Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material

Autores
Palazzolo, Martín Alejandro; Dourges, Marie Anne; Magueresse, Anthony; Glouannec, Patrick; Maheo, Laurent; Deleuze, Hervé
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Currently, further research on the valorization of lignin is needed to shift biorefineries from a conceptual basis to profitable practice. Providing global warming is a major concern as well, the use of lignin as the sole precursor to elaborate materials with thermal energy storage (TES) applications is especially welcomed in the search for new sustainable solutions. To this end, the preparation of on-demand macroporous carbon foams from calcium lignosulfonate (CaLS) by pyrolysis is described herein, and their capability to microencapsulate phase change materials (PCMs) dedicated to the passive refrigeration of buildings by TES is further assessed as a proof of concept. The as-produced CaLS-based foams were found to be efficient containers for this purpose, displaying any appreciable leakage of PCMs. Furthermore, the thermal properties of the final materials were satisfactory as well, showing that the support does not affect the PCM performance negatively. Considering the process to produce such materials is not only straightforward but also relies on an inexpensive, widely available carbon precursor, it is expected that it serves as a starting point for pilot studies in TES projects.
Fil: Palazzolo, Martín Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Dourges, Marie Anne. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Magueresse, Anthony. Université de Bretagne Sud; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Glouannec, Patrick. Université de Bretagne Sud; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Maheo, Laurent. Université de Bretagne Sud; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Deleuze, Hervé. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; Francia
Materia
BUTYL STEARATE
CARBON FOAM
LIGNOSULFONATE
MACROPOROUS MATERIAL
PHASE CHANGE MATERIALS
PYROLYSIS
THERMAL ENERGY STORAGE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/86528
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/86528
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change MaterialPalazzolo, Martín AlejandroDourges, Marie AnneMagueresse, AnthonyGlouannec, PatrickMaheo, LaurentDeleuze, HervéBUTYL STEARATECARBON FOAMLIGNOSULFONATEMACROPOROUS MATERIALPHASE CHANGE MATERIALSPYROLYSISTHERMAL ENERGY STORAGEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.9https://purl.org/becyt/ford/2Currently, further research on the valorization of lignin is needed to shift biorefineries from a conceptual basis to profitable practice. Providing global warming is a major concern as well, the use of lignin as the sole precursor to elaborate materials with thermal energy storage (TES) applications is especially welcomed in the search for new sustainable solutions. To this end, the preparation of on-demand macroporous carbon foams from calcium lignosulfonate (CaLS) by pyrolysis is described herein, and their capability to microencapsulate phase change materials (PCMs) dedicated to the passive refrigeration of buildings by TES is further assessed as a proof of concept. The as-produced CaLS-based foams were found to be efficient containers for this purpose, displaying any appreciable leakage of PCMs. Furthermore, the thermal properties of the final materials were satisfactory as well, showing that the support does not affect the PCM performance negatively. Considering the process to produce such materials is not only straightforward but also relies on an inexpensive, widely available carbon precursor, it is expected that it serves as a starting point for pilot studies in TES projects.Fil: Palazzolo, Martín Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; FranciaFil: Dourges, Marie Anne. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; FranciaFil: Magueresse, Anthony. Université de Bretagne Sud; Francia. Centre National de la Recherche Scientifique; FranciaFil: Glouannec, Patrick. Université de Bretagne Sud; Francia. Centre National de la Recherche Scientifique; FranciaFil: Maheo, Laurent. Université de Bretagne Sud; Francia. Centre National de la Recherche Scientifique; FranciaFil: Deleuze, Hervé. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; FranciaAmerican Chemical Society2018-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/86528Palazzolo, Martín Alejandro; Dourges, Marie Anne; Magueresse, Anthony; Glouannec, Patrick; Maheo, Laurent; et al.; Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material; American Chemical Society; ACS Sustainable Chemistry and Engineering; 6; 2; 2-2018; 2453-24612168-0485CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acssuschemeng.7b03900info:eu-repo/semantics/altIdentifier/doi/10.1021/acssuschemeng.7b03900info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:49:18Zoai:ri.conicet.gov.ar:11336/86528instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:49:18.946CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material
title Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material
spellingShingle Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material
Palazzolo, Martín Alejandro
BUTYL STEARATE
CARBON FOAM
LIGNOSULFONATE
MACROPOROUS MATERIAL
PHASE CHANGE MATERIALS
PYROLYSIS
THERMAL ENERGY STORAGE
title_short Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material
title_full Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material
title_fullStr Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material
title_full_unstemmed Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material
title_sort Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material
dc.creator.none.fl_str_mv Palazzolo, Martín Alejandro
Dourges, Marie Anne
Magueresse, Anthony
Glouannec, Patrick
Maheo, Laurent
Deleuze, Hervé
author Palazzolo, Martín Alejandro
author_facet Palazzolo, Martín Alejandro
Dourges, Marie Anne
Magueresse, Anthony
Glouannec, Patrick
Maheo, Laurent
Deleuze, Hervé
author_role author
author2 Dourges, Marie Anne
Magueresse, Anthony
Glouannec, Patrick
Maheo, Laurent
Deleuze, Hervé
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv BUTYL STEARATE
CARBON FOAM
LIGNOSULFONATE
MACROPOROUS MATERIAL
PHASE CHANGE MATERIALS
PYROLYSIS
THERMAL ENERGY STORAGE
topic BUTYL STEARATE
CARBON FOAM
LIGNOSULFONATE
MACROPOROUS MATERIAL
PHASE CHANGE MATERIALS
PYROLYSIS
THERMAL ENERGY STORAGE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.9
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Currently, further research on the valorization of lignin is needed to shift biorefineries from a conceptual basis to profitable practice. Providing global warming is a major concern as well, the use of lignin as the sole precursor to elaborate materials with thermal energy storage (TES) applications is especially welcomed in the search for new sustainable solutions. To this end, the preparation of on-demand macroporous carbon foams from calcium lignosulfonate (CaLS) by pyrolysis is described herein, and their capability to microencapsulate phase change materials (PCMs) dedicated to the passive refrigeration of buildings by TES is further assessed as a proof of concept. The as-produced CaLS-based foams were found to be efficient containers for this purpose, displaying any appreciable leakage of PCMs. Furthermore, the thermal properties of the final materials were satisfactory as well, showing that the support does not affect the PCM performance negatively. Considering the process to produce such materials is not only straightforward but also relies on an inexpensive, widely available carbon precursor, it is expected that it serves as a starting point for pilot studies in TES projects.
Fil: Palazzolo, Martín Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Dourges, Marie Anne. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Magueresse, Anthony. Université de Bretagne Sud; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Glouannec, Patrick. Université de Bretagne Sud; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Maheo, Laurent. Université de Bretagne Sud; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Deleuze, Hervé. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; Francia
description Currently, further research on the valorization of lignin is needed to shift biorefineries from a conceptual basis to profitable practice. Providing global warming is a major concern as well, the use of lignin as the sole precursor to elaborate materials with thermal energy storage (TES) applications is especially welcomed in the search for new sustainable solutions. To this end, the preparation of on-demand macroporous carbon foams from calcium lignosulfonate (CaLS) by pyrolysis is described herein, and their capability to microencapsulate phase change materials (PCMs) dedicated to the passive refrigeration of buildings by TES is further assessed as a proof of concept. The as-produced CaLS-based foams were found to be efficient containers for this purpose, displaying any appreciable leakage of PCMs. Furthermore, the thermal properties of the final materials were satisfactory as well, showing that the support does not affect the PCM performance negatively. Considering the process to produce such materials is not only straightforward but also relies on an inexpensive, widely available carbon precursor, it is expected that it serves as a starting point for pilot studies in TES projects.
publishDate 2018
dc.date.none.fl_str_mv 2018-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/86528
Palazzolo, Martín Alejandro; Dourges, Marie Anne; Magueresse, Anthony; Glouannec, Patrick; Maheo, Laurent; et al.; Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material; American Chemical Society; ACS Sustainable Chemistry and Engineering; 6; 2; 2-2018; 2453-2461
2168-0485
CONICET Digital
CONICET
url http://hdl.handle.net/11336/86528
identifier_str_mv Palazzolo, Martín Alejandro; Dourges, Marie Anne; Magueresse, Anthony; Glouannec, Patrick; Maheo, Laurent; et al.; Preparation of Lignosulfonate-Based Carbon Foams by Pyrolysis and Their Use in the Microencapsulation of a Phase Change Material; American Chemical Society; ACS Sustainable Chemistry and Engineering; 6; 2; 2-2018; 2453-2461
2168-0485
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acssuschemeng.7b03900
info:eu-repo/semantics/altIdentifier/doi/10.1021/acssuschemeng.7b03900
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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