Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions

Autores
Ferrari, Sergio; Grinblat, Florencia; Bilovol, Vitaliy; Pampillo, Laura Gabriela; Saccone, Fabio Daniel; Errandonea, D.; Chanquia, Corina Mercedes
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We have successfully synthesized for the first time a Ti-doped ZrSiO4 powder (stoichiometry Zr0.95Ti0.05SiO4) via a sol–gel route. The structural and vibrational properties have been characterized by X-ray diffraction, electron microscopy and Raman spectroscopy. Zr0.95Ti0.05SiO4 has a tetragonal zircon-type structure with a = 6.5981(2) Å and c = 5.9810(2) Å. Eight of its Raman-active modes have been measured and assigned. We also performed high-pressure synchrotron X-ray diffraction experiments. The structural behavior was studied up to 31 GPa. At this pressure, we found evidence of the onset of a phase transition, coexisting the low-pressure polymorphs (zircon) with the typical high-pressure polymorph of ZrSiO4 (reidite-type). From the analysis of unit-cell volume versus pressure using a Birch–Murnaghan equation of state, in the quasi-hydrostatic pressure regime (P < 10.5 GPa), we have determined a bulk modulus of 297 GPa. This magnitude represents an enhancement of a 30% in the value of this parameter if compared with un-doped zircon-type ZrSiO4 (bulk modulus < 227 GPa). The low compressibility of Zr0.95Ti0.05SiO4 converts this compound in a very good candidate for many technological applications. The effect of pressure on the linear compressibility of the lattice parameters is also analyzed.
Fil: Ferrari, Sergio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Grinblat, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Bilovol, Vitaliy. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Pampillo, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Saccone, Fabio Daniel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Errandonea, D.. Universidad de Valencia; España
Fil: Chanquia, Corina Mercedes. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Materia
HIGH PRESSURE
ZIRCON
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acceso abierto
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https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
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CONICET Digital (CONICET)
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Consejo Nacional de Investigaciones Científicas y Técnicas
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oai:ri.conicet.gov.ar:11336/88309
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditionsFerrari, SergioGrinblat, FlorenciaBilovol, VitaliyPampillo, Laura GabrielaSaccone, Fabio DanielErrandonea, D.Chanquia, Corina MercedesHIGH PRESSUREZIRCONhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2We have successfully synthesized for the first time a Ti-doped ZrSiO4 powder (stoichiometry Zr0.95Ti0.05SiO4) via a sol–gel route. The structural and vibrational properties have been characterized by X-ray diffraction, electron microscopy and Raman spectroscopy. Zr0.95Ti0.05SiO4 has a tetragonal zircon-type structure with a = 6.5981(2) Å and c = 5.9810(2) Å. Eight of its Raman-active modes have been measured and assigned. We also performed high-pressure synchrotron X-ray diffraction experiments. The structural behavior was studied up to 31 GPa. At this pressure, we found evidence of the onset of a phase transition, coexisting the low-pressure polymorphs (zircon) with the typical high-pressure polymorph of ZrSiO4 (reidite-type). From the analysis of unit-cell volume versus pressure using a Birch–Murnaghan equation of state, in the quasi-hydrostatic pressure regime (P < 10.5 GPa), we have determined a bulk modulus of 297 GPa. This magnitude represents an enhancement of a 30% in the value of this parameter if compared with un-doped zircon-type ZrSiO4 (bulk modulus < 227 GPa). The low compressibility of Zr0.95Ti0.05SiO4 converts this compound in a very good candidate for many technological applications. The effect of pressure on the linear compressibility of the lattice parameters is also analyzed.Fil: Ferrari, Sergio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaFil: Grinblat, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaFil: Bilovol, Vitaliy. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaFil: Pampillo, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaFil: Saccone, Fabio Daniel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Errandonea, D.. Universidad de Valencia; EspañaFil: Chanquia, Corina Mercedes. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaSpringer2018-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/88309Ferrari, Sergio; Grinblat, Florencia; Bilovol, Vitaliy; Pampillo, Laura Gabriela; Saccone, Fabio Daniel; et al.; Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions; Springer; Journal of Materials Science; 53; 12; 6-2018; 8817-88250022-2461CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10853-018-2170-2info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/nag.2748info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-01-14T12:05:04Zoai:ri.conicet.gov.ar:11336/88309instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-01-14 12:05:04.248CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions
title Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions
spellingShingle Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions
Ferrari, Sergio
HIGH PRESSURE
ZIRCON
title_short Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions
title_full Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions
title_fullStr Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions
title_full_unstemmed Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions
title_sort Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions
dc.creator.none.fl_str_mv Ferrari, Sergio
Grinblat, Florencia
Bilovol, Vitaliy
Pampillo, Laura Gabriela
Saccone, Fabio Daniel
Errandonea, D.
Chanquia, Corina Mercedes
author Ferrari, Sergio
author_facet Ferrari, Sergio
Grinblat, Florencia
Bilovol, Vitaliy
Pampillo, Laura Gabriela
Saccone, Fabio Daniel
Errandonea, D.
Chanquia, Corina Mercedes
author_role author
author2 Grinblat, Florencia
Bilovol, Vitaliy
Pampillo, Laura Gabriela
Saccone, Fabio Daniel
Errandonea, D.
Chanquia, Corina Mercedes
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv HIGH PRESSURE
ZIRCON
topic HIGH PRESSURE
ZIRCON
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv We have successfully synthesized for the first time a Ti-doped ZrSiO4 powder (stoichiometry Zr0.95Ti0.05SiO4) via a sol–gel route. The structural and vibrational properties have been characterized by X-ray diffraction, electron microscopy and Raman spectroscopy. Zr0.95Ti0.05SiO4 has a tetragonal zircon-type structure with a = 6.5981(2) Å and c = 5.9810(2) Å. Eight of its Raman-active modes have been measured and assigned. We also performed high-pressure synchrotron X-ray diffraction experiments. The structural behavior was studied up to 31 GPa. At this pressure, we found evidence of the onset of a phase transition, coexisting the low-pressure polymorphs (zircon) with the typical high-pressure polymorph of ZrSiO4 (reidite-type). From the analysis of unit-cell volume versus pressure using a Birch–Murnaghan equation of state, in the quasi-hydrostatic pressure regime (P < 10.5 GPa), we have determined a bulk modulus of 297 GPa. This magnitude represents an enhancement of a 30% in the value of this parameter if compared with un-doped zircon-type ZrSiO4 (bulk modulus < 227 GPa). The low compressibility of Zr0.95Ti0.05SiO4 converts this compound in a very good candidate for many technological applications. The effect of pressure on the linear compressibility of the lattice parameters is also analyzed.
Fil: Ferrari, Sergio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Grinblat, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Bilovol, Vitaliy. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Pampillo, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Saccone, Fabio Daniel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Errandonea, D.. Universidad de Valencia; España
Fil: Chanquia, Corina Mercedes. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
description We have successfully synthesized for the first time a Ti-doped ZrSiO4 powder (stoichiometry Zr0.95Ti0.05SiO4) via a sol–gel route. The structural and vibrational properties have been characterized by X-ray diffraction, electron microscopy and Raman spectroscopy. Zr0.95Ti0.05SiO4 has a tetragonal zircon-type structure with a = 6.5981(2) Å and c = 5.9810(2) Å. Eight of its Raman-active modes have been measured and assigned. We also performed high-pressure synchrotron X-ray diffraction experiments. The structural behavior was studied up to 31 GPa. At this pressure, we found evidence of the onset of a phase transition, coexisting the low-pressure polymorphs (zircon) with the typical high-pressure polymorph of ZrSiO4 (reidite-type). From the analysis of unit-cell volume versus pressure using a Birch–Murnaghan equation of state, in the quasi-hydrostatic pressure regime (P < 10.5 GPa), we have determined a bulk modulus of 297 GPa. This magnitude represents an enhancement of a 30% in the value of this parameter if compared with un-doped zircon-type ZrSiO4 (bulk modulus < 227 GPa). The low compressibility of Zr0.95Ti0.05SiO4 converts this compound in a very good candidate for many technological applications. The effect of pressure on the linear compressibility of the lattice parameters is also analyzed.
publishDate 2018
dc.date.none.fl_str_mv 2018-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/88309
Ferrari, Sergio; Grinblat, Florencia; Bilovol, Vitaliy; Pampillo, Laura Gabriela; Saccone, Fabio Daniel; et al.; Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions; Springer; Journal of Materials Science; 53; 12; 6-2018; 8817-8825
0022-2461
CONICET Digital
CONICET
url http://hdl.handle.net/11336/88309
identifier_str_mv Ferrari, Sergio; Grinblat, Florencia; Bilovol, Vitaliy; Pampillo, Laura Gabriela; Saccone, Fabio Daniel; et al.; Synthesis and characterization of Ti-doped ZrSiO4 at ambient and high-pressure conditions; Springer; Journal of Materials Science; 53; 12; 6-2018; 8817-8825
0022-2461
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
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info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/nag.2748
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
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dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
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reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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