Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)

Autores
Seoane, Beatriz; Zamaro, Juan Manuel; Téllez, Carlos; Coronas, Joaquin
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Zeolitic imidazolate frameworks ZIF-7, ZIF-8, ZIF-11 and ZIF-20 have been synthesized by sonocrystallization. In general, crystals obtained at lower temperatures and shorter times are smaller and have a narrower size distribution than those achieved by conventional solvothermal synthesis. Moreover, crystallization curves have been calculated from the XRD patterns and the Gualtieri?s model has been applied to simulate the extent of crystallization as a function of time. According to the parameters calculated, for ZIF-8 the nucleation rate controls the synthesis reaction, while for ZIF-11 and ZIF-20 both growth and nucleation rates are similar.
Fil: Seoane, Beatriz. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Téllez, Carlos. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Coronas, Joaquin. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Materia
Metal-Organic Framework
Zif
Sonocrystallization
Synthesis
Ultrasound
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/53044
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)Seoane, BeatrizZamaro, Juan ManuelTéllez, CarlosCoronas, JoaquinMetal-Organic FrameworkZifSonocrystallizationSynthesisUltrasoundZeolitic imidazolate frameworks ZIF-7, ZIF-8, ZIF-11 and ZIF-20 have been synthesized by sonocrystallization. In general, crystals obtained at lower temperatures and shorter times are smaller and have a narrower size distribution than those achieved by conventional solvothermal synthesis. Moreover, crystallization curves have been calculated from the XRD patterns and the Gualtieri?s model has been applied to simulate the extent of crystallization as a function of time. According to the parameters calculated, for ZIF-8 the nucleation rate controls the synthesis reaction, while for ZIF-11 and ZIF-20 both growth and nucleation rates are similar.Fil: Seoane, Beatriz. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaFil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Téllez, Carlos. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaFil: Coronas, Joaquin. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaRoyal Society of Chemistry2012-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/53044Seoane, Beatriz; Zamaro, Juan Manuel; Téllez, Carlos; Coronas, Joaquin; Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20); Royal Society of Chemistry; CrystEngComm; 14; 2-2012; 3103-31071466-8033CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2012/CE/c2ce06382dinfo:eu-repo/semantics/altIdentifier/doi/10.1039/c2ce06382dinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:07:10Zoai:ri.conicet.gov.ar:11336/53044instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:07:10.921CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)
title Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)
spellingShingle Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)
Seoane, Beatriz
Metal-Organic Framework
Zif
Sonocrystallization
Synthesis
Ultrasound
title_short Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)
title_full Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)
title_fullStr Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)
title_full_unstemmed Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)
title_sort Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)
dc.creator.none.fl_str_mv Seoane, Beatriz
Zamaro, Juan Manuel
Téllez, Carlos
Coronas, Joaquin
author Seoane, Beatriz
author_facet Seoane, Beatriz
Zamaro, Juan Manuel
Téllez, Carlos
Coronas, Joaquin
author_role author
author2 Zamaro, Juan Manuel
Téllez, Carlos
Coronas, Joaquin
author2_role author
author
author
dc.subject.none.fl_str_mv Metal-Organic Framework
Zif
Sonocrystallization
Synthesis
Ultrasound
topic Metal-Organic Framework
Zif
Sonocrystallization
Synthesis
Ultrasound
dc.description.none.fl_txt_mv Zeolitic imidazolate frameworks ZIF-7, ZIF-8, ZIF-11 and ZIF-20 have been synthesized by sonocrystallization. In general, crystals obtained at lower temperatures and shorter times are smaller and have a narrower size distribution than those achieved by conventional solvothermal synthesis. Moreover, crystallization curves have been calculated from the XRD patterns and the Gualtieri?s model has been applied to simulate the extent of crystallization as a function of time. According to the parameters calculated, for ZIF-8 the nucleation rate controls the synthesis reaction, while for ZIF-11 and ZIF-20 both growth and nucleation rates are similar.
Fil: Seoane, Beatriz. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Téllez, Carlos. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Coronas, Joaquin. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
description Zeolitic imidazolate frameworks ZIF-7, ZIF-8, ZIF-11 and ZIF-20 have been synthesized by sonocrystallization. In general, crystals obtained at lower temperatures and shorter times are smaller and have a narrower size distribution than those achieved by conventional solvothermal synthesis. Moreover, crystallization curves have been calculated from the XRD patterns and the Gualtieri?s model has been applied to simulate the extent of crystallization as a function of time. According to the parameters calculated, for ZIF-8 the nucleation rate controls the synthesis reaction, while for ZIF-11 and ZIF-20 both growth and nucleation rates are similar.
publishDate 2012
dc.date.none.fl_str_mv 2012-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/53044
Seoane, Beatriz; Zamaro, Juan Manuel; Téllez, Carlos; Coronas, Joaquin; Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20); Royal Society of Chemistry; CrystEngComm; 14; 2-2012; 3103-3107
1466-8033
CONICET Digital
CONICET
url http://hdl.handle.net/11336/53044
identifier_str_mv Seoane, Beatriz; Zamaro, Juan Manuel; Téllez, Carlos; Coronas, Joaquin; Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20); Royal Society of Chemistry; CrystEngComm; 14; 2-2012; 3103-3107
1466-8033
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2012/CE/c2ce06382d
info:eu-repo/semantics/altIdentifier/doi/10.1039/c2ce06382d
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269992467300352
score 13.13397

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