Assembly of Ferrocene Molecules on Metal Surfaces Revisited

Autores
Ormaza, Maider; Abufager, Paula Natalia; Bachellier, Nicolas; Robles, Roberto; Verot, Martin; Le Bahers, Tangui; Bocquet, Marie Laure; Lorente, Nicolas; Limot, Laurent
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Metallocene (MCp2) wires have recently attracted considerable interest in relation to molecular spintronics due to predictions concerning their half-metallic nature. This exciting prospect is however hampered by the little and often-contradictory knowledge we have concerning the metallocene self-assembly and interaction with a metal. Here, we elucidate these aspects by focusing on the adsorption of ferrocene on Cu(111) and Cu(100). Combining low-temperature scanning tunneling microscopy and density functional theory calculations, we demonstrate that the two-dimensional molecular arrangement consists of vertical- and horizontal-lying molecules. The noncovalent T-shaped interactions between Cp rings of vertical and horizontal molecules are essential for the stability of the physisorbed molecular layer. These results provide a fresh insight into ferrocene adsorption on surfaces and may serve as an archetypal reference for future work with this important variety of organometallic molecules.
Fil: Ormaza, Maider. Universite de Strasbourg; Francia
Fil: Abufager, Paula Natalia. Institut Cataláde Nanociencia i Nanotecnologia; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Física de Rosario (i); Argentina
Fil: Bachellier, Nicolas. Universite de Strasbourg; Francia
Fil: Robles, Roberto . Institut Cataláde Nanociencia i Nanotecnologia; España. Consejo Superior de Investigaciones Científicas; España
Fil: Verot, Martin. Universite Clause Bernard de Lyon; Francia
Fil: Le Bahers, Tangui. Universite Clause Bernard de Lyon; Francia
Fil: Bocquet, Marie Laure. Universite Clause Bernard de Lyon; Francia
Fil: Lorente, Nicolas. Institut Cataláde Nanociencia i Nanotecnologia; España. Consejo Superior de Investigaciones Científicas; España
Fil: Limot, Laurent. Universite de Strasbourg; Francia
Materia
Ferrocene
Assembly
Surface
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/6163
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Assembly of Ferrocene Molecules on Metal Surfaces RevisitedOrmaza, MaiderAbufager, Paula NataliaBachellier, NicolasRobles, Roberto Verot, MartinLe Bahers, TanguiBocquet, Marie LaureLorente, NicolasLimot, LaurentFerroceneAssemblySurfacehttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Metallocene (MCp2) wires have recently attracted considerable interest in relation to molecular spintronics due to predictions concerning their half-metallic nature. This exciting prospect is however hampered by the little and often-contradictory knowledge we have concerning the metallocene self-assembly and interaction with a metal. Here, we elucidate these aspects by focusing on the adsorption of ferrocene on Cu(111) and Cu(100). Combining low-temperature scanning tunneling microscopy and density functional theory calculations, we demonstrate that the two-dimensional molecular arrangement consists of vertical- and horizontal-lying molecules. The noncovalent T-shaped interactions between Cp rings of vertical and horizontal molecules are essential for the stability of the physisorbed molecular layer. These results provide a fresh insight into ferrocene adsorption on surfaces and may serve as an archetypal reference for future work with this important variety of organometallic molecules.Fil: Ormaza, Maider. Universite de Strasbourg; FranciaFil: Abufager, Paula Natalia. Institut Cataláde Nanociencia i Nanotecnologia; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Física de Rosario (i); ArgentinaFil: Bachellier, Nicolas. Universite de Strasbourg; FranciaFil: Robles, Roberto . Institut Cataláde Nanociencia i Nanotecnologia; España. Consejo Superior de Investigaciones Científicas; EspañaFil: Verot, Martin. Universite Clause Bernard de Lyon; FranciaFil: Le Bahers, Tangui. Universite Clause Bernard de Lyon; FranciaFil: Bocquet, Marie Laure. Universite Clause Bernard de Lyon; FranciaFil: Lorente, Nicolas. Institut Cataláde Nanociencia i Nanotecnologia; España. Consejo Superior de Investigaciones Científicas; EspañaFil: Limot, Laurent. Universite de Strasbourg; FranciaAmerican Chemical Society2015-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6163Ormaza, Maider; Abufager, Paula Natalia; Bachellier, Nicolas; Robles, Roberto ; Verot, Martin; et al.; Assembly of Ferrocene Molecules on Metal Surfaces Revisited; American Chemical Society; Journal of Physical Chemistry Letters; 6; 3; 1-2015; 395-4001948-7185enginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jz5026118info:eu-repo/semantics/altIdentifier/doi/10.1021/jz5026118info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T10:08:21Zoai:ri.conicet.gov.ar:11336/6163instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 10:08:22.197CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Assembly of Ferrocene Molecules on Metal Surfaces Revisited
title Assembly of Ferrocene Molecules on Metal Surfaces Revisited
spellingShingle Assembly of Ferrocene Molecules on Metal Surfaces Revisited
Ormaza, Maider
Ferrocene
Assembly
Surface
title_short Assembly of Ferrocene Molecules on Metal Surfaces Revisited
title_full Assembly of Ferrocene Molecules on Metal Surfaces Revisited
title_fullStr Assembly of Ferrocene Molecules on Metal Surfaces Revisited
title_full_unstemmed Assembly of Ferrocene Molecules on Metal Surfaces Revisited
title_sort Assembly of Ferrocene Molecules on Metal Surfaces Revisited
dc.creator.none.fl_str_mv Ormaza, Maider
Abufager, Paula Natalia
Bachellier, Nicolas
Robles, Roberto
Verot, Martin
Le Bahers, Tangui
Bocquet, Marie Laure
Lorente, Nicolas
Limot, Laurent
author Ormaza, Maider
author_facet Ormaza, Maider
Abufager, Paula Natalia
Bachellier, Nicolas
Robles, Roberto
Verot, Martin
Le Bahers, Tangui
Bocquet, Marie Laure
Lorente, Nicolas
Limot, Laurent
author_role author
author2 Abufager, Paula Natalia
Bachellier, Nicolas
Robles, Roberto
Verot, Martin
Le Bahers, Tangui
Bocquet, Marie Laure
Lorente, Nicolas
Limot, Laurent
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Ferrocene
Assembly
Surface
topic Ferrocene
Assembly
Surface
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Metallocene (MCp2) wires have recently attracted considerable interest in relation to molecular spintronics due to predictions concerning their half-metallic nature. This exciting prospect is however hampered by the little and often-contradictory knowledge we have concerning the metallocene self-assembly and interaction with a metal. Here, we elucidate these aspects by focusing on the adsorption of ferrocene on Cu(111) and Cu(100). Combining low-temperature scanning tunneling microscopy and density functional theory calculations, we demonstrate that the two-dimensional molecular arrangement consists of vertical- and horizontal-lying molecules. The noncovalent T-shaped interactions between Cp rings of vertical and horizontal molecules are essential for the stability of the physisorbed molecular layer. These results provide a fresh insight into ferrocene adsorption on surfaces and may serve as an archetypal reference for future work with this important variety of organometallic molecules.
Fil: Ormaza, Maider. Universite de Strasbourg; Francia
Fil: Abufager, Paula Natalia. Institut Cataláde Nanociencia i Nanotecnologia; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Física de Rosario (i); Argentina
Fil: Bachellier, Nicolas. Universite de Strasbourg; Francia
Fil: Robles, Roberto . Institut Cataláde Nanociencia i Nanotecnologia; España. Consejo Superior de Investigaciones Científicas; España
Fil: Verot, Martin. Universite Clause Bernard de Lyon; Francia
Fil: Le Bahers, Tangui. Universite Clause Bernard de Lyon; Francia
Fil: Bocquet, Marie Laure. Universite Clause Bernard de Lyon; Francia
Fil: Lorente, Nicolas. Institut Cataláde Nanociencia i Nanotecnologia; España. Consejo Superior de Investigaciones Científicas; España
Fil: Limot, Laurent. Universite de Strasbourg; Francia
description Metallocene (MCp2) wires have recently attracted considerable interest in relation to molecular spintronics due to predictions concerning their half-metallic nature. This exciting prospect is however hampered by the little and often-contradictory knowledge we have concerning the metallocene self-assembly and interaction with a metal. Here, we elucidate these aspects by focusing on the adsorption of ferrocene on Cu(111) and Cu(100). Combining low-temperature scanning tunneling microscopy and density functional theory calculations, we demonstrate that the two-dimensional molecular arrangement consists of vertical- and horizontal-lying molecules. The noncovalent T-shaped interactions between Cp rings of vertical and horizontal molecules are essential for the stability of the physisorbed molecular layer. These results provide a fresh insight into ferrocene adsorption on surfaces and may serve as an archetypal reference for future work with this important variety of organometallic molecules.
publishDate 2015
dc.date.none.fl_str_mv 2015-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/6163
Ormaza, Maider; Abufager, Paula Natalia; Bachellier, Nicolas; Robles, Roberto ; Verot, Martin; et al.; Assembly of Ferrocene Molecules on Metal Surfaces Revisited; American Chemical Society; Journal of Physical Chemistry Letters; 6; 3; 1-2015; 395-400
1948-7185
url http://hdl.handle.net/11336/6163
identifier_str_mv Ormaza, Maider; Abufager, Paula Natalia; Bachellier, Nicolas; Robles, Roberto ; Verot, Martin; et al.; Assembly of Ferrocene Molecules on Metal Surfaces Revisited; American Chemical Society; Journal of Physical Chemistry Letters; 6; 3; 1-2015; 395-400
1948-7185
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jz5026118
info:eu-repo/semantics/altIdentifier/doi/10.1021/jz5026118
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.121305

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