Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films

Autores
Marmisollé, Waldemar Alejandro; Irigoyen, Joseba; Gregurec, Danijela; Moya, Sergio; Azzaroni, Omar
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The ability to engineer surfaces at the supramolecular level by controlled integration of specific chemical units through substrate-independent methodologies represents one of the new paradigms of contemporary materials science. Here, a method is reported to form multifunctional supramolecular coatings through simple dip-coating of substrates in an aqueous solution of polyamine in the presence of phosphate anions. The chemical richness and versatility of polyamines are exploited as phosphate receptors to form thin functional films on a broad variety of substrates, ranging from metal to carbonaceous surfaces. It is shown that the simple derivatization of pendant amino groups of polyallylamine precursors with different chemical groups can endow fi lms with predefi ned responsiveness or multiple functions?this translates into one-pot and one-step preparation of substrate-adherent fi lms displaying built-in functions. It is believed that the flexibility, speed, and versatility with which this method provides such robust functional fi lms make it very attractive for preparing samples of fundamental and technological interest.
Fil: Marmisollé, Waldemar Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Irigoyen, Joseba. CIC biome GUNE. Soft Matter Nanotechnology Group; España
Fil: Gregurec, Danijela. CIC biome GUNE. Soft Matter Nanotechnology Group; España
Fil: Moya, Sergio. CIC biome GUNE. Soft Matter Nanotechnology Group; España
Fil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Materia
Supramolecular Assembly
Surface Chemistry
Supramolecular Materials
Self-Assembly
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5037
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin filmsMarmisollé, Waldemar AlejandroIrigoyen, JosebaGregurec, DanijelaMoya, SergioAzzaroni, OmarSupramolecular AssemblySurface ChemistrySupramolecular MaterialsSelf-Assemblyhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The ability to engineer surfaces at the supramolecular level by controlled integration of specific chemical units through substrate-independent methodologies represents one of the new paradigms of contemporary materials science. Here, a method is reported to form multifunctional supramolecular coatings through simple dip-coating of substrates in an aqueous solution of polyamine in the presence of phosphate anions. The chemical richness and versatility of polyamines are exploited as phosphate receptors to form thin functional films on a broad variety of substrates, ranging from metal to carbonaceous surfaces. It is shown that the simple derivatization of pendant amino groups of polyallylamine precursors with different chemical groups can endow fi lms with predefi ned responsiveness or multiple functions?this translates into one-pot and one-step preparation of substrate-adherent fi lms displaying built-in functions. It is believed that the flexibility, speed, and versatility with which this method provides such robust functional fi lms make it very attractive for preparing samples of fundamental and technological interest.Fil: Marmisollé, Waldemar Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Irigoyen, Joseba. CIC biome GUNE. Soft Matter Nanotechnology Group; EspañaFil: Gregurec, Danijela. CIC biome GUNE. Soft Matter Nanotechnology Group; EspañaFil: Moya, Sergio. CIC biome GUNE. Soft Matter Nanotechnology Group; EspañaFil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaWiley2015-05-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5037Marmisollé, Waldemar Alejandro; Irigoyen, Joseba; Gregurec, Danijela; Moya, Sergio; Azzaroni, Omar; Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films; Wiley; Advanced Functional Materials; 25; 26; 21-5-2015; 4144-41521616-301Xenginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/adfm.201501140/abstractinfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1002/adfm.201501140info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:47Zoai:ri.conicet.gov.ar:11336/5037instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:48.27CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films
title Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films
spellingShingle Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films
Marmisollé, Waldemar Alejandro
Supramolecular Assembly
Surface Chemistry
Supramolecular Materials
Self-Assembly
title_short Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films
title_full Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films
title_fullStr Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films
title_full_unstemmed Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films
title_sort Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films
dc.creator.none.fl_str_mv Marmisollé, Waldemar Alejandro
Irigoyen, Joseba
Gregurec, Danijela
Moya, Sergio
Azzaroni, Omar
author Marmisollé, Waldemar Alejandro
author_facet Marmisollé, Waldemar Alejandro
Irigoyen, Joseba
Gregurec, Danijela
Moya, Sergio
Azzaroni, Omar
author_role author
author2 Irigoyen, Joseba
Gregurec, Danijela
Moya, Sergio
Azzaroni, Omar
author2_role author
author
author
author
dc.subject.none.fl_str_mv Supramolecular Assembly
Surface Chemistry
Supramolecular Materials
Self-Assembly
topic Supramolecular Assembly
Surface Chemistry
Supramolecular Materials
Self-Assembly
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The ability to engineer surfaces at the supramolecular level by controlled integration of specific chemical units through substrate-independent methodologies represents one of the new paradigms of contemporary materials science. Here, a method is reported to form multifunctional supramolecular coatings through simple dip-coating of substrates in an aqueous solution of polyamine in the presence of phosphate anions. The chemical richness and versatility of polyamines are exploited as phosphate receptors to form thin functional films on a broad variety of substrates, ranging from metal to carbonaceous surfaces. It is shown that the simple derivatization of pendant amino groups of polyallylamine precursors with different chemical groups can endow fi lms with predefi ned responsiveness or multiple functions?this translates into one-pot and one-step preparation of substrate-adherent fi lms displaying built-in functions. It is believed that the flexibility, speed, and versatility with which this method provides such robust functional fi lms make it very attractive for preparing samples of fundamental and technological interest.
Fil: Marmisollé, Waldemar Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Irigoyen, Joseba. CIC biome GUNE. Soft Matter Nanotechnology Group; España
Fil: Gregurec, Danijela. CIC biome GUNE. Soft Matter Nanotechnology Group; España
Fil: Moya, Sergio. CIC biome GUNE. Soft Matter Nanotechnology Group; España
Fil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
description The ability to engineer surfaces at the supramolecular level by controlled integration of specific chemical units through substrate-independent methodologies represents one of the new paradigms of contemporary materials science. Here, a method is reported to form multifunctional supramolecular coatings through simple dip-coating of substrates in an aqueous solution of polyamine in the presence of phosphate anions. The chemical richness and versatility of polyamines are exploited as phosphate receptors to form thin functional films on a broad variety of substrates, ranging from metal to carbonaceous surfaces. It is shown that the simple derivatization of pendant amino groups of polyallylamine precursors with different chemical groups can endow fi lms with predefi ned responsiveness or multiple functions?this translates into one-pot and one-step preparation of substrate-adherent fi lms displaying built-in functions. It is believed that the flexibility, speed, and versatility with which this method provides such robust functional fi lms make it very attractive for preparing samples of fundamental and technological interest.
publishDate 2015
dc.date.none.fl_str_mv 2015-05-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5037
Marmisollé, Waldemar Alejandro; Irigoyen, Joseba; Gregurec, Danijela; Moya, Sergio; Azzaroni, Omar; Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films; Wiley; Advanced Functional Materials; 25; 26; 21-5-2015; 4144-4152
1616-301X
url http://hdl.handle.net/11336/5037
identifier_str_mv Marmisollé, Waldemar Alejandro; Irigoyen, Joseba; Gregurec, Danijela; Moya, Sergio; Azzaroni, Omar; Supramolecular surface chemistry: Substrate-independent, phosphate-driven growth of polyamine-based multifunctional thin films; Wiley; Advanced Functional Materials; 25; 26; 21-5-2015; 4144-4152
1616-301X
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/adfm.201501140/abstract
info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/doi/10.1002/adfm.201501140
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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