Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties

Autores
Arrua, Ruben Dario; San Roman del Barrio, Julio; Gallardo Ruiz, Alberto; Strumia, Miriam Cristina; Alvarez Igarzabal, Cecilia Ines
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Polymeric macroporous rod systems were prepared using N-acryloyl-tris(hydroxymethyl)aminomethane (NAT) and glycidyl methacrylate (GMA) as mono-vinyl monomers and N,N -methylenebisacrylamide (BIS) or trimethylolpropane trimethacrylate (TRIM) as crosslinking agents. The reactions were performed in the presence of a ternary porogenic diluent (composed by dimethylsulfoxide, tetradecanol and poly(ethylenglycol) 6000 (PEG 6000)) and azobisisobutyronitrile (AIBN) as initiator, by freeradical crosslinking copolymerization. The effect of polymerization temperature, porogenic mixture and crosslinker was analyzed. The results showed that a lower polymerization temperature and an increase in the amount of non-solvating diluents (tetradecanol and PEG 6000) in the reaction mixture led to products with higher porosity. The prepared monoliths were promising as potential base supports for different chromatography processes, especially those synthesized with GMA, since its incorporation allows to bind different ligands in a direct coupling reaction.
Fil: Arrua, Ruben Dario. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: San Roman del Barrio, Julio. Instituto de Ciencia y Tecnología de Polímeros; España
Fil: Gallardo Ruiz, Alberto. Instituto de Ciencia y Tecnología de Polímeros; España
Fil: Strumia, Miriam Cristina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Alvarez Igarzabal, Cecilia Ines. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Macroporous Polymers Macroporous Polymers
Rods Systems
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/21333
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/21333
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous propertiesArrua, Ruben DarioSan Roman del Barrio, JulioGallardo Ruiz, AlbertoStrumia, Miriam CristinaAlvarez Igarzabal, Cecilia InesMacroporous Polymers Macroporous PolymersRods Systemshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Polymeric macroporous rod systems were prepared using N-acryloyl-tris(hydroxymethyl)aminomethane (NAT) and glycidyl methacrylate (GMA) as mono-vinyl monomers and N,N -methylenebisacrylamide (BIS) or trimethylolpropane trimethacrylate (TRIM) as crosslinking agents. The reactions were performed in the presence of a ternary porogenic diluent (composed by dimethylsulfoxide, tetradecanol and poly(ethylenglycol) 6000 (PEG 6000)) and azobisisobutyronitrile (AIBN) as initiator, by freeradical crosslinking copolymerization. The effect of polymerization temperature, porogenic mixture and crosslinker was analyzed. The results showed that a lower polymerization temperature and an increase in the amount of non-solvating diluents (tetradecanol and PEG 6000) in the reaction mixture led to products with higher porosity. The prepared monoliths were promising as potential base supports for different chromatography processes, especially those synthesized with GMA, since its incorporation allows to bind different ligands in a direct coupling reaction.Fil: Arrua, Ruben Dario. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: San Roman del Barrio, Julio. Instituto de Ciencia y Tecnología de Polímeros; EspañaFil: Gallardo Ruiz, Alberto. Instituto de Ciencia y Tecnología de Polímeros; EspañaFil: Strumia, Miriam Cristina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Alvarez Igarzabal, Cecilia Ines. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier Science SA2008-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/21333Arrua, Ruben Dario; San Roman del Barrio, Julio; Gallardo Ruiz, Alberto; Strumia, Miriam Cristina; Alvarez Igarzabal, Cecilia Ines; Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties; Elsevier Science SA; Materials Chemistry and Physics; 112; 3; 12-2008; 1055-10600254-0584CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0254058408004811info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2008.07.019info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:51:10Zoai:ri.conicet.gov.ar:11336/21333instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:51:10.383CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties
title Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties
spellingShingle Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties
Arrua, Ruben Dario
Macroporous Polymers Macroporous Polymers
Rods Systems
title_short Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties
title_full Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties
title_fullStr Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties
title_full_unstemmed Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties
title_sort Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties
dc.creator.none.fl_str_mv Arrua, Ruben Dario
San Roman del Barrio, Julio
Gallardo Ruiz, Alberto
Strumia, Miriam Cristina
Alvarez Igarzabal, Cecilia Ines
author Arrua, Ruben Dario
author_facet Arrua, Ruben Dario
San Roman del Barrio, Julio
Gallardo Ruiz, Alberto
Strumia, Miriam Cristina
Alvarez Igarzabal, Cecilia Ines
author_role author
author2 San Roman del Barrio, Julio
Gallardo Ruiz, Alberto
Strumia, Miriam Cristina
Alvarez Igarzabal, Cecilia Ines
author2_role author
author
author
author
dc.subject.none.fl_str_mv Macroporous Polymers Macroporous Polymers
Rods Systems
topic Macroporous Polymers Macroporous Polymers
Rods Systems
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Polymeric macroporous rod systems were prepared using N-acryloyl-tris(hydroxymethyl)aminomethane (NAT) and glycidyl methacrylate (GMA) as mono-vinyl monomers and N,N -methylenebisacrylamide (BIS) or trimethylolpropane trimethacrylate (TRIM) as crosslinking agents. The reactions were performed in the presence of a ternary porogenic diluent (composed by dimethylsulfoxide, tetradecanol and poly(ethylenglycol) 6000 (PEG 6000)) and azobisisobutyronitrile (AIBN) as initiator, by freeradical crosslinking copolymerization. The effect of polymerization temperature, porogenic mixture and crosslinker was analyzed. The results showed that a lower polymerization temperature and an increase in the amount of non-solvating diluents (tetradecanol and PEG 6000) in the reaction mixture led to products with higher porosity. The prepared monoliths were promising as potential base supports for different chromatography processes, especially those synthesized with GMA, since its incorporation allows to bind different ligands in a direct coupling reaction.
Fil: Arrua, Ruben Dario. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: San Roman del Barrio, Julio. Instituto de Ciencia y Tecnología de Polímeros; España
Fil: Gallardo Ruiz, Alberto. Instituto de Ciencia y Tecnología de Polímeros; España
Fil: Strumia, Miriam Cristina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Alvarez Igarzabal, Cecilia Ines. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Polymeric macroporous rod systems were prepared using N-acryloyl-tris(hydroxymethyl)aminomethane (NAT) and glycidyl methacrylate (GMA) as mono-vinyl monomers and N,N -methylenebisacrylamide (BIS) or trimethylolpropane trimethacrylate (TRIM) as crosslinking agents. The reactions were performed in the presence of a ternary porogenic diluent (composed by dimethylsulfoxide, tetradecanol and poly(ethylenglycol) 6000 (PEG 6000)) and azobisisobutyronitrile (AIBN) as initiator, by freeradical crosslinking copolymerization. The effect of polymerization temperature, porogenic mixture and crosslinker was analyzed. The results showed that a lower polymerization temperature and an increase in the amount of non-solvating diluents (tetradecanol and PEG 6000) in the reaction mixture led to products with higher porosity. The prepared monoliths were promising as potential base supports for different chromatography processes, especially those synthesized with GMA, since its incorporation allows to bind different ligands in a direct coupling reaction.
publishDate 2008
dc.date.none.fl_str_mv 2008-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/21333
Arrua, Ruben Dario; San Roman del Barrio, Julio; Gallardo Ruiz, Alberto; Strumia, Miriam Cristina; Alvarez Igarzabal, Cecilia Ines; Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties; Elsevier Science SA; Materials Chemistry and Physics; 112; 3; 12-2008; 1055-1060
0254-0584
CONICET Digital
CONICET
url http://hdl.handle.net/11336/21333
identifier_str_mv Arrua, Ruben Dario; San Roman del Barrio, Julio; Gallardo Ruiz, Alberto; Strumia, Miriam Cristina; Alvarez Igarzabal, Cecilia Ines; Preparation of polymeric macroporous rod systems: Study of the influence of the reaction parameters on the porous properties; Elsevier Science SA; Materials Chemistry and Physics; 112; 3; 12-2008; 1055-1060
0254-0584
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0254058408004811
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2008.07.019
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613574247317504
score 13.070432

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