Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands
- Autores
- Martínez, Miguel A.; De Jiménez, María C.L.; Castellano, Eduardo E.; Piro, Oscar Enrique; Aymonino, Pedro Jose
- Año de publicación
- 2003
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The reaction of lapachol, 2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphtoquinone, C15H 14O3, with zinc acetate, in ethanol, produces a chelate formula Zn(C15H13O3)2(C 2H6O)2, whose structure has been determined by single crystal X-ray diffraction. It pertains to the triclinic system, space group P 1̄ (No. 2), a = 8.2380(3) Å, b = 9.4900(2) Å, c = 11.0110(4) Å, α = 112.536(2)°, β = 91.204(2)°, γ = 92.664(2)°, Z = 1. Some spectroscopic and chemical properties of the complex are also reported.
Fil: Martínez, Miguel A.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; Argentina
Fil: De Jiménez, María C.L.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; Argentina
Fil: Castellano, Eduardo E.. Universidade de Sao Paulo; Brasil
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Aymonino, Pedro Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina - Materia
-
Ethanol
Lapacholate
Properties
Structure
Zn(Ii) Complex - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/72355
Ver los metadatos del registro completo
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Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligandsMartínez, Miguel A.De Jiménez, María C.L.Castellano, Eduardo E.Piro, Oscar EnriqueAymonino, Pedro JoseEthanolLapacholatePropertiesStructureZn(Ii) Complexhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The reaction of lapachol, 2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphtoquinone, C15H 14O3, with zinc acetate, in ethanol, produces a chelate formula Zn(C15H13O3)2(C 2H6O)2, whose structure has been determined by single crystal X-ray diffraction. It pertains to the triclinic system, space group P 1̄ (No. 2), a = 8.2380(3) Å, b = 9.4900(2) Å, c = 11.0110(4) Å, α = 112.536(2)°, β = 91.204(2)°, γ = 92.664(2)°, Z = 1. Some spectroscopic and chemical properties of the complex are also reported.Fil: Martínez, Miguel A.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; ArgentinaFil: De Jiménez, María C.L.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; ArgentinaFil: Castellano, Eduardo E.. Universidade de Sao Paulo; BrasilFil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Aymonino, Pedro Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; ArgentinaTaylor & Francis Ltd2003-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/72355Martínez, Miguel A.; De Jiménez, María C.L.; Castellano, Eduardo E.; Piro, Oscar Enrique; Aymonino, Pedro Jose; Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands; Taylor & Francis Ltd; Journal of Coordination Chemistry; 56; 9; 6-2003; 803-8160095-8972CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1080/0095897031000113959info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/0095897031000113959info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:26Zoai:ri.conicet.gov.ar:11336/72355instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:26.633CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands |
title |
Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands |
spellingShingle |
Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands Martínez, Miguel A. Ethanol Lapacholate Properties Structure Zn(Ii) Complex |
title_short |
Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands |
title_full |
Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands |
title_fullStr |
Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands |
title_full_unstemmed |
Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands |
title_sort |
Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands |
dc.creator.none.fl_str_mv |
Martínez, Miguel A. De Jiménez, María C.L. Castellano, Eduardo E. Piro, Oscar Enrique Aymonino, Pedro Jose |
author |
Martínez, Miguel A. |
author_facet |
Martínez, Miguel A. De Jiménez, María C.L. Castellano, Eduardo E. Piro, Oscar Enrique Aymonino, Pedro Jose |
author_role |
author |
author2 |
De Jiménez, María C.L. Castellano, Eduardo E. Piro, Oscar Enrique Aymonino, Pedro Jose |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Ethanol Lapacholate Properties Structure Zn(Ii) Complex |
topic |
Ethanol Lapacholate Properties Structure Zn(Ii) Complex |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The reaction of lapachol, 2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphtoquinone, C15H 14O3, with zinc acetate, in ethanol, produces a chelate formula Zn(C15H13O3)2(C 2H6O)2, whose structure has been determined by single crystal X-ray diffraction. It pertains to the triclinic system, space group P 1̄ (No. 2), a = 8.2380(3) Å, b = 9.4900(2) Å, c = 11.0110(4) Å, α = 112.536(2)°, β = 91.204(2)°, γ = 92.664(2)°, Z = 1. Some spectroscopic and chemical properties of the complex are also reported. Fil: Martínez, Miguel A.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; Argentina Fil: De Jiménez, María C.L.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia; Argentina Fil: Castellano, Eduardo E.. Universidade de Sao Paulo; Brasil Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina Fil: Aymonino, Pedro Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina |
description |
The reaction of lapachol, 2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphtoquinone, C15H 14O3, with zinc acetate, in ethanol, produces a chelate formula Zn(C15H13O3)2(C 2H6O)2, whose structure has been determined by single crystal X-ray diffraction. It pertains to the triclinic system, space group P 1̄ (No. 2), a = 8.2380(3) Å, b = 9.4900(2) Å, c = 11.0110(4) Å, α = 112.536(2)°, β = 91.204(2)°, γ = 92.664(2)°, Z = 1. Some spectroscopic and chemical properties of the complex are also reported. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/72355 Martínez, Miguel A.; De Jiménez, María C.L.; Castellano, Eduardo E.; Piro, Oscar Enrique; Aymonino, Pedro Jose; Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands; Taylor & Francis Ltd; Journal of Coordination Chemistry; 56; 9; 6-2003; 803-816 0095-8972 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/72355 |
identifier_str_mv |
Martínez, Miguel A.; De Jiménez, María C.L.; Castellano, Eduardo E.; Piro, Oscar Enrique; Aymonino, Pedro Jose; Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands; Taylor & Francis Ltd; Journal of Coordination Chemistry; 56; 9; 6-2003; 803-816 0095-8972 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1080/0095897031000113959 info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/0095897031000113959 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Taylor & Francis Ltd |
publisher.none.fl_str_mv |
Taylor & Francis Ltd |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613309291036672 |
score |
13.070432 |