Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature

Autores
Bustamante, Eugenia L.; Fernandez, Jose Luis; Zamaro, Juan Manuel
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of the solvent on the synthesis process and on the nanocrystal characteristics of the zeolitic imidazolate framework-8 (ZIF-8) was investigated. A synthesis protocol at room temperature employing a series of aliphatic alcohols, water, dimethylformamide and acetone was employed. The results show that the solvent modifies the evolution of the reaction, altering the crystallization rates and nanocrystal sizes. Its hydrogen bond donation ability is the main factor that governs this effect. More precisely, the solvent modulates the formation of ZIF-8 nanocrystals with sizes in the range between 15 and 42 nm. When synthesized in alcohol and acetone, these nanocrystals form globular aggregates with sizes between 130 and 420 nm. In contrast, under the same synthesis conditions, when using water or dimethylformamide the ZIF phase is not developed. In alcohols other than methanol, the crystals develop pill-shaped morphologies with poorly defined facets. Moreover, a markedly fast growing kinetics is verified in these alcohols, leading to an ultra-fast crystallization of ZIF-8 in about 60 s. These findings provide new information about the role of the solvent in the synthesis process of nanoZIF-8, which can be useful for controlling the crystallization rates and nanocrystal sizes of this material.
Fil: Bustamante, Eugenia L.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Fernandez, Jose Luis. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Metal-Organic Frameworks
Zif-8
Porous Nanomaterials
Solvent Effect
Crystallization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31268
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperatureBustamante, Eugenia L.Fernandez, Jose LuisZamaro, Juan ManuelMetal-Organic FrameworksZif-8Porous NanomaterialsSolvent EffectCrystallizationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The effect of the solvent on the synthesis process and on the nanocrystal characteristics of the zeolitic imidazolate framework-8 (ZIF-8) was investigated. A synthesis protocol at room temperature employing a series of aliphatic alcohols, water, dimethylformamide and acetone was employed. The results show that the solvent modifies the evolution of the reaction, altering the crystallization rates and nanocrystal sizes. Its hydrogen bond donation ability is the main factor that governs this effect. More precisely, the solvent modulates the formation of ZIF-8 nanocrystals with sizes in the range between 15 and 42 nm. When synthesized in alcohol and acetone, these nanocrystals form globular aggregates with sizes between 130 and 420 nm. In contrast, under the same synthesis conditions, when using water or dimethylformamide the ZIF phase is not developed. In alcohols other than methanol, the crystals develop pill-shaped morphologies with poorly defined facets. Moreover, a markedly fast growing kinetics is verified in these alcohols, leading to an ultra-fast crystallization of ZIF-8 in about 60 s. These findings provide new information about the role of the solvent in the synthesis process of nanoZIF-8, which can be useful for controlling the crystallization rates and nanocrystal sizes of this material.Fil: Bustamante, Eugenia L.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Fernandez, Jose Luis. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier2014-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31268Zamaro, Juan Manuel; Fernandez, Jose Luis; Bustamante, Eugenia L.; Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature; Elsevier; Journal of Colloid and Interface Science; 424; 3-2014; 37-430021-9797CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0021979714001349info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jcis.2014.03.014info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:23:09Zoai:ri.conicet.gov.ar:11336/31268instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:23:09.409CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature
title Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature
spellingShingle Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature
Bustamante, Eugenia L.
Metal-Organic Frameworks
Zif-8
Porous Nanomaterials
Solvent Effect
Crystallization
title_short Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature
title_full Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature
title_fullStr Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature
title_full_unstemmed Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature
title_sort Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature
dc.creator.none.fl_str_mv Bustamante, Eugenia L.
Fernandez, Jose Luis
Zamaro, Juan Manuel
author Bustamante, Eugenia L.
author_facet Bustamante, Eugenia L.
Fernandez, Jose Luis
Zamaro, Juan Manuel
author_role author
author2 Fernandez, Jose Luis
Zamaro, Juan Manuel
author2_role author
author
dc.subject.none.fl_str_mv Metal-Organic Frameworks
Zif-8
Porous Nanomaterials
Solvent Effect
Crystallization
topic Metal-Organic Frameworks
Zif-8
Porous Nanomaterials
Solvent Effect
Crystallization
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The effect of the solvent on the synthesis process and on the nanocrystal characteristics of the zeolitic imidazolate framework-8 (ZIF-8) was investigated. A synthesis protocol at room temperature employing a series of aliphatic alcohols, water, dimethylformamide and acetone was employed. The results show that the solvent modifies the evolution of the reaction, altering the crystallization rates and nanocrystal sizes. Its hydrogen bond donation ability is the main factor that governs this effect. More precisely, the solvent modulates the formation of ZIF-8 nanocrystals with sizes in the range between 15 and 42 nm. When synthesized in alcohol and acetone, these nanocrystals form globular aggregates with sizes between 130 and 420 nm. In contrast, under the same synthesis conditions, when using water or dimethylformamide the ZIF phase is not developed. In alcohols other than methanol, the crystals develop pill-shaped morphologies with poorly defined facets. Moreover, a markedly fast growing kinetics is verified in these alcohols, leading to an ultra-fast crystallization of ZIF-8 in about 60 s. These findings provide new information about the role of the solvent in the synthesis process of nanoZIF-8, which can be useful for controlling the crystallization rates and nanocrystal sizes of this material.
Fil: Bustamante, Eugenia L.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Fernandez, Jose Luis. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description The effect of the solvent on the synthesis process and on the nanocrystal characteristics of the zeolitic imidazolate framework-8 (ZIF-8) was investigated. A synthesis protocol at room temperature employing a series of aliphatic alcohols, water, dimethylformamide and acetone was employed. The results show that the solvent modifies the evolution of the reaction, altering the crystallization rates and nanocrystal sizes. Its hydrogen bond donation ability is the main factor that governs this effect. More precisely, the solvent modulates the formation of ZIF-8 nanocrystals with sizes in the range between 15 and 42 nm. When synthesized in alcohol and acetone, these nanocrystals form globular aggregates with sizes between 130 and 420 nm. In contrast, under the same synthesis conditions, when using water or dimethylformamide the ZIF phase is not developed. In alcohols other than methanol, the crystals develop pill-shaped morphologies with poorly defined facets. Moreover, a markedly fast growing kinetics is verified in these alcohols, leading to an ultra-fast crystallization of ZIF-8 in about 60 s. These findings provide new information about the role of the solvent in the synthesis process of nanoZIF-8, which can be useful for controlling the crystallization rates and nanocrystal sizes of this material.
publishDate 2014
dc.date.none.fl_str_mv 2014-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31268
Zamaro, Juan Manuel; Fernandez, Jose Luis; Bustamante, Eugenia L.; Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature; Elsevier; Journal of Colloid and Interface Science; 424; 3-2014; 37-43
0021-9797
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31268
identifier_str_mv Zamaro, Juan Manuel; Fernandez, Jose Luis; Bustamante, Eugenia L.; Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature; Elsevier; Journal of Colloid and Interface Science; 424; 3-2014; 37-43
0021-9797
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0021979714001349
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jcis.2014.03.014
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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