Silica Composites as High-Performance Lithium-Ion batteries anodes; John Wiley and Sons Inc; Energy Technology; 11; 9; 08-6-2023; 1-21
2194-4288
2194-4296
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/ente.202300342
info:eu-repo/semantics/altIdentifier/doi/10.1002/ente.202300342
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley and Sons Inc
publisher.none.fl_str_mv John Wiley and Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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