Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole

Autores
Dinamarca, Robinson; Vallés, Verónica Alejandra; Ledesma, Brenda Cecilia Soledad; Campos, Cristian H.; Pecchi, Gina; Beltramone, Andrea Raquel
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of a second porous SiO2 shell in the activity and selectivity of the Fe3O4atSiO2-Pt catalyst in the hydrodenitrogenation of indole is reported. The double Fe3O4atSiO2-PtatSiO2 structure was prepared by coating Fe3O4 nanoparticles with tetraethyl orthosilicate (TEOS) with a further impregnation of 1.0 wt.% of Pt on the (3-aminopropyl)triethoxysilane functionalized Fe3O4atSiO2 structures. The second porous SiO2 shell, obtained by using a hexadecyltrimethylammonium bromide (CTAB) template, covered the Fe3O4atSiO2-Pt catalyst with a well-defined and narrow pore-sized distribution. The full characterization by TEM, inductively coupled plasma-optical emission spectroscopy (ICP-OES), XRD, and N2 adsorption isotherm at 77 K and vibrating sample magnetometry (VSM) of the catalysts indicates homogeneous coreatshell structures with a controlled nano-size of metallic Pt. A significant effect of the double SiO2 shell in the catalytic performance was demonstrated by both a higher activity to eliminate the nitrogen atom of the indole molecule present in model liquid fuel and the improvement of the catalytic stability reaching four consecutive reaction cycles with only a slight conversion level decrease.
Fil: Dinamarca, Robinson. Universidad de Concepción; Chile
Fil: Vallés, Verónica Alejandra. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Ledesma, Brenda Cecilia Soledad. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Campos, Cristian H.. Universidad de Concepción; Chile
Fil: Pecchi, Gina. Universidad de Concepción; Chile. Pontificia Universidad Católica de Chile; Chile
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Materia
COREATSHELL
INDOLE HDN
MESOPOROUS MATERIALS
PLATINUM
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/129885
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/129885
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indoleDinamarca, RobinsonVallés, Verónica AlejandraLedesma, Brenda Cecilia SoledadCampos, Cristian H.Pecchi, GinaBeltramone, Andrea RaquelCOREATSHELLINDOLE HDNMESOPOROUS MATERIALSPLATINUMhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The effect of a second porous SiO2 shell in the activity and selectivity of the Fe3O4atSiO2-Pt catalyst in the hydrodenitrogenation of indole is reported. The double Fe3O4atSiO2-PtatSiO2 structure was prepared by coating Fe3O4 nanoparticles with tetraethyl orthosilicate (TEOS) with a further impregnation of 1.0 wt.% of Pt on the (3-aminopropyl)triethoxysilane functionalized Fe3O4atSiO2 structures. The second porous SiO2 shell, obtained by using a hexadecyltrimethylammonium bromide (CTAB) template, covered the Fe3O4atSiO2-Pt catalyst with a well-defined and narrow pore-sized distribution. The full characterization by TEM, inductively coupled plasma-optical emission spectroscopy (ICP-OES), XRD, and N2 adsorption isotherm at 77 K and vibrating sample magnetometry (VSM) of the catalysts indicates homogeneous coreatshell structures with a controlled nano-size of metallic Pt. A significant effect of the double SiO2 shell in the catalytic performance was demonstrated by both a higher activity to eliminate the nitrogen atom of the indole molecule present in model liquid fuel and the improvement of the catalytic stability reaching four consecutive reaction cycles with only a slight conversion level decrease.Fil: Dinamarca, Robinson. Universidad de Concepción; ChileFil: Vallés, Verónica Alejandra. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Ledesma, Brenda Cecilia Soledad. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Campos, Cristian H.. Universidad de Concepción; ChileFil: Pecchi, Gina. Universidad de Concepción; Chile. Pontificia Universidad Católica de Chile; ChileFil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaMultidisciplinary Digital Publishing Institute2019-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/129885Dinamarca, Robinson; Vallés, Verónica Alejandra; Ledesma, Brenda Cecilia Soledad; Campos, Cristian H.; Pecchi, Gina; et al.; Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole; Multidisciplinary Digital Publishing Institute; Materials; 12; 23; 12-2019; 1-121996-1944CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1944/12/23/3878info:eu-repo/semantics/altIdentifier/doi/10.3390/ma12233878info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:47:13Zoai:ri.conicet.gov.ar:11336/129885instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:47:13.796CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole
title Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole
spellingShingle Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole
Dinamarca, Robinson
COREATSHELL
INDOLE HDN
MESOPOROUS MATERIALS
PLATINUM
title_short Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole
title_full Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole
title_fullStr Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole
title_full_unstemmed Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole
title_sort Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole
dc.creator.none.fl_str_mv Dinamarca, Robinson
Vallés, Verónica Alejandra
Ledesma, Brenda Cecilia Soledad
Campos, Cristian H.
Pecchi, Gina
Beltramone, Andrea Raquel
author Dinamarca, Robinson
author_facet Dinamarca, Robinson
Vallés, Verónica Alejandra
Ledesma, Brenda Cecilia Soledad
Campos, Cristian H.
Pecchi, Gina
Beltramone, Andrea Raquel
author_role author
author2 Vallés, Verónica Alejandra
Ledesma, Brenda Cecilia Soledad
Campos, Cristian H.
Pecchi, Gina
Beltramone, Andrea Raquel
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv COREATSHELL
INDOLE HDN
MESOPOROUS MATERIALS
PLATINUM
topic COREATSHELL
INDOLE HDN
MESOPOROUS MATERIALS
PLATINUM
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The effect of a second porous SiO2 shell in the activity and selectivity of the Fe3O4atSiO2-Pt catalyst in the hydrodenitrogenation of indole is reported. The double Fe3O4atSiO2-PtatSiO2 structure was prepared by coating Fe3O4 nanoparticles with tetraethyl orthosilicate (TEOS) with a further impregnation of 1.0 wt.% of Pt on the (3-aminopropyl)triethoxysilane functionalized Fe3O4atSiO2 structures. The second porous SiO2 shell, obtained by using a hexadecyltrimethylammonium bromide (CTAB) template, covered the Fe3O4atSiO2-Pt catalyst with a well-defined and narrow pore-sized distribution. The full characterization by TEM, inductively coupled plasma-optical emission spectroscopy (ICP-OES), XRD, and N2 adsorption isotherm at 77 K and vibrating sample magnetometry (VSM) of the catalysts indicates homogeneous coreatshell structures with a controlled nano-size of metallic Pt. A significant effect of the double SiO2 shell in the catalytic performance was demonstrated by both a higher activity to eliminate the nitrogen atom of the indole molecule present in model liquid fuel and the improvement of the catalytic stability reaching four consecutive reaction cycles with only a slight conversion level decrease.
Fil: Dinamarca, Robinson. Universidad de Concepción; Chile
Fil: Vallés, Verónica Alejandra. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Ledesma, Brenda Cecilia Soledad. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Campos, Cristian H.. Universidad de Concepción; Chile
Fil: Pecchi, Gina. Universidad de Concepción; Chile. Pontificia Universidad Católica de Chile; Chile
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
description The effect of a second porous SiO2 shell in the activity and selectivity of the Fe3O4atSiO2-Pt catalyst in the hydrodenitrogenation of indole is reported. The double Fe3O4atSiO2-PtatSiO2 structure was prepared by coating Fe3O4 nanoparticles with tetraethyl orthosilicate (TEOS) with a further impregnation of 1.0 wt.% of Pt on the (3-aminopropyl)triethoxysilane functionalized Fe3O4atSiO2 structures. The second porous SiO2 shell, obtained by using a hexadecyltrimethylammonium bromide (CTAB) template, covered the Fe3O4atSiO2-Pt catalyst with a well-defined and narrow pore-sized distribution. The full characterization by TEM, inductively coupled plasma-optical emission spectroscopy (ICP-OES), XRD, and N2 adsorption isotherm at 77 K and vibrating sample magnetometry (VSM) of the catalysts indicates homogeneous coreatshell structures with a controlled nano-size of metallic Pt. A significant effect of the double SiO2 shell in the catalytic performance was demonstrated by both a higher activity to eliminate the nitrogen atom of the indole molecule present in model liquid fuel and the improvement of the catalytic stability reaching four consecutive reaction cycles with only a slight conversion level decrease.
publishDate 2019
dc.date.none.fl_str_mv 2019-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/129885
Dinamarca, Robinson; Vallés, Verónica Alejandra; Ledesma, Brenda Cecilia Soledad; Campos, Cristian H.; Pecchi, Gina; et al.; Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole; Multidisciplinary Digital Publishing Institute; Materials; 12; 23; 12-2019; 1-12
1996-1944
CONICET Digital
CONICET
url http://hdl.handle.net/11336/129885
identifier_str_mv Dinamarca, Robinson; Vallés, Verónica Alejandra; Ledesma, Brenda Cecilia Soledad; Campos, Cristian H.; Pecchi, Gina; et al.; Magnetic Fe3O4atSiO2-Pt and Fe3O4atSiO2-PtatSiO2 structures for HDN of indole; Multidisciplinary Digital Publishing Institute; Materials; 12; 23; 12-2019; 1-12
1996-1944
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1944/12/23/3878
info:eu-repo/semantics/altIdentifier/doi/10.3390/ma12233878
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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