Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release

Autores
Wang, Changlong; Tuninetti, Jimena Soledad; Wang, Zhao; Zhang, Chen; Ciganda, Roberto; Salmon, Lionel; Moya, Sergio; Ruiz, Jaime; Astruc, Didier
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Non-noble metal nanoparticles are notoriously difficult to prepare and stabilize with appropriate dispersion, which in turn severely limits their catalytic functions. Here, using zeolitic imidazolate framework (ZIF-8) as MOF template, catalytically remarkably efficient ligand-free first-row late transition-metal nanoparticles are prepared and compared. Upon scrutiny of the catalytic principles in the hydrolysis of ammonia-borane, the highest total turnover frequency among these first-row late transition metals is achieved for the templated Ni nanoparticles with 85.7 molH2 molcat -1 min-1 at room temperature, which overtakes performances of previous non-noble metal nanoparticles systems, and is even better than some noble metal nanoparticles systems. Mechanistic studies especially using kinetic isotope effects show that cleavage by oxidative addition of an O-H bond in H2O is the rate-determining step in this reaction. Inspired by these mechanistic studies, an attractive and effective "on-off" control of hydrogen production is further proposed.
Fil: Wang, Changlong. Centre National de la Recherche Scientifique/laboratoir; Francia
Fil: Tuninetti, Jimena Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Wang, Zhao. Sorbonne Universités; Francia
Fil: Zhang, Chen. Sorbonne Universites; Francia
Fil: Ciganda, Roberto. Universite Bordeaux; Francia
Fil: Salmon, Lionel. Laboratoire de Chimie de Coordination; Francia
Fil: Moya, Sergio. Cic Biomagune; España
Fil: Ruiz, Jaime. Universite de Bordeaux; Francia
Fil: Astruc, Didier. Universite de Bordeaux; Francia
Materia
CATALYSIS
ZIF-8
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/64286
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/64286
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen ReleaseWang, ChanglongTuninetti, Jimena SoledadWang, ZhaoZhang, ChenCiganda, RobertoSalmon, LionelMoya, SergioRuiz, JaimeAstruc, DidierCATALYSISZIF-8https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Non-noble metal nanoparticles are notoriously difficult to prepare and stabilize with appropriate dispersion, which in turn severely limits their catalytic functions. Here, using zeolitic imidazolate framework (ZIF-8) as MOF template, catalytically remarkably efficient ligand-free first-row late transition-metal nanoparticles are prepared and compared. Upon scrutiny of the catalytic principles in the hydrolysis of ammonia-borane, the highest total turnover frequency among these first-row late transition metals is achieved for the templated Ni nanoparticles with 85.7 molH2 molcat -1 min-1 at room temperature, which overtakes performances of previous non-noble metal nanoparticles systems, and is even better than some noble metal nanoparticles systems. Mechanistic studies especially using kinetic isotope effects show that cleavage by oxidative addition of an O-H bond in H2O is the rate-determining step in this reaction. Inspired by these mechanistic studies, an attractive and effective "on-off" control of hydrogen production is further proposed.Fil: Wang, Changlong. Centre National de la Recherche Scientifique/laboratoir; FranciaFil: Tuninetti, Jimena Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Wang, Zhao. Sorbonne Universités; FranciaFil: Zhang, Chen. Sorbonne Universites; FranciaFil: Ciganda, Roberto. Universite Bordeaux; FranciaFil: Salmon, Lionel. Laboratoire de Chimie de Coordination; FranciaFil: Moya, Sergio. Cic Biomagune; EspañaFil: Ruiz, Jaime. Universite de Bordeaux; FranciaFil: Astruc, Didier. Universite de Bordeaux; FranciaAmerican Chemical Society2017-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/64286Wang, Changlong; Tuninetti, Jimena Soledad; Wang, Zhao; Zhang, Chen; Ciganda, Roberto; et al.; Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release; American Chemical Society; Journal of the American Chemical Society; 139; 33; 8-2017; 11610-116150002-7863CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jacs.7b06859info:eu-repo/semantics/altIdentifier/doi/10.1021/jacs.7b06859info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:13:30Zoai:ri.conicet.gov.ar:11336/64286instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:13:30.749CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release
title Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release
spellingShingle Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release
Wang, Changlong
CATALYSIS
ZIF-8
title_short Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release
title_full Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release
title_fullStr Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release
title_full_unstemmed Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release
title_sort Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release
dc.creator.none.fl_str_mv Wang, Changlong
Tuninetti, Jimena Soledad
Wang, Zhao
Zhang, Chen
Ciganda, Roberto
Salmon, Lionel
Moya, Sergio
Ruiz, Jaime
Astruc, Didier
author Wang, Changlong
author_facet Wang, Changlong
Tuninetti, Jimena Soledad
Wang, Zhao
Zhang, Chen
Ciganda, Roberto
Salmon, Lionel
Moya, Sergio
Ruiz, Jaime
Astruc, Didier
author_role author
author2 Tuninetti, Jimena Soledad
Wang, Zhao
Zhang, Chen
Ciganda, Roberto
Salmon, Lionel
Moya, Sergio
Ruiz, Jaime
Astruc, Didier
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv CATALYSIS
ZIF-8
topic CATALYSIS
ZIF-8
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Non-noble metal nanoparticles are notoriously difficult to prepare and stabilize with appropriate dispersion, which in turn severely limits their catalytic functions. Here, using zeolitic imidazolate framework (ZIF-8) as MOF template, catalytically remarkably efficient ligand-free first-row late transition-metal nanoparticles are prepared and compared. Upon scrutiny of the catalytic principles in the hydrolysis of ammonia-borane, the highest total turnover frequency among these first-row late transition metals is achieved for the templated Ni nanoparticles with 85.7 molH2 molcat -1 min-1 at room temperature, which overtakes performances of previous non-noble metal nanoparticles systems, and is even better than some noble metal nanoparticles systems. Mechanistic studies especially using kinetic isotope effects show that cleavage by oxidative addition of an O-H bond in H2O is the rate-determining step in this reaction. Inspired by these mechanistic studies, an attractive and effective "on-off" control of hydrogen production is further proposed.
Fil: Wang, Changlong. Centre National de la Recherche Scientifique/laboratoir; Francia
Fil: Tuninetti, Jimena Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Wang, Zhao. Sorbonne Universités; Francia
Fil: Zhang, Chen. Sorbonne Universites; Francia
Fil: Ciganda, Roberto. Universite Bordeaux; Francia
Fil: Salmon, Lionel. Laboratoire de Chimie de Coordination; Francia
Fil: Moya, Sergio. Cic Biomagune; España
Fil: Ruiz, Jaime. Universite de Bordeaux; Francia
Fil: Astruc, Didier. Universite de Bordeaux; Francia
description Non-noble metal nanoparticles are notoriously difficult to prepare and stabilize with appropriate dispersion, which in turn severely limits their catalytic functions. Here, using zeolitic imidazolate framework (ZIF-8) as MOF template, catalytically remarkably efficient ligand-free first-row late transition-metal nanoparticles are prepared and compared. Upon scrutiny of the catalytic principles in the hydrolysis of ammonia-borane, the highest total turnover frequency among these first-row late transition metals is achieved for the templated Ni nanoparticles with 85.7 molH2 molcat -1 min-1 at room temperature, which overtakes performances of previous non-noble metal nanoparticles systems, and is even better than some noble metal nanoparticles systems. Mechanistic studies especially using kinetic isotope effects show that cleavage by oxidative addition of an O-H bond in H2O is the rate-determining step in this reaction. Inspired by these mechanistic studies, an attractive and effective "on-off" control of hydrogen production is further proposed.
publishDate 2017
dc.date.none.fl_str_mv 2017-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/64286
Wang, Changlong; Tuninetti, Jimena Soledad; Wang, Zhao; Zhang, Chen; Ciganda, Roberto; et al.; Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release; American Chemical Society; Journal of the American Chemical Society; 139; 33; 8-2017; 11610-11615
0002-7863
CONICET Digital
CONICET
url http://hdl.handle.net/11336/64286
identifier_str_mv Wang, Changlong; Tuninetti, Jimena Soledad; Wang, Zhao; Zhang, Chen; Ciganda, Roberto; et al.; Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release; American Chemical Society; Journal of the American Chemical Society; 139; 33; 8-2017; 11610-11615
0002-7863
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jacs.7b06859
info:eu-repo/semantics/altIdentifier/doi/10.1021/jacs.7b06859
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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