Morphology and structure of ABS membranes filled with two different activated carbons

Autores
Marchese, Jose; Anson, M.; Ochoa, Nelio Ariel; Prádanos, P.; Palacio, L.; Hernández, A.
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Mixed matrix-composite membranes (MMCM) for gas separation are prepared and characterized in this work. Acrylonitrile-butadiene-styrene (ABS) copolymer was used for the continuum phase of the membrane filled with two different activated carbons (AC). The so-obtained membranes have been characterized by gas permeability, optical microscopy, electronic microscopy and atomic force microscopy. The membranes have different roughness on both their surfaces but are always recovered by the polymeric material. Better ABS-AC adhesion has been always reached giving high selectivity and permeability for CO2 / CH4. Such intimate contact can be attributed to the rubber properties of the butadiene-styrene chains in ABS. The morphological characteristics and the increase in both permeability and selectivity with the volume fraction of the filler are explained in terms of the properties of pure activated carbons.
Fil: Marchese, Jose. Universidad Nacional de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina
Fil: Anson, M.. Universidad Nacional de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina
Fil: Ochoa, Nelio Ariel. Universidad Nacional de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina
Fil: Prádanos, P.. Universidad de Valladolid; España
Fil: Palacio, L.. Universidad de Valladolid; España
Fil: Hernández, A.. Universidad de Valladolid; España
Materia
ACTIVATED CARBON
GAS SEPARATION
MEMBRANE CHARACTERIZATION
MEMBRANE MATERIALS
MIXED MATRIX-COMPOSITE MEMBRANES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/214001
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Morphology and structure of ABS membranes filled with two different activated carbonsMarchese, JoseAnson, M.Ochoa, Nelio ArielPrádanos, P.Palacio, L.Hernández, A.ACTIVATED CARBONGAS SEPARATIONMEMBRANE CHARACTERIZATIONMEMBRANE MATERIALSMIXED MATRIX-COMPOSITE MEMBRANEShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Mixed matrix-composite membranes (MMCM) for gas separation are prepared and characterized in this work. Acrylonitrile-butadiene-styrene (ABS) copolymer was used for the continuum phase of the membrane filled with two different activated carbons (AC). The so-obtained membranes have been characterized by gas permeability, optical microscopy, electronic microscopy and atomic force microscopy. The membranes have different roughness on both their surfaces but are always recovered by the polymeric material. Better ABS-AC adhesion has been always reached giving high selectivity and permeability for CO2 / CH4. Such intimate contact can be attributed to the rubber properties of the butadiene-styrene chains in ABS. The morphological characteristics and the increase in both permeability and selectivity with the volume fraction of the filler are explained in terms of the properties of pure activated carbons.Fil: Marchese, Jose. Universidad Nacional de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; ArgentinaFil: Anson, M.. Universidad Nacional de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; ArgentinaFil: Ochoa, Nelio Ariel. Universidad Nacional de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; ArgentinaFil: Prádanos, P.. Universidad de Valladolid; EspañaFil: Palacio, L.. Universidad de Valladolid; EspañaFil: Hernández, A.. Universidad de Valladolid; EspañaPergamon-Elsevier Science Ltd2006-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/214001Marchese, Jose; Anson, M.; Ochoa, Nelio Ariel; Prádanos, P.; Palacio, L.; et al.; Morphology and structure of ABS membranes filled with two different activated carbons; Pergamon-Elsevier Science Ltd; Chemical Engineering Science; 61; 16; 12-2006; 5448-54540009-2509CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009250906002727info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2006.04.013info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:01:02Zoai:ri.conicet.gov.ar:11336/214001instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:01:03.06CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Morphology and structure of ABS membranes filled with two different activated carbons
title Morphology and structure of ABS membranes filled with two different activated carbons
spellingShingle Morphology and structure of ABS membranes filled with two different activated carbons
Marchese, Jose
ACTIVATED CARBON
GAS SEPARATION
MEMBRANE CHARACTERIZATION
MEMBRANE MATERIALS
MIXED MATRIX-COMPOSITE MEMBRANES
title_short Morphology and structure of ABS membranes filled with two different activated carbons
title_full Morphology and structure of ABS membranes filled with two different activated carbons
title_fullStr Morphology and structure of ABS membranes filled with two different activated carbons
title_full_unstemmed Morphology and structure of ABS membranes filled with two different activated carbons
title_sort Morphology and structure of ABS membranes filled with two different activated carbons
dc.creator.none.fl_str_mv Marchese, Jose
Anson, M.
Ochoa, Nelio Ariel
Prádanos, P.
Palacio, L.
Hernández, A.
author Marchese, Jose
author_facet Marchese, Jose
Anson, M.
Ochoa, Nelio Ariel
Prádanos, P.
Palacio, L.
Hernández, A.
author_role author
author2 Anson, M.
Ochoa, Nelio Ariel
Prádanos, P.
Palacio, L.
Hernández, A.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv ACTIVATED CARBON
GAS SEPARATION
MEMBRANE CHARACTERIZATION
MEMBRANE MATERIALS
MIXED MATRIX-COMPOSITE MEMBRANES
topic ACTIVATED CARBON
GAS SEPARATION
MEMBRANE CHARACTERIZATION
MEMBRANE MATERIALS
MIXED MATRIX-COMPOSITE MEMBRANES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Mixed matrix-composite membranes (MMCM) for gas separation are prepared and characterized in this work. Acrylonitrile-butadiene-styrene (ABS) copolymer was used for the continuum phase of the membrane filled with two different activated carbons (AC). The so-obtained membranes have been characterized by gas permeability, optical microscopy, electronic microscopy and atomic force microscopy. The membranes have different roughness on both their surfaces but are always recovered by the polymeric material. Better ABS-AC adhesion has been always reached giving high selectivity and permeability for CO2 / CH4. Such intimate contact can be attributed to the rubber properties of the butadiene-styrene chains in ABS. The morphological characteristics and the increase in both permeability and selectivity with the volume fraction of the filler are explained in terms of the properties of pure activated carbons.
Fil: Marchese, Jose. Universidad Nacional de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina
Fil: Anson, M.. Universidad Nacional de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina
Fil: Ochoa, Nelio Ariel. Universidad Nacional de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina
Fil: Prádanos, P.. Universidad de Valladolid; España
Fil: Palacio, L.. Universidad de Valladolid; España
Fil: Hernández, A.. Universidad de Valladolid; España
description Mixed matrix-composite membranes (MMCM) for gas separation are prepared and characterized in this work. Acrylonitrile-butadiene-styrene (ABS) copolymer was used for the continuum phase of the membrane filled with two different activated carbons (AC). The so-obtained membranes have been characterized by gas permeability, optical microscopy, electronic microscopy and atomic force microscopy. The membranes have different roughness on both their surfaces but are always recovered by the polymeric material. Better ABS-AC adhesion has been always reached giving high selectivity and permeability for CO2 / CH4. Such intimate contact can be attributed to the rubber properties of the butadiene-styrene chains in ABS. The morphological characteristics and the increase in both permeability and selectivity with the volume fraction of the filler are explained in terms of the properties of pure activated carbons.
publishDate 2006
dc.date.none.fl_str_mv 2006-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/214001
Marchese, Jose; Anson, M.; Ochoa, Nelio Ariel; Prádanos, P.; Palacio, L.; et al.; Morphology and structure of ABS membranes filled with two different activated carbons; Pergamon-Elsevier Science Ltd; Chemical Engineering Science; 61; 16; 12-2006; 5448-5454
0009-2509
CONICET Digital
CONICET
url http://hdl.handle.net/11336/214001
identifier_str_mv Marchese, Jose; Anson, M.; Ochoa, Nelio Ariel; Prádanos, P.; Palacio, L.; et al.; Morphology and structure of ABS membranes filled with two different activated carbons; Pergamon-Elsevier Science Ltd; Chemical Engineering Science; 61; 16; 12-2006; 5448-5454
0009-2509
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009250906002727
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2006.04.013
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.48226

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