A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions

Autores
D'alessandro, Oriana; Sathicq, Angel Gabriel; Sambeth, Jorge Enrique; Thomas, Horacio Jorge; Romanelli, Gustavo Pablo
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this communication, four materials (CeO2,CeO2(Cu), MnOx, and MnOx(Cu)) were prepared, characterized and tested as catalysts, in solvent-free conditions, for the multicomponent Hantzsch reactions to obtain alternatively the 1,4-dihydropyridine or 2-phenylpyridine depending on the reaction conditions. 1,4-Dihydropyridine 4 was the main product formed at 80 °C (76%), and 2-phenylpyridine7 was the main product at 40 °C (91%), inoxidant-free conditions, CeO2 catalyst. It is the first report that shows that, not only the temperature but also the nature of the catalyst may change the product selectivity in Hantzsch reactions.
Fil: D'alessandro, Oriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Thomas, Horacio Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Materia
Cerium And Manganese Oxides
Hantzsch Reaction
1,4-Dihydropyridine
2-Phenylpyridine
Green Chemistry
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/8305
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/8305
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditionsD'alessandro, OrianaSathicq, Angel GabrielSambeth, Jorge EnriqueThomas, Horacio JorgeRomanelli, Gustavo PabloCerium And Manganese OxidesHantzsch Reaction1,4-Dihydropyridine2-PhenylpyridineGreen Chemistryhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this communication, four materials (CeO2,CeO2(Cu), MnOx, and MnOx(Cu)) were prepared, characterized and tested as catalysts, in solvent-free conditions, for the multicomponent Hantzsch reactions to obtain alternatively the 1,4-dihydropyridine or 2-phenylpyridine depending on the reaction conditions. 1,4-Dihydropyridine 4 was the main product formed at 80 °C (76%), and 2-phenylpyridine7 was the main product at 40 °C (91%), inoxidant-free conditions, CeO2 catalyst. It is the first report that shows that, not only the temperature but also the nature of the catalyst may change the product selectivity in Hantzsch reactions.Fil: D'alessandro, Oriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Thomas, Horacio Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaElsevier2014-11-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/8305D'alessandro, Oriana; Sathicq, Angel Gabriel; Sambeth, Jorge Enrique; Thomas, Horacio Jorge; Romanelli, Gustavo Pablo; A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions; Elsevier; Catalysis Communications; 60; 21-11-2014; 65-691566-7367enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2014.11.022info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1566736714004750info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:12:13Zoai:ri.conicet.gov.ar:11336/8305instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:12:13.536CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions
title A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions
spellingShingle A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions
D'alessandro, Oriana
Cerium And Manganese Oxides
Hantzsch Reaction
1,4-Dihydropyridine
2-Phenylpyridine
Green Chemistry
title_short A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions
title_full A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions
title_fullStr A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions
title_full_unstemmed A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions
title_sort A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions
dc.creator.none.fl_str_mv D'alessandro, Oriana
Sathicq, Angel Gabriel
Sambeth, Jorge Enrique
Thomas, Horacio Jorge
Romanelli, Gustavo Pablo
author D'alessandro, Oriana
author_facet D'alessandro, Oriana
Sathicq, Angel Gabriel
Sambeth, Jorge Enrique
Thomas, Horacio Jorge
Romanelli, Gustavo Pablo
author_role author
author2 Sathicq, Angel Gabriel
Sambeth, Jorge Enrique
Thomas, Horacio Jorge
Romanelli, Gustavo Pablo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Cerium And Manganese Oxides
Hantzsch Reaction
1,4-Dihydropyridine
2-Phenylpyridine
Green Chemistry
topic Cerium And Manganese Oxides
Hantzsch Reaction
1,4-Dihydropyridine
2-Phenylpyridine
Green Chemistry
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this communication, four materials (CeO2,CeO2(Cu), MnOx, and MnOx(Cu)) were prepared, characterized and tested as catalysts, in solvent-free conditions, for the multicomponent Hantzsch reactions to obtain alternatively the 1,4-dihydropyridine or 2-phenylpyridine depending on the reaction conditions. 1,4-Dihydropyridine 4 was the main product formed at 80 °C (76%), and 2-phenylpyridine7 was the main product at 40 °C (91%), inoxidant-free conditions, CeO2 catalyst. It is the first report that shows that, not only the temperature but also the nature of the catalyst may change the product selectivity in Hantzsch reactions.
Fil: D'alessandro, Oriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Thomas, Horacio Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
description In this communication, four materials (CeO2,CeO2(Cu), MnOx, and MnOx(Cu)) were prepared, characterized and tested as catalysts, in solvent-free conditions, for the multicomponent Hantzsch reactions to obtain alternatively the 1,4-dihydropyridine or 2-phenylpyridine depending on the reaction conditions. 1,4-Dihydropyridine 4 was the main product formed at 80 °C (76%), and 2-phenylpyridine7 was the main product at 40 °C (91%), inoxidant-free conditions, CeO2 catalyst. It is the first report that shows that, not only the temperature but also the nature of the catalyst may change the product selectivity in Hantzsch reactions.
publishDate 2014
dc.date.none.fl_str_mv 2014-11-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/8305
D'alessandro, Oriana; Sathicq, Angel Gabriel; Sambeth, Jorge Enrique; Thomas, Horacio Jorge; Romanelli, Gustavo Pablo; A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions; Elsevier; Catalysis Communications; 60; 21-11-2014; 65-69
1566-7367
url http://hdl.handle.net/11336/8305
identifier_str_mv D'alessandro, Oriana; Sathicq, Angel Gabriel; Sambeth, Jorge Enrique; Thomas, Horacio Jorge; Romanelli, Gustavo Pablo; A study of the temperature effect on Hantzsch reaction selectivity using Mn and Ce oxides under solvent-free conditions; Elsevier; Catalysis Communications; 60; 21-11-2014; 65-69
1566-7367
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2014.11.022
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1566736714004750
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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