Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospher...
- Autores
- Mussari, Lelia María Ester; Canzonieri, Salvador Humberto; Mariano, Alejandra Beatríz
- Año de publicación
- 2017
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Surface tension and density were measured for the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K. Meditions were done using mechanical oscillation densimetry and falling drop tensiometry. Densities and surface tensions increases as it grows the carbonated chain of the methyl esters and decreases as temperature increases. Experimental data were satisfactory fitted by the polynomial equation of Redlich-Kister. Adsorption isotherm of Gibbs was applied to estimate the relative adsorption of each ester respect to toluene. The modified group contribution model of UNIFAC was using to estimate the activity coefficients of the components. Positive values of the relative adsorption showed that there was a great accumulation of ester molecules on the surface of the dissolution respect to the fluid?s sine.
Fil: Mussari, Lelia María Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería. Universidad Nacional del Comahue. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería; Argentina
Fil: Canzonieri, Salvador Humberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería. Universidad Nacional del Comahue. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería; Argentina
Fil: Mariano, Alejandra Beatríz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería. Universidad Nacional del Comahue. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería; Argentina - Materia
-
SURFACE TENSION
DENSITY
FALLING DROP TENSIOMETRY
AROMATIC HYDROCARBONS
ESTERS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/111126
Ver los metadatos del registro completo
id |
CONICETDig_d978034251e7af01e5d3e128224857b6 |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/111126 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 KMussari, Lelia María EsterCanzonieri, Salvador HumbertoMariano, Alejandra BeatrízSURFACE TENSIONDENSITYFALLING DROP TENSIOMETRYAROMATIC HYDROCARBONSESTERShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Surface tension and density were measured for the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K. Meditions were done using mechanical oscillation densimetry and falling drop tensiometry. Densities and surface tensions increases as it grows the carbonated chain of the methyl esters and decreases as temperature increases. Experimental data were satisfactory fitted by the polynomial equation of Redlich-Kister. Adsorption isotherm of Gibbs was applied to estimate the relative adsorption of each ester respect to toluene. The modified group contribution model of UNIFAC was using to estimate the activity coefficients of the components. Positive values of the relative adsorption showed that there was a great accumulation of ester molecules on the surface of the dissolution respect to the fluid?s sine. Fil: Mussari, Lelia María Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería. Universidad Nacional del Comahue. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería; ArgentinaFil: Canzonieri, Salvador Humberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería. Universidad Nacional del Comahue. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería; ArgentinaFil: Mariano, Alejandra Beatríz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería. Universidad Nacional del Comahue. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería; ArgentinaElsevier2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/111126Mussari, Lelia María Ester; Canzonieri, Salvador Humberto; Mariano, Alejandra Beatríz; Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K; Elsevier; Chemical Data Collections; 9-10; 2017; 125-1332405-8300CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cdc.2017.05.001info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S2405830016300891?via%3Dihubinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:37Zoai:ri.conicet.gov.ar:11336/111126instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:37.647CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K |
title |
Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K |
spellingShingle |
Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K Mussari, Lelia María Ester SURFACE TENSION DENSITY FALLING DROP TENSIOMETRY AROMATIC HYDROCARBONS ESTERS |
title_short |
Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K |
title_full |
Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K |
title_fullStr |
Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K |
title_full_unstemmed |
Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K |
title_sort |
Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K |
dc.creator.none.fl_str_mv |
Mussari, Lelia María Ester Canzonieri, Salvador Humberto Mariano, Alejandra Beatríz |
author |
Mussari, Lelia María Ester |
author_facet |
Mussari, Lelia María Ester Canzonieri, Salvador Humberto Mariano, Alejandra Beatríz |
author_role |
author |
author2 |
Canzonieri, Salvador Humberto Mariano, Alejandra Beatríz |
author2_role |
author author |
dc.subject.none.fl_str_mv |
SURFACE TENSION DENSITY FALLING DROP TENSIOMETRY AROMATIC HYDROCARBONS ESTERS |
topic |
SURFACE TENSION DENSITY FALLING DROP TENSIOMETRY AROMATIC HYDROCARBONS ESTERS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Surface tension and density were measured for the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K. Meditions were done using mechanical oscillation densimetry and falling drop tensiometry. Densities and surface tensions increases as it grows the carbonated chain of the methyl esters and decreases as temperature increases. Experimental data were satisfactory fitted by the polynomial equation of Redlich-Kister. Adsorption isotherm of Gibbs was applied to estimate the relative adsorption of each ester respect to toluene. The modified group contribution model of UNIFAC was using to estimate the activity coefficients of the components. Positive values of the relative adsorption showed that there was a great accumulation of ester molecules on the surface of the dissolution respect to the fluid?s sine. Fil: Mussari, Lelia María Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería. Universidad Nacional del Comahue. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería; Argentina Fil: Canzonieri, Salvador Humberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería. Universidad Nacional del Comahue. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería; Argentina Fil: Mariano, Alejandra Beatríz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería. Universidad Nacional del Comahue. Instituto de Investigación En Tecnologías y Ciencias de la Ingeniería; Argentina |
description |
Surface tension and density were measured for the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K. Meditions were done using mechanical oscillation densimetry and falling drop tensiometry. Densities and surface tensions increases as it grows the carbonated chain of the methyl esters and decreases as temperature increases. Experimental data were satisfactory fitted by the polynomial equation of Redlich-Kister. Adsorption isotherm of Gibbs was applied to estimate the relative adsorption of each ester respect to toluene. The modified group contribution model of UNIFAC was using to estimate the activity coefficients of the components. Positive values of the relative adsorption showed that there was a great accumulation of ester molecules on the surface of the dissolution respect to the fluid?s sine. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/111126 Mussari, Lelia María Ester; Canzonieri, Salvador Humberto; Mariano, Alejandra Beatríz; Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K; Elsevier; Chemical Data Collections; 9-10; 2017; 125-133 2405-8300 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/111126 |
identifier_str_mv |
Mussari, Lelia María Ester; Canzonieri, Salvador Humberto; Mariano, Alejandra Beatríz; Surface tension and density of the binary mixtures toluene + methyl propanoate, toluene + methyl pentanoate, toluene + methyl heptanoate and toluene + methyl octanoate at atmospheric pressure and 288.15, 298.15 and 308.15 K; Elsevier; Chemical Data Collections; 9-10; 2017; 125-133 2405-8300 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cdc.2017.05.001 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S2405830016300891?via%3Dihub |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613034128965632 |
score |
13.070432 |