Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K

Autores
Mariano, Alejandra Beatríz; Mussari, Lelia María Ester; Camacho, Alberto Gustavo; Canzonieri, Salvador Humberto; Postigo, Miguel Angel
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Density, speed of sound and viscosity for the ternary system formed by toluene, benzene and methyl acetate and their corresponding binaries were measured at atmospheric pressure in the temperature range of 288.15 K to 318.15 K, every 5 K. Experimental data were used to calculate derived properties: excess molar volume, isentropic compressibility, isentropic compressibility deviation, viscosity deviation and excess free energy of activation for viscous flow. These magnitudes were fitted to different equations available in the literature. In addition, geometrical models have been used to predict ternary magnitudes. Predictions of viscosities for the ternary system were performed by group contribution models. Molecular interactions among the components of the mixtures were inferred from the sign of the excess and deviation properties.
Fil: Mariano, Alejandra Beatríz. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mussari, Lelia María Ester. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Química; Argentina
Fil: Camacho, Alberto Gustavo. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Química; Argentina
Fil: Canzonieri, Salvador Humberto. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Física; Argentina
Fil: Postigo, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Density
Viscosity
Speed of Sound
Toluene
Benzene
Esters
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/17627
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 KMariano, Alejandra BeatrízMussari, Lelia María EsterCamacho, Alberto GustavoCanzonieri, Salvador HumbertoPostigo, Miguel AngelDensityViscositySpeed of SoundTolueneBenzeneEstershttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Density, speed of sound and viscosity for the ternary system formed by toluene, benzene and methyl acetate and their corresponding binaries were measured at atmospheric pressure in the temperature range of 288.15 K to 318.15 K, every 5 K. Experimental data were used to calculate derived properties: excess molar volume, isentropic compressibility, isentropic compressibility deviation, viscosity deviation and excess free energy of activation for viscous flow. These magnitudes were fitted to different equations available in the literature. In addition, geometrical models have been used to predict ternary magnitudes. Predictions of viscosities for the ternary system were performed by group contribution models. Molecular interactions among the components of the mixtures were inferred from the sign of the excess and deviation properties.Fil: Mariano, Alejandra Beatríz. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Mussari, Lelia María Ester. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Química; ArgentinaFil: Camacho, Alberto Gustavo. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Química; ArgentinaFil: Canzonieri, Salvador Humberto. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Física; ArgentinaFil: Postigo, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaTaylor & Francis2013-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/17627Mariano, Alejandra Beatríz; Mussari, Lelia María Ester; Camacho, Alberto Gustavo; Canzonieri, Salvador Humberto; Postigo, Miguel Angel; Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K; Taylor & Francis; Physics And Chemistry Of Liquids; 51; 6; 7-2013; 731-7410031-9104enginfo:eu-repo/semantics/altIdentifier/doi/10.1080/00319104.2013.812018info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/abs/10.1080/00319104.2013.812018info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:00:00Zoai:ri.conicet.gov.ar:11336/17627instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:00:00.447CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K
title Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K
spellingShingle Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K
Mariano, Alejandra Beatríz
Density
Viscosity
Speed of Sound
Toluene
Benzene
Esters
title_short Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K
title_full Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K
title_fullStr Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K
title_full_unstemmed Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K
title_sort Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K
dc.creator.none.fl_str_mv Mariano, Alejandra Beatríz
Mussari, Lelia María Ester
Camacho, Alberto Gustavo
Canzonieri, Salvador Humberto
Postigo, Miguel Angel
author Mariano, Alejandra Beatríz
author_facet Mariano, Alejandra Beatríz
Mussari, Lelia María Ester
Camacho, Alberto Gustavo
Canzonieri, Salvador Humberto
Postigo, Miguel Angel
author_role author
author2 Mussari, Lelia María Ester
Camacho, Alberto Gustavo
Canzonieri, Salvador Humberto
Postigo, Miguel Angel
author2_role author
author
author
author
dc.subject.none.fl_str_mv Density
Viscosity
Speed of Sound
Toluene
Benzene
Esters
topic Density
Viscosity
Speed of Sound
Toluene
Benzene
Esters
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Density, speed of sound and viscosity for the ternary system formed by toluene, benzene and methyl acetate and their corresponding binaries were measured at atmospheric pressure in the temperature range of 288.15 K to 318.15 K, every 5 K. Experimental data were used to calculate derived properties: excess molar volume, isentropic compressibility, isentropic compressibility deviation, viscosity deviation and excess free energy of activation for viscous flow. These magnitudes were fitted to different equations available in the literature. In addition, geometrical models have been used to predict ternary magnitudes. Predictions of viscosities for the ternary system were performed by group contribution models. Molecular interactions among the components of the mixtures were inferred from the sign of the excess and deviation properties.
Fil: Mariano, Alejandra Beatríz. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mussari, Lelia María Ester. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Química; Argentina
Fil: Camacho, Alberto Gustavo. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Química; Argentina
Fil: Canzonieri, Salvador Humberto. Universidad Nacional del Comahue. Facultad de Ingeniería. Departamento de Física; Argentina
Fil: Postigo, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Density, speed of sound and viscosity for the ternary system formed by toluene, benzene and methyl acetate and their corresponding binaries were measured at atmospheric pressure in the temperature range of 288.15 K to 318.15 K, every 5 K. Experimental data were used to calculate derived properties: excess molar volume, isentropic compressibility, isentropic compressibility deviation, viscosity deviation and excess free energy of activation for viscous flow. These magnitudes were fitted to different equations available in the literature. In addition, geometrical models have been used to predict ternary magnitudes. Predictions of viscosities for the ternary system were performed by group contribution models. Molecular interactions among the components of the mixtures were inferred from the sign of the excess and deviation properties.
publishDate 2013
dc.date.none.fl_str_mv 2013-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/17627
Mariano, Alejandra Beatríz; Mussari, Lelia María Ester; Camacho, Alberto Gustavo; Canzonieri, Salvador Humberto; Postigo, Miguel Angel; Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K; Taylor & Francis; Physics And Chemistry Of Liquids; 51; 6; 7-2013; 731-741
0031-9104
url http://hdl.handle.net/11336/17627
identifier_str_mv Mariano, Alejandra Beatríz; Mussari, Lelia María Ester; Camacho, Alberto Gustavo; Canzonieri, Salvador Humberto; Postigo, Miguel Angel; Thermophysical properties for the ternary systems toluene (1) + benzene (2) + methyl acetate (3), at various temperatures from 288.15 K to 318.15 K; Taylor & Francis; Physics And Chemistry Of Liquids; 51; 6; 7-2013; 731-741
0031-9104
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1080/00319104.2013.812018
info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/abs/10.1080/00319104.2013.812018
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083138960228352
score 13.22299

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