Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes

Autores
Mártire, Ana Paula; Fenoy, Gonzalo Eduardo; Azzaroni, Omar; Rafti, Matias; Marmisollé, Waldemar Alejandro
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Supercapacitors are devices that bridge the gap between traditional capacitors and rechargeable batteries, offering exceptional energy storage capabilities, rapid charge/discharge rates, long cycle life, and environmental friendliness. This study explores the development of neutral-aqueous supercapacitor materials using conductive polymers, with a focus on polyaniline (PANI) doped with anionic polyelectrolytes. Combining PANI with carbon nanomaterials through various construction processes, including layer-by-layer assembly, nanoarchitectonics is employed to create desirable nanostructures on the electrode surface. The introduction of a redox-active surfactant (ferrocene-labelled surfactant, FcCTAB) in the layer-by-layer assembly adds a unique dimension of redox activity, enhancing the electrochemical capacitance of the hybrid coatings. Through voltammetric, charge–discharge, and electrochemical quartz crystal microbalance (EQCM) measurements, we investigate the capacitive performance and dynamic mass changes during potential cycling. The study demonstrates that the integration of the redox moiety significantly improves capacitive performance in neutral solutions without compromising structural stability and cyclability. This approach synergistically combines nanocarbon materials, electroactive polymers, and the faradaic contribution of the electroactive surfactant, presenting a supercapacitor material with excellent performance with potential application in wearable devices for secure energy storage.
Fil: Mártire, Ana Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Fenoy, Gonzalo Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Rafti, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Marmisollé, Waldemar Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Materia
Ferrocene
Conducting Polymers
Supercapacitors
nanoarchitectonics
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/262259
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/262259
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodesMártire, Ana PaulaFenoy, Gonzalo EduardoAzzaroni, OmarRafti, MatiasMarmisollé, Waldemar AlejandroFerroceneConducting PolymersSupercapacitorsnanoarchitectonicshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Supercapacitors are devices that bridge the gap between traditional capacitors and rechargeable batteries, offering exceptional energy storage capabilities, rapid charge/discharge rates, long cycle life, and environmental friendliness. This study explores the development of neutral-aqueous supercapacitor materials using conductive polymers, with a focus on polyaniline (PANI) doped with anionic polyelectrolytes. Combining PANI with carbon nanomaterials through various construction processes, including layer-by-layer assembly, nanoarchitectonics is employed to create desirable nanostructures on the electrode surface. The introduction of a redox-active surfactant (ferrocene-labelled surfactant, FcCTAB) in the layer-by-layer assembly adds a unique dimension of redox activity, enhancing the electrochemical capacitance of the hybrid coatings. Through voltammetric, charge–discharge, and electrochemical quartz crystal microbalance (EQCM) measurements, we investigate the capacitive performance and dynamic mass changes during potential cycling. The study demonstrates that the integration of the redox moiety significantly improves capacitive performance in neutral solutions without compromising structural stability and cyclability. This approach synergistically combines nanocarbon materials, electroactive polymers, and the faradaic contribution of the electroactive surfactant, presenting a supercapacitor material with excellent performance with potential application in wearable devices for secure energy storage.Fil: Mártire, Ana Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Fenoy, Gonzalo Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Rafti, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Marmisollé, Waldemar Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaRoyal Society of Chemistry2024-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/262259Mártire, Ana Paula; Fenoy, Gonzalo Eduardo; Azzaroni, Omar; Rafti, Matias; Marmisollé, Waldemar Alejandro; Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes; Royal Society of Chemistry; RSC Applied Interfaces; 1; 3; 2-2024; 511-5212755-3701CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=D3LF00236Einfo:eu-repo/semantics/altIdentifier/doi/10.1039/D3LF00236Einfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:43:39Zoai:ri.conicet.gov.ar:11336/262259instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:43:39.712CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes
title Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes
spellingShingle Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes
Mártire, Ana Paula
Ferrocene
Conducting Polymers
Supercapacitors
nanoarchitectonics
title_short Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes
title_full Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes
title_fullStr Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes
title_full_unstemmed Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes
title_sort Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes
dc.creator.none.fl_str_mv Mártire, Ana Paula
Fenoy, Gonzalo Eduardo
Azzaroni, Omar
Rafti, Matias
Marmisollé, Waldemar Alejandro
author Mártire, Ana Paula
author_facet Mártire, Ana Paula
Fenoy, Gonzalo Eduardo
Azzaroni, Omar
Rafti, Matias
Marmisollé, Waldemar Alejandro
author_role author
author2 Fenoy, Gonzalo Eduardo
Azzaroni, Omar
Rafti, Matias
Marmisollé, Waldemar Alejandro
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ferrocene
Conducting Polymers
Supercapacitors
nanoarchitectonics
topic Ferrocene
Conducting Polymers
Supercapacitors
nanoarchitectonics
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Supercapacitors are devices that bridge the gap between traditional capacitors and rechargeable batteries, offering exceptional energy storage capabilities, rapid charge/discharge rates, long cycle life, and environmental friendliness. This study explores the development of neutral-aqueous supercapacitor materials using conductive polymers, with a focus on polyaniline (PANI) doped with anionic polyelectrolytes. Combining PANI with carbon nanomaterials through various construction processes, including layer-by-layer assembly, nanoarchitectonics is employed to create desirable nanostructures on the electrode surface. The introduction of a redox-active surfactant (ferrocene-labelled surfactant, FcCTAB) in the layer-by-layer assembly adds a unique dimension of redox activity, enhancing the electrochemical capacitance of the hybrid coatings. Through voltammetric, charge–discharge, and electrochemical quartz crystal microbalance (EQCM) measurements, we investigate the capacitive performance and dynamic mass changes during potential cycling. The study demonstrates that the integration of the redox moiety significantly improves capacitive performance in neutral solutions without compromising structural stability and cyclability. This approach synergistically combines nanocarbon materials, electroactive polymers, and the faradaic contribution of the electroactive surfactant, presenting a supercapacitor material with excellent performance with potential application in wearable devices for secure energy storage.
Fil: Mártire, Ana Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Fenoy, Gonzalo Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Rafti, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Marmisollé, Waldemar Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
description Supercapacitors are devices that bridge the gap between traditional capacitors and rechargeable batteries, offering exceptional energy storage capabilities, rapid charge/discharge rates, long cycle life, and environmental friendliness. This study explores the development of neutral-aqueous supercapacitor materials using conductive polymers, with a focus on polyaniline (PANI) doped with anionic polyelectrolytes. Combining PANI with carbon nanomaterials through various construction processes, including layer-by-layer assembly, nanoarchitectonics is employed to create desirable nanostructures on the electrode surface. The introduction of a redox-active surfactant (ferrocene-labelled surfactant, FcCTAB) in the layer-by-layer assembly adds a unique dimension of redox activity, enhancing the electrochemical capacitance of the hybrid coatings. Through voltammetric, charge–discharge, and electrochemical quartz crystal microbalance (EQCM) measurements, we investigate the capacitive performance and dynamic mass changes during potential cycling. The study demonstrates that the integration of the redox moiety significantly improves capacitive performance in neutral solutions without compromising structural stability and cyclability. This approach synergistically combines nanocarbon materials, electroactive polymers, and the faradaic contribution of the electroactive surfactant, presenting a supercapacitor material with excellent performance with potential application in wearable devices for secure energy storage.
publishDate 2024
dc.date.none.fl_str_mv 2024-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/262259
Mártire, Ana Paula; Fenoy, Gonzalo Eduardo; Azzaroni, Omar; Rafti, Matias; Marmisollé, Waldemar Alejandro; Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes; Royal Society of Chemistry; RSC Applied Interfaces; 1; 3; 2-2024; 511-521
2755-3701
CONICET Digital
CONICET
url http://hdl.handle.net/11336/262259
identifier_str_mv Mártire, Ana Paula; Fenoy, Gonzalo Eduardo; Azzaroni, Omar; Rafti, Matias; Marmisollé, Waldemar Alejandro; Ferrocene-labelled surfactants enhance the supercapacitor performance in PANI-PSS/nanocarbon layer-by-layer nanoarchitectonics electrodes; Royal Society of Chemistry; RSC Applied Interfaces; 1; 3; 2-2024; 511-521
2755-3701
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=D3LF00236E
info:eu-repo/semantics/altIdentifier/doi/10.1039/D3LF00236E
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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