Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation

Autores
Kneeteman, Maria Nelida; López Baena, Anna Francesca; Della Rosa, Claudia Daniela; Mancini, Pedro Maximo Emilio
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work we studied a series of polar Diels-Alder reactions using different heterocycles derivatives acting as electrophiles joint to dienes of different nucleophilicity, analyzing the effect of the microwave irradiation in these processes. We employ the technique in two conditions: benzene as solvent and solvent free reactions. The last one presents the better yield in shorter time of reaction. Using microwave heating the aromatic cycloadducts are clearly predominant. It is possible to demonstrate that the microwave irradiation has a better influence on these cycloaddition reactions respect to those developed in thermal classical conditions.
Fil: Kneeteman, Maria Nelida. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: López Baena, Anna Francesca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Della Rosa, Claudia Daniela. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Mancini, Pedro Maximo Emilio. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Materia
AROMATIC HETEROCYCLES
microwave irradiation
SOLVENT FREE
DIELS-ALDER
electrophiles
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/49229
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave IrradiationKneeteman, Maria NelidaLópez Baena, Anna FrancescaDella Rosa, Claudia DanielaMancini, Pedro Maximo EmilioAROMATIC HETEROCYCLESmicrowave irradiationSOLVENT FREEDIELS-ALDERelectrophileshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work we studied a series of polar Diels-Alder reactions using different heterocycles derivatives acting as electrophiles joint to dienes of different nucleophilicity, analyzing the effect of the microwave irradiation in these processes. We employ the technique in two conditions: benzene as solvent and solvent free reactions. The last one presents the better yield in shorter time of reaction. Using microwave heating the aromatic cycloadducts are clearly predominant. It is possible to demonstrate that the microwave irradiation has a better influence on these cycloaddition reactions respect to those developed in thermal classical conditions.Fil: Kneeteman, Maria Nelida. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: López Baena, Anna Francesca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química; ArgentinaFil: Della Rosa, Claudia Daniela. Universidad Nacional del Litoral. Facultad de Ingeniería Química; ArgentinaFil: Mancini, Pedro Maximo Emilio. Universidad Nacional del Litoral. Facultad de Ingeniería Química; ArgentinaScienceDomain international2015-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/49229Kneeteman, Maria Nelida; López Baena, Anna Francesca; Della Rosa, Claudia Daniela; Mancini, Pedro Maximo Emilio; Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation; ScienceDomain international; International Research Journal of Pure and Applied Chemistry; 8; 4; 6-2015; 229-2352231-3443CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.9734/IRJPAC/2015/18867info:eu-repo/semantics/altIdentifier/url/http://www.sciencedomain.org/abstract/9590info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:22Zoai:ri.conicet.gov.ar:11336/49229instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:22.509CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation
title Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation
spellingShingle Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation
Kneeteman, Maria Nelida
AROMATIC HETEROCYCLES
microwave irradiation
SOLVENT FREE
DIELS-ALDER
electrophiles
title_short Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation
title_full Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation
title_fullStr Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation
title_full_unstemmed Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation
title_sort Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation
dc.creator.none.fl_str_mv Kneeteman, Maria Nelida
López Baena, Anna Francesca
Della Rosa, Claudia Daniela
Mancini, Pedro Maximo Emilio
author Kneeteman, Maria Nelida
author_facet Kneeteman, Maria Nelida
López Baena, Anna Francesca
Della Rosa, Claudia Daniela
Mancini, Pedro Maximo Emilio
author_role author
author2 López Baena, Anna Francesca
Della Rosa, Claudia Daniela
Mancini, Pedro Maximo Emilio
author2_role author
author
author
dc.subject.none.fl_str_mv AROMATIC HETEROCYCLES
microwave irradiation
SOLVENT FREE
DIELS-ALDER
electrophiles
topic AROMATIC HETEROCYCLES
microwave irradiation
SOLVENT FREE
DIELS-ALDER
electrophiles
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work we studied a series of polar Diels-Alder reactions using different heterocycles derivatives acting as electrophiles joint to dienes of different nucleophilicity, analyzing the effect of the microwave irradiation in these processes. We employ the technique in two conditions: benzene as solvent and solvent free reactions. The last one presents the better yield in shorter time of reaction. Using microwave heating the aromatic cycloadducts are clearly predominant. It is possible to demonstrate that the microwave irradiation has a better influence on these cycloaddition reactions respect to those developed in thermal classical conditions.
Fil: Kneeteman, Maria Nelida. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: López Baena, Anna Francesca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Della Rosa, Claudia Daniela. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Mancini, Pedro Maximo Emilio. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
description In this work we studied a series of polar Diels-Alder reactions using different heterocycles derivatives acting as electrophiles joint to dienes of different nucleophilicity, analyzing the effect of the microwave irradiation in these processes. We employ the technique in two conditions: benzene as solvent and solvent free reactions. The last one presents the better yield in shorter time of reaction. Using microwave heating the aromatic cycloadducts are clearly predominant. It is possible to demonstrate that the microwave irradiation has a better influence on these cycloaddition reactions respect to those developed in thermal classical conditions.
publishDate 2015
dc.date.none.fl_str_mv 2015-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/49229
Kneeteman, Maria Nelida; López Baena, Anna Francesca; Della Rosa, Claudia Daniela; Mancini, Pedro Maximo Emilio; Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation; ScienceDomain international; International Research Journal of Pure and Applied Chemistry; 8; 4; 6-2015; 229-235
2231-3443
CONICET Digital
CONICET
url http://hdl.handle.net/11336/49229
identifier_str_mv Kneeteman, Maria Nelida; López Baena, Anna Francesca; Della Rosa, Claudia Daniela; Mancini, Pedro Maximo Emilio; Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation; ScienceDomain international; International Research Journal of Pure and Applied Chemistry; 8; 4; 6-2015; 229-235
2231-3443
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.9734/IRJPAC/2015/18867
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedomain.org/abstract/9590
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv ScienceDomain international
publisher.none.fl_str_mv ScienceDomain international
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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