Metsulfuron-methyl determination in environmental samples by solid surface fluorescence

Autores
Alesso, Magdalena; Almeida, César Américo; Talio, María Carolina; Fernandez, Liliana Patricia
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A new environmental friendly methodology for metsulfuron-methyl quantification based on the fluorescent signal enhancement of rhodamine B dye has been developed. A cationic surfactant (cetyltrimethylammonium bromide, CTAB) and an anionic one (sodium dodecylsulfate) were employed to preconcentrate the herbicide using a coacervation phenomenon, in sodium borate buffer medium (pH 9.2). The coacervate phase was collected on a nylon membrane (0.45 μm) and the solid surface fluorescence signal was determined (λexc = 515 nm, λem = 565 nm). Experimental variables that influence on preconcentration step and fluorimetric sensitivity have been studied and optimized using response surface methodology. Under optimal working conditions, a LOD of 0.17 μg L−1 and a LOQ 0.53 μg L−1 was obtained. The zeroth order regression calibration was linear from 0.53 to 5.00 μg L−1. The method showed adequate sensitivity and selectivity, and was applied to the determination of trace amounts of metsulfuron-methyl in environmental water samples. The proposed methodology implies an alternative to traditional techniques for metsulfuron-methyl monitoring using an accessible instrument in control laboratories, representing a contribution in the toxicological and environmental areas for the monitoring of MSM in environmental samples, in agreement with the Green Chemistry.
Fil: Alesso, Magdalena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Almeida, César Américo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Talio, María Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Fernandez, Liliana Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Materia
FLUORESCENCE
HERBICIDE
METSULFURON-METHYL
SOLID PHASE EXTRACTION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/87351
Acceder
id CONICETDig_d6063eb123a43cda89577f939ff5a86a
oai_identifier_str oai:ri.conicet.gov.ar:11336/87351
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Metsulfuron-methyl determination in environmental samples by solid surface fluorescenceAlesso, MagdalenaAlmeida, César AméricoTalio, María CarolinaFernandez, Liliana PatriciaFLUORESCENCEHERBICIDEMETSULFURON-METHYLSOLID PHASE EXTRACTIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A new environmental friendly methodology for metsulfuron-methyl quantification based on the fluorescent signal enhancement of rhodamine B dye has been developed. A cationic surfactant (cetyltrimethylammonium bromide, CTAB) and an anionic one (sodium dodecylsulfate) were employed to preconcentrate the herbicide using a coacervation phenomenon, in sodium borate buffer medium (pH 9.2). The coacervate phase was collected on a nylon membrane (0.45 μm) and the solid surface fluorescence signal was determined (λexc = 515 nm, λem = 565 nm). Experimental variables that influence on preconcentration step and fluorimetric sensitivity have been studied and optimized using response surface methodology. Under optimal working conditions, a LOD of 0.17 μg L−1 and a LOQ 0.53 μg L−1 was obtained. The zeroth order regression calibration was linear from 0.53 to 5.00 μg L−1. The method showed adequate sensitivity and selectivity, and was applied to the determination of trace amounts of metsulfuron-methyl in environmental water samples. The proposed methodology implies an alternative to traditional techniques for metsulfuron-methyl monitoring using an accessible instrument in control laboratories, representing a contribution in the toxicological and environmental areas for the monitoring of MSM in environmental samples, in agreement with the Green Chemistry.Fil: Alesso, Magdalena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Almeida, César Américo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Talio, María Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Fernandez, Liliana Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaElsevier Science2018-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/87351Alesso, Magdalena; Almeida, César Américo; Talio, María Carolina; Fernandez, Liliana Patricia; Metsulfuron-methyl determination in environmental samples by solid surface fluorescence; Elsevier Science; Microchemical Journal; 139; 6-2018; 150-1540026-265XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X17313024info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2018.02.023info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:51Zoai:ri.conicet.gov.ar:11336/87351instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:51.726CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Metsulfuron-methyl determination in environmental samples by solid surface fluorescence
title Metsulfuron-methyl determination in environmental samples by solid surface fluorescence
spellingShingle Metsulfuron-methyl determination in environmental samples by solid surface fluorescence
Alesso, Magdalena
FLUORESCENCE
HERBICIDE
METSULFURON-METHYL
SOLID PHASE EXTRACTION
title_short Metsulfuron-methyl determination in environmental samples by solid surface fluorescence
title_full Metsulfuron-methyl determination in environmental samples by solid surface fluorescence
title_fullStr Metsulfuron-methyl determination in environmental samples by solid surface fluorescence
title_full_unstemmed Metsulfuron-methyl determination in environmental samples by solid surface fluorescence
title_sort Metsulfuron-methyl determination in environmental samples by solid surface fluorescence
dc.creator.none.fl_str_mv Alesso, Magdalena
Almeida, César Américo
Talio, María Carolina
Fernandez, Liliana Patricia
author Alesso, Magdalena
author_facet Alesso, Magdalena
Almeida, César Américo
Talio, María Carolina
Fernandez, Liliana Patricia
author_role author
author2 Almeida, César Américo
Talio, María Carolina
Fernandez, Liliana Patricia
author2_role author
author
author
dc.subject.none.fl_str_mv FLUORESCENCE
HERBICIDE
METSULFURON-METHYL
SOLID PHASE EXTRACTION
topic FLUORESCENCE
HERBICIDE
METSULFURON-METHYL
SOLID PHASE EXTRACTION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A new environmental friendly methodology for metsulfuron-methyl quantification based on the fluorescent signal enhancement of rhodamine B dye has been developed. A cationic surfactant (cetyltrimethylammonium bromide, CTAB) and an anionic one (sodium dodecylsulfate) were employed to preconcentrate the herbicide using a coacervation phenomenon, in sodium borate buffer medium (pH 9.2). The coacervate phase was collected on a nylon membrane (0.45 μm) and the solid surface fluorescence signal was determined (λexc = 515 nm, λem = 565 nm). Experimental variables that influence on preconcentration step and fluorimetric sensitivity have been studied and optimized using response surface methodology. Under optimal working conditions, a LOD of 0.17 μg L−1 and a LOQ 0.53 μg L−1 was obtained. The zeroth order regression calibration was linear from 0.53 to 5.00 μg L−1. The method showed adequate sensitivity and selectivity, and was applied to the determination of trace amounts of metsulfuron-methyl in environmental water samples. The proposed methodology implies an alternative to traditional techniques for metsulfuron-methyl monitoring using an accessible instrument in control laboratories, representing a contribution in the toxicological and environmental areas for the monitoring of MSM in environmental samples, in agreement with the Green Chemistry.
Fil: Alesso, Magdalena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Almeida, César Américo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Talio, María Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Fernandez, Liliana Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
description A new environmental friendly methodology for metsulfuron-methyl quantification based on the fluorescent signal enhancement of rhodamine B dye has been developed. A cationic surfactant (cetyltrimethylammonium bromide, CTAB) and an anionic one (sodium dodecylsulfate) were employed to preconcentrate the herbicide using a coacervation phenomenon, in sodium borate buffer medium (pH 9.2). The coacervate phase was collected on a nylon membrane (0.45 μm) and the solid surface fluorescence signal was determined (λexc = 515 nm, λem = 565 nm). Experimental variables that influence on preconcentration step and fluorimetric sensitivity have been studied and optimized using response surface methodology. Under optimal working conditions, a LOD of 0.17 μg L−1 and a LOQ 0.53 μg L−1 was obtained. The zeroth order regression calibration was linear from 0.53 to 5.00 μg L−1. The method showed adequate sensitivity and selectivity, and was applied to the determination of trace amounts of metsulfuron-methyl in environmental water samples. The proposed methodology implies an alternative to traditional techniques for metsulfuron-methyl monitoring using an accessible instrument in control laboratories, representing a contribution in the toxicological and environmental areas for the monitoring of MSM in environmental samples, in agreement with the Green Chemistry.
publishDate 2018
dc.date.none.fl_str_mv 2018-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/87351
Alesso, Magdalena; Almeida, César Américo; Talio, María Carolina; Fernandez, Liliana Patricia; Metsulfuron-methyl determination in environmental samples by solid surface fluorescence; Elsevier Science; Microchemical Journal; 139; 6-2018; 150-154
0026-265X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/87351
identifier_str_mv Alesso, Magdalena; Almeida, César Américo; Talio, María Carolina; Fernandez, Liliana Patricia; Metsulfuron-methyl determination in environmental samples by solid surface fluorescence; Elsevier Science; Microchemical Journal; 139; 6-2018; 150-154
0026-265X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X17313024
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2018.02.023
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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