Hydrogenation of tetralin over Ir-containing mesoporous catalysts

Autores
Vallés, Verónica Alejandra; Balangero Bottazzi, Gerardo Simon; Martínez, María Laura; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo; Beltramone, Andrea Raquel
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A new series of catalysts based on noble metals have been prepared with the main aim of obtaining thiotolerant catalysts to be used in second-stage processes of mild hydrotreating. We studied the catalytic properties of 1 wt % Ir-containing mesoporous materials in the hydrogenation of tetralin to decalin, in the presence of 100 ppm of dibenzotiophene at 250 °C and 15 atm pressure of hydrogen, using a Parr reactor. Ir/mesoporous materials were prepared by wetness impregnation, using iridium acetylacetonate as the source of Ir. The Ir/SBA-3 catalyst synthesized by us had a high activity in tetralin hydrogenation under mild conditions. The experimental data were quantitatively represented by a modified Langmuir-Hinshelwood-type rate equation. The preliminary results reveal that these materials are promising catalyts for HDS/HDN reactions.
Fil: Vallés, Verónica Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina
Fil: Balangero Bottazzi, Gerardo Simon. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina
Fil: Martínez, María Laura. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina
Fil: Gómez Costa, Marcos Bruno. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Materia
Ir-Containing mesoporous materials
Ir-SBA-3
HDS
HDN
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/188883
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Hydrogenation of tetralin over Ir-containing mesoporous catalystsVallés, Verónica AlejandraBalangero Bottazzi, Gerardo SimonMartínez, María LauraGómez Costa, Marcos BrunoAnunziata, Oscar AlfredoBeltramone, Andrea RaquelIr-Containing mesoporous materialsIr-SBA-3HDSHDNhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A new series of catalysts based on noble metals have been prepared with the main aim of obtaining thiotolerant catalysts to be used in second-stage processes of mild hydrotreating. We studied the catalytic properties of 1 wt % Ir-containing mesoporous materials in the hydrogenation of tetralin to decalin, in the presence of 100 ppm of dibenzotiophene at 250 °C and 15 atm pressure of hydrogen, using a Parr reactor. Ir/mesoporous materials were prepared by wetness impregnation, using iridium acetylacetonate as the source of Ir. The Ir/SBA-3 catalyst synthesized by us had a high activity in tetralin hydrogenation under mild conditions. The experimental data were quantitatively represented by a modified Langmuir-Hinshelwood-type rate equation. The preliminary results reveal that these materials are promising catalyts for HDS/HDN reactions.Fil: Vallés, Verónica Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba; ArgentinaFil: Balangero Bottazzi, Gerardo Simon. Universidad Tecnológica Nacional. Facultad Regional Córdoba; ArgentinaFil: Martínez, María Laura. Universidad Tecnológica Nacional. Facultad Regional Córdoba; ArgentinaFil: Gómez Costa, Marcos Bruno. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba; ArgentinaFil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaAmerican Chemical Society2012-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/188883Vallés, Verónica Alejandra; Balangero Bottazzi, Gerardo Simon; Martínez, María Laura; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo; et al.; Hydrogenation of tetralin over Ir-containing mesoporous catalysts; American Chemical Society; Industrial & Engineering Chemical Research; 51; 21; 5-2012; 7185-71950888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie202727rinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie202727rinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-29T12:19:23Zoai:ri.conicet.gov.ar:11336/188883instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-29 12:19:24.003CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrogenation of tetralin over Ir-containing mesoporous catalysts
title Hydrogenation of tetralin over Ir-containing mesoporous catalysts
spellingShingle Hydrogenation of tetralin over Ir-containing mesoporous catalysts
Vallés, Verónica Alejandra
Ir-Containing mesoporous materials
Ir-SBA-3
HDS
HDN
title_short Hydrogenation of tetralin over Ir-containing mesoporous catalysts
title_full Hydrogenation of tetralin over Ir-containing mesoporous catalysts
title_fullStr Hydrogenation of tetralin over Ir-containing mesoporous catalysts
title_full_unstemmed Hydrogenation of tetralin over Ir-containing mesoporous catalysts
title_sort Hydrogenation of tetralin over Ir-containing mesoporous catalysts
dc.creator.none.fl_str_mv Vallés, Verónica Alejandra
Balangero Bottazzi, Gerardo Simon
Martínez, María Laura
Gómez Costa, Marcos Bruno
Anunziata, Oscar Alfredo
Beltramone, Andrea Raquel
author Vallés, Verónica Alejandra
author_facet Vallés, Verónica Alejandra
Balangero Bottazzi, Gerardo Simon
Martínez, María Laura
Gómez Costa, Marcos Bruno
Anunziata, Oscar Alfredo
Beltramone, Andrea Raquel
author_role author
author2 Balangero Bottazzi, Gerardo Simon
Martínez, María Laura
Gómez Costa, Marcos Bruno
Anunziata, Oscar Alfredo
Beltramone, Andrea Raquel
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Ir-Containing mesoporous materials
Ir-SBA-3
HDS
HDN
topic Ir-Containing mesoporous materials
Ir-SBA-3
HDS
HDN
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A new series of catalysts based on noble metals have been prepared with the main aim of obtaining thiotolerant catalysts to be used in second-stage processes of mild hydrotreating. We studied the catalytic properties of 1 wt % Ir-containing mesoporous materials in the hydrogenation of tetralin to decalin, in the presence of 100 ppm of dibenzotiophene at 250 °C and 15 atm pressure of hydrogen, using a Parr reactor. Ir/mesoporous materials were prepared by wetness impregnation, using iridium acetylacetonate as the source of Ir. The Ir/SBA-3 catalyst synthesized by us had a high activity in tetralin hydrogenation under mild conditions. The experimental data were quantitatively represented by a modified Langmuir-Hinshelwood-type rate equation. The preliminary results reveal that these materials are promising catalyts for HDS/HDN reactions.
Fil: Vallés, Verónica Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina
Fil: Balangero Bottazzi, Gerardo Simon. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina
Fil: Martínez, María Laura. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina
Fil: Gómez Costa, Marcos Bruno. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
description A new series of catalysts based on noble metals have been prepared with the main aim of obtaining thiotolerant catalysts to be used in second-stage processes of mild hydrotreating. We studied the catalytic properties of 1 wt % Ir-containing mesoporous materials in the hydrogenation of tetralin to decalin, in the presence of 100 ppm of dibenzotiophene at 250 °C and 15 atm pressure of hydrogen, using a Parr reactor. Ir/mesoporous materials were prepared by wetness impregnation, using iridium acetylacetonate as the source of Ir. The Ir/SBA-3 catalyst synthesized by us had a high activity in tetralin hydrogenation under mild conditions. The experimental data were quantitatively represented by a modified Langmuir-Hinshelwood-type rate equation. The preliminary results reveal that these materials are promising catalyts for HDS/HDN reactions.
publishDate 2012
dc.date.none.fl_str_mv 2012-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/188883
Vallés, Verónica Alejandra; Balangero Bottazzi, Gerardo Simon; Martínez, María Laura; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo; et al.; Hydrogenation of tetralin over Ir-containing mesoporous catalysts; American Chemical Society; Industrial & Engineering Chemical Research; 51; 21; 5-2012; 7185-7195
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/188883
identifier_str_mv Vallés, Verónica Alejandra; Balangero Bottazzi, Gerardo Simon; Martínez, María Laura; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo; et al.; Hydrogenation of tetralin over Ir-containing mesoporous catalysts; American Chemical Society; Industrial & Engineering Chemical Research; 51; 21; 5-2012; 7185-7195
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ie202727r
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie202727r
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1847427087365832704
score 12.589754

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