Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics
- Autores
- Dominguez Alfaro, Antonio; Mitoudi Vagourdi, Eleni; Dimov, Ivan; Picchio, Matías Luis; Lopez Larrea, Naroa; Lopez de Lacalle, Jon; Tao, Xudong; Ruiz Mateos Serrano, Ruben; Gallastegui, Antonela; Vassardanis, Nikolaos; Mecerreyes, David; Malliaras, George G.
- Año de publicación
- 2024
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this work, a new method of multi-material printing in one-go using a commercially available 3D printer is presented. The approach is simple and versatile, allowing the manufacturing of multi-material layered or multi-material printing in the same layer. To the best of the knowledge, it is the first time that 3D printed Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) micro-patterns combining different materials are reported, overcoming mechanical stability issues. Moreover, the conducting ink is engineered to obtain stable in-time materials while retaining sub-100 µm resolution. Micro-structured bio-shaped protuberances are designed and 3D printed as electrodes for electrophysiology. Moreover, these microstructures are combined with polymerizable deep eutectic solvents (polyDES) as functional additives, gaining adhesion and ionic conductivity. As a result of the novel electrodes, low skin impedance values showed suitable performance for electromyography recording on the forearm. Finally, this concluded that the use of polyDES conferred stability over time, allowing the usability of the electrode 90 days after fabrication without losing its performance. All in all, this demonstrated a very easy-to-make procedure that allows printing PEDOT:PSS on soft, hard, and/or flexible functional substrates, opening up a new paradigm in the manufacturing of conducting multi-functional materials for the field of bioelectronics and wearables.
Fil: Dominguez Alfaro, Antonio. Universidad del País Vasco; España
Fil: Mitoudi Vagourdi, Eleni. University of Cambridge; Estados Unidos
Fil: Dimov, Ivan. University of Cambridge; Estados Unidos
Fil: Picchio, Matías Luis. Universidad del País Vasco; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Lopez Larrea, Naroa. Universidad del País Vasco; España
Fil: Lopez de Lacalle, Jon. Universidad del País Vasco; España
Fil: Tao, Xudong. University of Cambridge; Estados Unidos
Fil: Ruiz Mateos Serrano, Ruben. University of Cambridge; Estados Unidos
Fil: Gallastegui, Antonela. Universidad del País Vasco; España. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Vassardanis, Nikolaos. No especifíca;
Fil: Mecerreyes, David. Universidad del País Vasco; España
Fil: Malliaras, George G.. University of Cambridge; Estados Unidos - Materia
-
ADHESION
BIOELECTRONICS
DLP 3D PRINTING
MULTI-MATERIAL PRINTING
PEDOT:PSS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/243879
Ver los metadatos del registro completo
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CONICET Digital (CONICET) |
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Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for BioelectronicsDominguez Alfaro, AntonioMitoudi Vagourdi, EleniDimov, IvanPicchio, Matías LuisLopez Larrea, NaroaLopez de Lacalle, JonTao, XudongRuiz Mateos Serrano, RubenGallastegui, AntonelaVassardanis, NikolaosMecerreyes, DavidMalliaras, George G.ADHESIONBIOELECTRONICSDLP 3D PRINTINGMULTI-MATERIAL PRINTINGPEDOT:PSShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work, a new method of multi-material printing in one-go using a commercially available 3D printer is presented. The approach is simple and versatile, allowing the manufacturing of multi-material layered or multi-material printing in the same layer. To the best of the knowledge, it is the first time that 3D printed Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) micro-patterns combining different materials are reported, overcoming mechanical stability issues. Moreover, the conducting ink is engineered to obtain stable in-time materials while retaining sub-100 µm resolution. Micro-structured bio-shaped protuberances are designed and 3D printed as electrodes for electrophysiology. Moreover, these microstructures are combined with polymerizable deep eutectic solvents (polyDES) as functional additives, gaining adhesion and ionic conductivity. As a result of the novel electrodes, low skin impedance values showed suitable performance for electromyography recording on the forearm. Finally, this concluded that the use of polyDES conferred stability over time, allowing the usability of the electrode 90 days after fabrication without losing its performance. All in all, this demonstrated a very easy-to-make procedure that allows printing PEDOT:PSS on soft, hard, and/or flexible functional substrates, opening up a new paradigm in the manufacturing of conducting multi-functional materials for the field of bioelectronics and wearables.Fil: Dominguez Alfaro, Antonio. Universidad del País Vasco; EspañaFil: Mitoudi Vagourdi, Eleni. University of Cambridge; Estados UnidosFil: Dimov, Ivan. University of Cambridge; Estados UnidosFil: Picchio, Matías Luis. Universidad del País Vasco; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Lopez Larrea, Naroa. Universidad del País Vasco; EspañaFil: Lopez de Lacalle, Jon. Universidad del País Vasco; EspañaFil: Tao, Xudong. University of Cambridge; Estados UnidosFil: Ruiz Mateos Serrano, Ruben. University of Cambridge; Estados UnidosFil: Gallastegui, Antonela. Universidad del País Vasco; España. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Vassardanis, Nikolaos. No especifíca;Fil: Mecerreyes, David. Universidad del País Vasco; EspañaFil: Malliaras, George G.. University of Cambridge; Estados UnidosJohn Wiley & Sons2024-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/243879Dominguez Alfaro, Antonio; Mitoudi Vagourdi, Eleni; Dimov, Ivan; Picchio, Matías Luis; Lopez Larrea, Naroa; et al.; Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics; John Wiley & Sons; Advanced Science; 11; 27; 1-2024; 1-132198-3844CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/advs.202306424info:eu-repo/semantics/altIdentifier/doi/10.1002/advs.202306424info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:28:47Zoai:ri.conicet.gov.ar:11336/243879instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:28:48.179CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics |
title |
Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics |
spellingShingle |
Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics Dominguez Alfaro, Antonio ADHESION BIOELECTRONICS DLP 3D PRINTING MULTI-MATERIAL PRINTING PEDOT:PSS |
title_short |
Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics |
title_full |
Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics |
title_fullStr |
Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics |
title_full_unstemmed |
Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics |
title_sort |
Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics |
dc.creator.none.fl_str_mv |
Dominguez Alfaro, Antonio Mitoudi Vagourdi, Eleni Dimov, Ivan Picchio, Matías Luis Lopez Larrea, Naroa Lopez de Lacalle, Jon Tao, Xudong Ruiz Mateos Serrano, Ruben Gallastegui, Antonela Vassardanis, Nikolaos Mecerreyes, David Malliaras, George G. |
author |
Dominguez Alfaro, Antonio |
author_facet |
Dominguez Alfaro, Antonio Mitoudi Vagourdi, Eleni Dimov, Ivan Picchio, Matías Luis Lopez Larrea, Naroa Lopez de Lacalle, Jon Tao, Xudong Ruiz Mateos Serrano, Ruben Gallastegui, Antonela Vassardanis, Nikolaos Mecerreyes, David Malliaras, George G. |
author_role |
author |
author2 |
Mitoudi Vagourdi, Eleni Dimov, Ivan Picchio, Matías Luis Lopez Larrea, Naroa Lopez de Lacalle, Jon Tao, Xudong Ruiz Mateos Serrano, Ruben Gallastegui, Antonela Vassardanis, Nikolaos Mecerreyes, David Malliaras, George G. |
author2_role |
author author author author author author author author author author author |
dc.subject.none.fl_str_mv |
ADHESION BIOELECTRONICS DLP 3D PRINTING MULTI-MATERIAL PRINTING PEDOT:PSS |
topic |
ADHESION BIOELECTRONICS DLP 3D PRINTING MULTI-MATERIAL PRINTING PEDOT:PSS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
In this work, a new method of multi-material printing in one-go using a commercially available 3D printer is presented. The approach is simple and versatile, allowing the manufacturing of multi-material layered or multi-material printing in the same layer. To the best of the knowledge, it is the first time that 3D printed Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) micro-patterns combining different materials are reported, overcoming mechanical stability issues. Moreover, the conducting ink is engineered to obtain stable in-time materials while retaining sub-100 µm resolution. Micro-structured bio-shaped protuberances are designed and 3D printed as electrodes for electrophysiology. Moreover, these microstructures are combined with polymerizable deep eutectic solvents (polyDES) as functional additives, gaining adhesion and ionic conductivity. As a result of the novel electrodes, low skin impedance values showed suitable performance for electromyography recording on the forearm. Finally, this concluded that the use of polyDES conferred stability over time, allowing the usability of the electrode 90 days after fabrication without losing its performance. All in all, this demonstrated a very easy-to-make procedure that allows printing PEDOT:PSS on soft, hard, and/or flexible functional substrates, opening up a new paradigm in the manufacturing of conducting multi-functional materials for the field of bioelectronics and wearables. Fil: Dominguez Alfaro, Antonio. Universidad del País Vasco; España Fil: Mitoudi Vagourdi, Eleni. University of Cambridge; Estados Unidos Fil: Dimov, Ivan. University of Cambridge; Estados Unidos Fil: Picchio, Matías Luis. Universidad del País Vasco; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Lopez Larrea, Naroa. Universidad del País Vasco; España Fil: Lopez de Lacalle, Jon. Universidad del País Vasco; España Fil: Tao, Xudong. University of Cambridge; Estados Unidos Fil: Ruiz Mateos Serrano, Ruben. University of Cambridge; Estados Unidos Fil: Gallastegui, Antonela. Universidad del País Vasco; España. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Vassardanis, Nikolaos. No especifíca; Fil: Mecerreyes, David. Universidad del País Vasco; España Fil: Malliaras, George G.. University of Cambridge; Estados Unidos |
description |
In this work, a new method of multi-material printing in one-go using a commercially available 3D printer is presented. The approach is simple and versatile, allowing the manufacturing of multi-material layered or multi-material printing in the same layer. To the best of the knowledge, it is the first time that 3D printed Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) micro-patterns combining different materials are reported, overcoming mechanical stability issues. Moreover, the conducting ink is engineered to obtain stable in-time materials while retaining sub-100 µm resolution. Micro-structured bio-shaped protuberances are designed and 3D printed as electrodes for electrophysiology. Moreover, these microstructures are combined with polymerizable deep eutectic solvents (polyDES) as functional additives, gaining adhesion and ionic conductivity. As a result of the novel electrodes, low skin impedance values showed suitable performance for electromyography recording on the forearm. Finally, this concluded that the use of polyDES conferred stability over time, allowing the usability of the electrode 90 days after fabrication without losing its performance. All in all, this demonstrated a very easy-to-make procedure that allows printing PEDOT:PSS on soft, hard, and/or flexible functional substrates, opening up a new paradigm in the manufacturing of conducting multi-functional materials for the field of bioelectronics and wearables. |
publishDate |
2024 |
dc.date.none.fl_str_mv |
2024-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/243879 Dominguez Alfaro, Antonio; Mitoudi Vagourdi, Eleni; Dimov, Ivan; Picchio, Matías Luis; Lopez Larrea, Naroa; et al.; Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics; John Wiley & Sons; Advanced Science; 11; 27; 1-2024; 1-13 2198-3844 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/243879 |
identifier_str_mv |
Dominguez Alfaro, Antonio; Mitoudi Vagourdi, Eleni; Dimov, Ivan; Picchio, Matías Luis; Lopez Larrea, Naroa; et al.; Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics; John Wiley & Sons; Advanced Science; 11; 27; 1-2024; 1-13 2198-3844 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/advs.202306424 info:eu-repo/semantics/altIdentifier/doi/10.1002/advs.202306424 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
John Wiley & Sons |
publisher.none.fl_str_mv |
John Wiley & Sons |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844614292585840640 |
score |
13.070432 |