Synthesis and characterization of a Zinc(II) complex of bispicen
- Autores
- Parajón Costa, Beatriz Susana; Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Baran, Enrique José
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The synthesis of a Zn(II) complex of bispicen, the tetradentate ligand N,N′-bis(2-pyridylmethyl)- ethylenediamine, of composition [Zn(bispicen)Cl(H2O)]2[ZnCl4] is reported. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2=c with Z =4 molecules per unit cell. The Zn(II) cation in the [Zn(bispicen)Cl(H2O)]+ complex is in a distorted octahedral environment, coordinated to a neutral bispicen molecule acting as a tetradentate ligand through its two amine nitrogen atoms, at cis positions, and its two pyridyl N atoms, at trans positions. The six-fold coordination is completed by a chloride ion and a water molecule. The tetrahedral [ZnCl4]2- counter-ion lies on a crystallographic twofold axis. The complex was further characterized by FTIR spectroscopy, and its vibrational behavior compared with that of the dihydrated tetrahydrochloride of free bispicen.
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Echeverría, Gustavo Alberto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Piro, Oscar Enrique. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina - Materia
-
Zn(Ii)-Bispicen Complex
Crystal Structure
Ftir Spectra - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/23574
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Synthesis and characterization of a Zinc(II) complex of bispicenParajón Costa, Beatriz SusanaEcheverría, Gustavo AlbertoPiro, Oscar EnriqueBaran, Enrique JoséZn(Ii)-Bispicen ComplexCrystal StructureFtir Spectrahttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The synthesis of a Zn(II) complex of bispicen, the tetradentate ligand N,N′-bis(2-pyridylmethyl)- ethylenediamine, of composition [Zn(bispicen)Cl(H2O)]2[ZnCl4] is reported. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2=c with Z =4 molecules per unit cell. The Zn(II) cation in the [Zn(bispicen)Cl(H2O)]+ complex is in a distorted octahedral environment, coordinated to a neutral bispicen molecule acting as a tetradentate ligand through its two amine nitrogen atoms, at cis positions, and its two pyridyl N atoms, at trans positions. The six-fold coordination is completed by a chloride ion and a water molecule. The tetrahedral [ZnCl4]2- counter-ion lies on a crystallographic twofold axis. The complex was further characterized by FTIR spectroscopy, and its vibrational behavior compared with that of the dihydrated tetrahydrochloride of free bispicen.Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Echeverría, Gustavo Alberto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Piro, Oscar Enrique. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaDe Gruyter2013-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/23574Parajón Costa, Beatriz Susana; Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Baran, Enrique José; Synthesis and characterization of a Zinc(II) complex of bispicen; De Gruyter; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 68; 12; 12-2013; 1327-13320932-07761865-7117CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.5560/znb.2013-3193info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/znb.2013.68.issue-12/znb.2013-3193/znb.2013-3193.xmlinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:16:45Zoai:ri.conicet.gov.ar:11336/23574instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:16:45.705CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Synthesis and characterization of a Zinc(II) complex of bispicen |
title |
Synthesis and characterization of a Zinc(II) complex of bispicen |
spellingShingle |
Synthesis and characterization of a Zinc(II) complex of bispicen Parajón Costa, Beatriz Susana Zn(Ii)-Bispicen Complex Crystal Structure Ftir Spectra |
title_short |
Synthesis and characterization of a Zinc(II) complex of bispicen |
title_full |
Synthesis and characterization of a Zinc(II) complex of bispicen |
title_fullStr |
Synthesis and characterization of a Zinc(II) complex of bispicen |
title_full_unstemmed |
Synthesis and characterization of a Zinc(II) complex of bispicen |
title_sort |
Synthesis and characterization of a Zinc(II) complex of bispicen |
dc.creator.none.fl_str_mv |
Parajón Costa, Beatriz Susana Echeverría, Gustavo Alberto Piro, Oscar Enrique Baran, Enrique José |
author |
Parajón Costa, Beatriz Susana |
author_facet |
Parajón Costa, Beatriz Susana Echeverría, Gustavo Alberto Piro, Oscar Enrique Baran, Enrique José |
author_role |
author |
author2 |
Echeverría, Gustavo Alberto Piro, Oscar Enrique Baran, Enrique José |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Zn(Ii)-Bispicen Complex Crystal Structure Ftir Spectra |
topic |
Zn(Ii)-Bispicen Complex Crystal Structure Ftir Spectra |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The synthesis of a Zn(II) complex of bispicen, the tetradentate ligand N,N′-bis(2-pyridylmethyl)- ethylenediamine, of composition [Zn(bispicen)Cl(H2O)]2[ZnCl4] is reported. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2=c with Z =4 molecules per unit cell. The Zn(II) cation in the [Zn(bispicen)Cl(H2O)]+ complex is in a distorted octahedral environment, coordinated to a neutral bispicen molecule acting as a tetradentate ligand through its two amine nitrogen atoms, at cis positions, and its two pyridyl N atoms, at trans positions. The six-fold coordination is completed by a chloride ion and a water molecule. The tetrahedral [ZnCl4]2- counter-ion lies on a crystallographic twofold axis. The complex was further characterized by FTIR spectroscopy, and its vibrational behavior compared with that of the dihydrated tetrahydrochloride of free bispicen. Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina Fil: Echeverría, Gustavo Alberto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina Fil: Piro, Oscar Enrique. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina |
description |
The synthesis of a Zn(II) complex of bispicen, the tetradentate ligand N,N′-bis(2-pyridylmethyl)- ethylenediamine, of composition [Zn(bispicen)Cl(H2O)]2[ZnCl4] is reported. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2=c with Z =4 molecules per unit cell. The Zn(II) cation in the [Zn(bispicen)Cl(H2O)]+ complex is in a distorted octahedral environment, coordinated to a neutral bispicen molecule acting as a tetradentate ligand through its two amine nitrogen atoms, at cis positions, and its two pyridyl N atoms, at trans positions. The six-fold coordination is completed by a chloride ion and a water molecule. The tetrahedral [ZnCl4]2- counter-ion lies on a crystallographic twofold axis. The complex was further characterized by FTIR spectroscopy, and its vibrational behavior compared with that of the dihydrated tetrahydrochloride of free bispicen. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/23574 Parajón Costa, Beatriz Susana; Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Baran, Enrique José; Synthesis and characterization of a Zinc(II) complex of bispicen; De Gruyter; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 68; 12; 12-2013; 1327-1332 0932-0776 1865-7117 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/23574 |
identifier_str_mv |
Parajón Costa, Beatriz Susana; Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Baran, Enrique José; Synthesis and characterization of a Zinc(II) complex of bispicen; De Gruyter; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 68; 12; 12-2013; 1327-1332 0932-0776 1865-7117 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.5560/znb.2013-3193 info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/znb.2013.68.issue-12/znb.2013-3193/znb.2013-3193.xml |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
De Gruyter |
publisher.none.fl_str_mv |
De Gruyter |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614114642493440 |
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13.070432 |