Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation

Autores
Hosseinzadeh Hejazi, S.A.; Avila, Adolfo María; Kuznicki, T.M.; Weizhu, A.; Kuznicki, S.M.
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Natural zeolite membranes can be used as a model for the development of robust molecular sieve membranes with superior separation characteristics. We describe the characterization of natural clinoptilolite membranes made from dense mineral deposits by single gas H2 and CO2 permeation. Permeability values as a function of temperature and pressure were analyzed on the basis of mass transport fundamentals of gas permeation through zeolite and nonzeolite pathways. H2 and CO2 fluxes through the membranes were fitted with a model based on a combination of zeolitic, Knudsen, and viscous transports so that the selective and nonselective flux fractions could be quantified. An increase in feed pressure increased the total permeance especially at low temperatures. The membranes were also characterized by XRD, SEM, and EDX analysis.
Fil: Hosseinzadeh Hejazi, S.A.. University of Alberta; Canadá
Fil: Avila, Adolfo María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Kuznicki, T.M.. University of Alberta; Canadá
Fil: Weizhu, A.. University of Alberta; Canadá
Fil: Kuznicki, S.M.. University of Alberta; Canadá
Materia
Membrane
Hydrogen
Zeolite
Gas Separation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/53048
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeationHosseinzadeh Hejazi, S.A.Avila, Adolfo MaríaKuznicki, T.M.Weizhu, A.Kuznicki, S.M.MembraneHydrogenZeoliteGas Separationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Natural zeolite membranes can be used as a model for the development of robust molecular sieve membranes with superior separation characteristics. We describe the characterization of natural clinoptilolite membranes made from dense mineral deposits by single gas H2 and CO2 permeation. Permeability values as a function of temperature and pressure were analyzed on the basis of mass transport fundamentals of gas permeation through zeolite and nonzeolite pathways. H2 and CO2 fluxes through the membranes were fitted with a model based on a combination of zeolitic, Knudsen, and viscous transports so that the selective and nonselective flux fractions could be quantified. An increase in feed pressure increased the total permeance especially at low temperatures. The membranes were also characterized by XRD, SEM, and EDX analysis.Fil: Hosseinzadeh Hejazi, S.A.. University of Alberta; CanadáFil: Avila, Adolfo María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Kuznicki, T.M.. University of Alberta; CanadáFil: Weizhu, A.. University of Alberta; CanadáFil: Kuznicki, S.M.. University of Alberta; CanadáAmerican Chemical Society2011-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/53048Hosseinzadeh Hejazi, S.A.; Avila, Adolfo María; Kuznicki, T.M.; Weizhu, A.; Kuznicki, S.M.; Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation; American Chemical Society; Industrial & Engineering Chemical Research; 50; 11-2011; 12717-127260888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie200529ninfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:52:44Zoai:ri.conicet.gov.ar:11336/53048instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:52:44.719CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation
title Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation
spellingShingle Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation
Hosseinzadeh Hejazi, S.A.
Membrane
Hydrogen
Zeolite
Gas Separation
title_short Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation
title_full Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation
title_fullStr Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation
title_full_unstemmed Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation
title_sort Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation
dc.creator.none.fl_str_mv Hosseinzadeh Hejazi, S.A.
Avila, Adolfo María
Kuznicki, T.M.
Weizhu, A.
Kuznicki, S.M.
author Hosseinzadeh Hejazi, S.A.
author_facet Hosseinzadeh Hejazi, S.A.
Avila, Adolfo María
Kuznicki, T.M.
Weizhu, A.
Kuznicki, S.M.
author_role author
author2 Avila, Adolfo María
Kuznicki, T.M.
Weizhu, A.
Kuznicki, S.M.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Membrane
Hydrogen
Zeolite
Gas Separation
topic Membrane
Hydrogen
Zeolite
Gas Separation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Natural zeolite membranes can be used as a model for the development of robust molecular sieve membranes with superior separation characteristics. We describe the characterization of natural clinoptilolite membranes made from dense mineral deposits by single gas H2 and CO2 permeation. Permeability values as a function of temperature and pressure were analyzed on the basis of mass transport fundamentals of gas permeation through zeolite and nonzeolite pathways. H2 and CO2 fluxes through the membranes were fitted with a model based on a combination of zeolitic, Knudsen, and viscous transports so that the selective and nonselective flux fractions could be quantified. An increase in feed pressure increased the total permeance especially at low temperatures. The membranes were also characterized by XRD, SEM, and EDX analysis.
Fil: Hosseinzadeh Hejazi, S.A.. University of Alberta; Canadá
Fil: Avila, Adolfo María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Kuznicki, T.M.. University of Alberta; Canadá
Fil: Weizhu, A.. University of Alberta; Canadá
Fil: Kuznicki, S.M.. University of Alberta; Canadá
description Natural zeolite membranes can be used as a model for the development of robust molecular sieve membranes with superior separation characteristics. We describe the characterization of natural clinoptilolite membranes made from dense mineral deposits by single gas H2 and CO2 permeation. Permeability values as a function of temperature and pressure were analyzed on the basis of mass transport fundamentals of gas permeation through zeolite and nonzeolite pathways. H2 and CO2 fluxes through the membranes were fitted with a model based on a combination of zeolitic, Knudsen, and viscous transports so that the selective and nonselective flux fractions could be quantified. An increase in feed pressure increased the total permeance especially at low temperatures. The membranes were also characterized by XRD, SEM, and EDX analysis.
publishDate 2011
dc.date.none.fl_str_mv 2011-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/53048
Hosseinzadeh Hejazi, S.A.; Avila, Adolfo María; Kuznicki, T.M.; Weizhu, A.; Kuznicki, S.M.; Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation; American Chemical Society; Industrial & Engineering Chemical Research; 50; 11-2011; 12717-12726
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/53048
identifier_str_mv Hosseinzadeh Hejazi, S.A.; Avila, Adolfo María; Kuznicki, T.M.; Weizhu, A.; Kuznicki, S.M.; Characterization of natural zeolite membranes for H2/CO2 separations by single gas permeation; American Chemical Society; Industrial & Engineering Chemical Research; 50; 11-2011; 12717-12726
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ie200529n
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083056531668992
score 13.22299

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