Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction

Autores
Poggio Fraccari, Eduardo Arístides; D'alessandro, Oriana; Sambeth, Jorge Enrique; Baronetti, Graciela Teresita; Mariño, Fernando Javier
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Cerium-manganese mixed oxides with different composition were prepared by co-precipitation, characterized and evaluated for the water–gas shift (WGS) reaction. Base metal (5 wt.% Cu and 5 wt.% Ni) catalysts supported on Ce–Mn mixed oxides were also tested for the WGS reaction. The activity of the bare supports is higher in the mixed samples than in pure ceria or manganese oxide. This result can be explained by a combination of greater reducibility and surface area in the mixed samples. Addition of base metals produces superior WGS catalysts. Particularly, nickel catalysts tested are able to reduce typical CO concentrations entering the WGS process to the CO levels tolerated by phosphoric acid fuel cells in a single unit operated at 400 °C.
Fil: Poggio Fraccari, Eduardo Arístides. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Ingenieria Quimica. Laboratorio de Procesos Cataliticos; Argentina
Fil: D'alessandro, Oriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Baronetti, Graciela Teresita. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Ingenieria Quimica. Laboratorio de Procesos Cataliticos; Argentina
Fil: Mariño, Fernando Javier. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Ingenieria Quimica. Laboratorio de Procesos Cataliticos; Argentina
Materia
Watergas Shift Reaction
Copper
Nickel
Cerium
Manganese
Fuel Cells
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5266
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reactionPoggio Fraccari, Eduardo ArístidesD'alessandro, OrianaSambeth, Jorge EnriqueBaronetti, Graciela TeresitaMariño, Fernando JavierWatergas Shift ReactionCopperNickelCeriumManganeseFuel Cellshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Cerium-manganese mixed oxides with different composition were prepared by co-precipitation, characterized and evaluated for the water–gas shift (WGS) reaction. Base metal (5 wt.% Cu and 5 wt.% Ni) catalysts supported on Ce–Mn mixed oxides were also tested for the WGS reaction. The activity of the bare supports is higher in the mixed samples than in pure ceria or manganese oxide. This result can be explained by a combination of greater reducibility and surface area in the mixed samples. Addition of base metals produces superior WGS catalysts. Particularly, nickel catalysts tested are able to reduce typical CO concentrations entering the WGS process to the CO levels tolerated by phosphoric acid fuel cells in a single unit operated at 400 °C.Fil: Poggio Fraccari, Eduardo Arístides. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Ingenieria Quimica. Laboratorio de Procesos Cataliticos; ArgentinaFil: D'alessandro, Oriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Baronetti, Graciela Teresita. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Ingenieria Quimica. Laboratorio de Procesos Cataliticos; ArgentinaFil: Mariño, Fernando Javier. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Ingenieria Quimica. Laboratorio de Procesos Cataliticos; ArgentinaElsevier2014-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5266Poggio Fraccari, Eduardo Arístides; D'alessandro, Oriana; Sambeth, Jorge Enrique; Baronetti, Graciela Teresita; Mariño, Fernando Javier; Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction; Elsevier; Fuel Processing Technology; 119; 3-2014; 67-730378-3820enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378382013003263info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuproc.2013.10.012info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:39:51Zoai:ri.conicet.gov.ar:11336/5266instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:39:51.672CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction
title Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction
spellingShingle Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction
Poggio Fraccari, Eduardo Arístides
Watergas Shift Reaction
Copper
Nickel
Cerium
Manganese
Fuel Cells
title_short Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction
title_full Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction
title_fullStr Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction
title_full_unstemmed Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction
title_sort Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction
dc.creator.none.fl_str_mv Poggio Fraccari, Eduardo Arístides
D'alessandro, Oriana
Sambeth, Jorge Enrique
Baronetti, Graciela Teresita
Mariño, Fernando Javier
author Poggio Fraccari, Eduardo Arístides
author_facet Poggio Fraccari, Eduardo Arístides
D'alessandro, Oriana
Sambeth, Jorge Enrique
Baronetti, Graciela Teresita
Mariño, Fernando Javier
author_role author
author2 D'alessandro, Oriana
Sambeth, Jorge Enrique
Baronetti, Graciela Teresita
Mariño, Fernando Javier
author2_role author
author
author
author
dc.subject.none.fl_str_mv Watergas Shift Reaction
Copper
Nickel
Cerium
Manganese
Fuel Cells
topic Watergas Shift Reaction
Copper
Nickel
Cerium
Manganese
Fuel Cells
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Cerium-manganese mixed oxides with different composition were prepared by co-precipitation, characterized and evaluated for the water–gas shift (WGS) reaction. Base metal (5 wt.% Cu and 5 wt.% Ni) catalysts supported on Ce–Mn mixed oxides were also tested for the WGS reaction. The activity of the bare supports is higher in the mixed samples than in pure ceria or manganese oxide. This result can be explained by a combination of greater reducibility and surface area in the mixed samples. Addition of base metals produces superior WGS catalysts. Particularly, nickel catalysts tested are able to reduce typical CO concentrations entering the WGS process to the CO levels tolerated by phosphoric acid fuel cells in a single unit operated at 400 °C.
Fil: Poggio Fraccari, Eduardo Arístides. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Ingenieria Quimica. Laboratorio de Procesos Cataliticos; Argentina
Fil: D'alessandro, Oriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Baronetti, Graciela Teresita. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Ingenieria Quimica. Laboratorio de Procesos Cataliticos; Argentina
Fil: Mariño, Fernando Javier. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Ingenieria Quimica. Laboratorio de Procesos Cataliticos; Argentina
description Cerium-manganese mixed oxides with different composition were prepared by co-precipitation, characterized and evaluated for the water–gas shift (WGS) reaction. Base metal (5 wt.% Cu and 5 wt.% Ni) catalysts supported on Ce–Mn mixed oxides were also tested for the WGS reaction. The activity of the bare supports is higher in the mixed samples than in pure ceria or manganese oxide. This result can be explained by a combination of greater reducibility and surface area in the mixed samples. Addition of base metals produces superior WGS catalysts. Particularly, nickel catalysts tested are able to reduce typical CO concentrations entering the WGS process to the CO levels tolerated by phosphoric acid fuel cells in a single unit operated at 400 °C.
publishDate 2014
dc.date.none.fl_str_mv 2014-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5266
Poggio Fraccari, Eduardo Arístides; D'alessandro, Oriana; Sambeth, Jorge Enrique; Baronetti, Graciela Teresita; Mariño, Fernando Javier; Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction; Elsevier; Fuel Processing Technology; 119; 3-2014; 67-73
0378-3820
url http://hdl.handle.net/11336/5266
identifier_str_mv Poggio Fraccari, Eduardo Arístides; D'alessandro, Oriana; Sambeth, Jorge Enrique; Baronetti, Graciela Teresita; Mariño, Fernando Javier; Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction; Elsevier; Fuel Processing Technology; 119; 3-2014; 67-73
0378-3820
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378382013003263
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuproc.2013.10.012
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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