Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands

Autores
Martínez, Miguel A.; De Jiménez, María C.L.; Castellano, Eduardo E.; Piro, Oscar Enrique; Aymonino, Pedro Jose
Año de publicación
2003
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The reaction of lapachol, 2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphtoquinone, C15H 14O3, with zinc acetate, in ethanol, produces a chelate formula Zn(C15H13O3)2(C 2H6O)2, whose structure has been determined by single crystal X-ray diffraction. It pertains to the triclinic system, space group P 1̄ (No. 2), a = 8.2380(3) Å, b = 9.4900(2) Å, c = 11.0110(4) Å, α = 112.536(2)°, β = 91.204(2)°, γ = 92.664(2)°, Z = 1. Some spectroscopic and chemical properties of the complex are also reported.
Fil: Martínez, Miguel A.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; Argentina
Fil: De Jiménez, María C.L.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; Argentina
Fil: Castellano, Eduardo E.. Universidade de Sao Paulo; Brasil
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Aymonino, Pedro Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Materia
Ethanol
Lapacholate
Properties
Structure
Zn(Ii) Complex
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/72355
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligandsMartínez, Miguel A.De Jiménez, María C.L.Castellano, Eduardo E.Piro, Oscar EnriqueAymonino, Pedro JoseEthanolLapacholatePropertiesStructureZn(Ii) Complexhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The reaction of lapachol, 2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphtoquinone, C15H 14O3, with zinc acetate, in ethanol, produces a chelate formula Zn(C15H13O3)2(C 2H6O)2, whose structure has been determined by single crystal X-ray diffraction. It pertains to the triclinic system, space group P 1̄ (No. 2), a = 8.2380(3) Å, b = 9.4900(2) Å, c = 11.0110(4) Å, α = 112.536(2)°, β = 91.204(2)°, γ = 92.664(2)°, Z = 1. Some spectroscopic and chemical properties of the complex are also reported.Fil: Martínez, Miguel A.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; ArgentinaFil: De Jiménez, María C.L.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; ArgentinaFil: Castellano, Eduardo E.. Universidade de Sao Paulo; BrasilFil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Aymonino, Pedro Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; ArgentinaTaylor & Francis Ltd2003-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/72355Martínez, Miguel A.; De Jiménez, María C.L.; Castellano, Eduardo E.; Piro, Oscar Enrique; Aymonino, Pedro Jose; Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands; Taylor & Francis Ltd; Journal of Coordination Chemistry; 56; 9; 6-2003; 803-8160095-8972CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1080/0095897031000113959info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/0095897031000113959info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:10:01Zoai:ri.conicet.gov.ar:11336/72355instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:10:01.71CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands
title Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands
spellingShingle Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands
Martínez, Miguel A.
Ethanol
Lapacholate
Properties
Structure
Zn(Ii) Complex
title_short Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands
title_full Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands
title_fullStr Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands
title_full_unstemmed Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands
title_sort Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands
dc.creator.none.fl_str_mv Martínez, Miguel A.
De Jiménez, María C.L.
Castellano, Eduardo E.
Piro, Oscar Enrique
Aymonino, Pedro Jose
author Martínez, Miguel A.
author_facet Martínez, Miguel A.
De Jiménez, María C.L.
Castellano, Eduardo E.
Piro, Oscar Enrique
Aymonino, Pedro Jose
author_role author
author2 De Jiménez, María C.L.
Castellano, Eduardo E.
Piro, Oscar Enrique
Aymonino, Pedro Jose
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ethanol
Lapacholate
Properties
Structure
Zn(Ii) Complex
topic Ethanol
Lapacholate
Properties
Structure
Zn(Ii) Complex
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The reaction of lapachol, 2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphtoquinone, C15H 14O3, with zinc acetate, in ethanol, produces a chelate formula Zn(C15H13O3)2(C 2H6O)2, whose structure has been determined by single crystal X-ray diffraction. It pertains to the triclinic system, space group P 1̄ (No. 2), a = 8.2380(3) Å, b = 9.4900(2) Å, c = 11.0110(4) Å, α = 112.536(2)°, β = 91.204(2)°, γ = 92.664(2)°, Z = 1. Some spectroscopic and chemical properties of the complex are also reported.
Fil: Martínez, Miguel A.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; Argentina
Fil: De Jiménez, María C.L.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; Argentina
Fil: Castellano, Eduardo E.. Universidade de Sao Paulo; Brasil
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Aymonino, Pedro Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
description The reaction of lapachol, 2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphtoquinone, C15H 14O3, with zinc acetate, in ethanol, produces a chelate formula Zn(C15H13O3)2(C 2H6O)2, whose structure has been determined by single crystal X-ray diffraction. It pertains to the triclinic system, space group P 1̄ (No. 2), a = 8.2380(3) Å, b = 9.4900(2) Å, c = 11.0110(4) Å, α = 112.536(2)°, β = 91.204(2)°, γ = 92.664(2)°, Z = 1. Some spectroscopic and chemical properties of the complex are also reported.
publishDate 2003
dc.date.none.fl_str_mv 2003-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/72355
Martínez, Miguel A.; De Jiménez, María C.L.; Castellano, Eduardo E.; Piro, Oscar Enrique; Aymonino, Pedro Jose; Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands; Taylor & Francis Ltd; Journal of Coordination Chemistry; 56; 9; 6-2003; 803-816
0095-8972
CONICET Digital
CONICET
url http://hdl.handle.net/11336/72355
identifier_str_mv Martínez, Miguel A.; De Jiménez, María C.L.; Castellano, Eduardo E.; Piro, Oscar Enrique; Aymonino, Pedro Jose; Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands; Taylor & Francis Ltd; Journal of Coordination Chemistry; 56; 9; 6-2003; 803-816
0095-8972
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1080/0095897031000113959
info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/0095897031000113959
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis Ltd
publisher.none.fl_str_mv Taylor & Francis Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781456522674176
score 12.982451

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