Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches

Autores
Brasca, Romina; Della Rosa, Claudia Daniela; Kneeteman, Maria Nelida; Mancini, Pedro Maximo Emilio
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The dienophilic behavior of electron-deficient substituted five-membered aromatic heterocyclices in polar cycloaddition reactions is studied from a theoretical point of view employing the global electrophilicity index to estimate the electrophilic character of the dienophiles and to compare them with the available experimental information. The type of substitution on the heteroatomic ring is also discussed. Complementary some new reactions of these substrates are described.
Fil: Brasca, Romina. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Della Rosa, Claudia Daniela. Universidad Nacional del Litoral; Argentina
Fil: Kneeteman, Maria Nelida. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Mancini, Pedro Maximo Emilio. Universidad Nacional del Litoral; Argentina
Materia
Dienophiles
Electrophilicity Index
Five-Membered Aromatic Heterocycles
Polar-Diels-Alder
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/74628
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental ResearchesBrasca, RominaDella Rosa, Claudia DanielaKneeteman, Maria NelidaMancini, Pedro Maximo EmilioDienophilesElectrophilicity IndexFive-Membered Aromatic HeterocyclesPolar-Diels-Alderhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The dienophilic behavior of electron-deficient substituted five-membered aromatic heterocyclices in polar cycloaddition reactions is studied from a theoretical point of view employing the global electrophilicity index to estimate the electrophilic character of the dienophiles and to compare them with the available experimental information. The type of substitution on the heteroatomic ring is also discussed. Complementary some new reactions of these substrates are described.Fil: Brasca, Romina. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Della Rosa, Claudia Daniela. Universidad Nacional del Litoral; ArgentinaFil: Kneeteman, Maria Nelida. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Mancini, Pedro Maximo Emilio. Universidad Nacional del Litoral; ArgentinaBentham Science Publishers2011-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/74628Brasca, Romina; Della Rosa, Claudia Daniela; Kneeteman, Maria Nelida; Mancini, Pedro Maximo Emilio; Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches; Bentham Science Publishers; Letters in Organic Chemistry; 8; 2; 2-2011; 82-871570-17861875-6255CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.eurekaselect.com/86496/articleinfo:eu-repo/semantics/altIdentifier/doi/10.2174/157017811794697511info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:38:12Zoai:ri.conicet.gov.ar:11336/74628instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:38:13.202CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches
title Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches
spellingShingle Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches
Brasca, Romina
Dienophiles
Electrophilicity Index
Five-Membered Aromatic Heterocycles
Polar-Diels-Alder
title_short Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches
title_full Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches
title_fullStr Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches
title_full_unstemmed Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches
title_sort Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches
dc.creator.none.fl_str_mv Brasca, Romina
Della Rosa, Claudia Daniela
Kneeteman, Maria Nelida
Mancini, Pedro Maximo Emilio
author Brasca, Romina
author_facet Brasca, Romina
Della Rosa, Claudia Daniela
Kneeteman, Maria Nelida
Mancini, Pedro Maximo Emilio
author_role author
author2 Della Rosa, Claudia Daniela
Kneeteman, Maria Nelida
Mancini, Pedro Maximo Emilio
author2_role author
author
author
dc.subject.none.fl_str_mv Dienophiles
Electrophilicity Index
Five-Membered Aromatic Heterocycles
Polar-Diels-Alder
topic Dienophiles
Electrophilicity Index
Five-Membered Aromatic Heterocycles
Polar-Diels-Alder
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The dienophilic behavior of electron-deficient substituted five-membered aromatic heterocyclices in polar cycloaddition reactions is studied from a theoretical point of view employing the global electrophilicity index to estimate the electrophilic character of the dienophiles and to compare them with the available experimental information. The type of substitution on the heteroatomic ring is also discussed. Complementary some new reactions of these substrates are described.
Fil: Brasca, Romina. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Della Rosa, Claudia Daniela. Universidad Nacional del Litoral; Argentina
Fil: Kneeteman, Maria Nelida. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Mancini, Pedro Maximo Emilio. Universidad Nacional del Litoral; Argentina
description The dienophilic behavior of electron-deficient substituted five-membered aromatic heterocyclices in polar cycloaddition reactions is studied from a theoretical point of view employing the global electrophilicity index to estimate the electrophilic character of the dienophiles and to compare them with the available experimental information. The type of substitution on the heteroatomic ring is also discussed. Complementary some new reactions of these substrates are described.
publishDate 2011
dc.date.none.fl_str_mv 2011-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/74628
Brasca, Romina; Della Rosa, Claudia Daniela; Kneeteman, Maria Nelida; Mancini, Pedro Maximo Emilio; Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches; Bentham Science Publishers; Letters in Organic Chemistry; 8; 2; 2-2011; 82-87
1570-1786
1875-6255
CONICET Digital
CONICET
url http://hdl.handle.net/11336/74628
identifier_str_mv Brasca, Romina; Della Rosa, Claudia Daniela; Kneeteman, Maria Nelida; Mancini, Pedro Maximo Emilio; Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches; Bentham Science Publishers; Letters in Organic Chemistry; 8; 2; 2-2011; 82-87
1570-1786
1875-6255
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.eurekaselect.com/86496/article
info:eu-repo/semantics/altIdentifier/doi/10.2174/157017811794697511
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Bentham Science Publishers
publisher.none.fl_str_mv Bentham Science Publishers
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846082859781062656
score 13.22299

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