In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry
- Autores
- Barella, Mariano; Violi, Ianina Lucila; Gargiulo, Julian; Martínez, Luciana Paula; Goschin, Florian; Guglielmotti, Victoria; Pallarola, Diego Andres; Schlücker, Sebastian; Pilo Pais, Mauricio; Acuna, Guillermo P.; Maier, Stefan A.; Cortés, Emiliano; Stefani, Fernando Daniel
- Año de publicación
- 2020
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Several fields of applications require a reliable characterization of the photothermal response and heat dissipation of nanoscopic systems, which remains a challenging task for both modeling and experimental measurements. Here, we present an implementation of anti-Stokes thermometry that enables the in situ photothermal characterization of individual nanoparticles (NPs) from a single hyperspectral photoluminescence confocal image. The method is label-free, potentially applicable to any NP with detectable anti-Stokes emission, and does not require any prior information about the NP itself or the surrounding media. With it, we first studied the photothermal response of spherical gold NPs of different sizes on glass substrates, immersed in water, and found that heat dissipation is mainly dominated by the water for NPs larger than 50 nm. Then, the role of the substrate was studied by comparing the photothermal response of 80 nm gold NPs on glass with sapphire and graphene, two materials with high thermal conductivity. For a given irradiance level, the NPs reach temperatures 18% lower on sapphire and 24% higher on graphene than on bare glass. The fact that the presence of a highly conductive material such as graphene leads to a poorer thermal dissipation demonstrates that interfacial thermal resistances play a very significant role in nanoscopic systems and emphasize the need for in situ experimental thermometry techniques. The developed method will allow addressing several open questions about the role of temperature in plasmon-assisted applications, especially ones where NPs of arbitrary shapes are present in complex matrixes and environments.
Fil: Barella, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Violi, Ianina Lucila. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Gargiulo, Julian. Ludwig Maximilians Universitat; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Martínez, Luciana Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Goschin, Florian. Ludwig Maximilians Universitat; Alemania
Fil: Guglielmotti, Victoria. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pallarola, Diego Andres. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Schlücker, Sebastian. Universitat Essen; Alemania
Fil: Pilo Pais, Mauricio. University Of Fribourg; Suiza
Fil: Acuna, Guillermo P.. University Of Fribourg; Suiza
Fil: Maier, Stefan A.. Ludwig Maximilians Universitat; Alemania. Imperial College London; Reino Unido
Fil: Cortés, Emiliano. Ludwig Maximilians Universitat; Alemania
Fil: Stefani, Fernando Daniel. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina - Materia
-
ANTI-STOKES NANOTHERMOMETRY
GRAPHENE
METAL PHOTOLUMINESCENCE
METALLIC NANOPARTICLES
OPTICAL PRINTING
PLASMONICS
THERMOPLASMONICS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/170794
Ver los metadatos del registro completo
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In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometryBarella, MarianoVioli, Ianina LucilaGargiulo, JulianMartínez, Luciana PaulaGoschin, FlorianGuglielmotti, VictoriaPallarola, Diego AndresSchlücker, SebastianPilo Pais, MauricioAcuna, Guillermo P.Maier, Stefan A.Cortés, EmilianoStefani, Fernando DanielANTI-STOKES NANOTHERMOMETRYGRAPHENEMETAL PHOTOLUMINESCENCEMETALLIC NANOPARTICLESOPTICAL PRINTINGPLASMONICSTHERMOPLASMONICShttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Several fields of applications require a reliable characterization of the photothermal response and heat dissipation of nanoscopic systems, which remains a challenging task for both modeling and experimental measurements. Here, we present an implementation of anti-Stokes thermometry that enables the in situ photothermal characterization of individual nanoparticles (NPs) from a single hyperspectral photoluminescence confocal image. The method is label-free, potentially applicable to any NP with detectable anti-Stokes emission, and does not require any prior information about the NP itself or the surrounding media. With it, we first studied the photothermal response of spherical gold NPs of different sizes on glass substrates, immersed in water, and found that heat dissipation is mainly dominated by the water for NPs larger than 50 nm. Then, the role of the substrate was studied by comparing the photothermal response of 80 nm gold NPs on glass with sapphire and graphene, two materials with high thermal conductivity. For a given irradiance level, the NPs reach temperatures 18% lower on sapphire and 24% higher on graphene than on bare glass. The fact that the presence of a highly conductive material such as graphene leads to a poorer thermal dissipation demonstrates that interfacial thermal resistances play a very significant role in nanoscopic systems and emphasize the need for in situ experimental thermometry techniques. The developed method will allow addressing several open questions about the role of temperature in plasmon-assisted applications, especially ones where NPs of arbitrary shapes are present in complex matrixes and environments.Fil: Barella, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; ArgentinaFil: Violi, Ianina Lucila. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; ArgentinaFil: Gargiulo, Julian. Ludwig Maximilians Universitat; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Martínez, Luciana Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; ArgentinaFil: Goschin, Florian. Ludwig Maximilians Universitat; AlemaniaFil: Guglielmotti, Victoria. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Pallarola, Diego Andres. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Schlücker, Sebastian. Universitat Essen; AlemaniaFil: Pilo Pais, Mauricio. University Of Fribourg; SuizaFil: Acuna, Guillermo P.. University Of Fribourg; SuizaFil: Maier, Stefan A.. Ludwig Maximilians Universitat; Alemania. Imperial College London; Reino UnidoFil: Cortés, Emiliano. Ludwig Maximilians Universitat; AlemaniaFil: Stefani, Fernando Daniel. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; ArgentinaAmerican Chemical Society2020-09-17info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/170794Barella, Mariano; Violi, Ianina Lucila; Gargiulo, Julian; Martínez, Luciana Paula; Goschin, Florian; et al.; In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry; American Chemical Society; ACS Nano; 15; 2; 17-9-2020; 2458-24671936-08511936-086XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsnano.0c06185info:eu-repo/semantics/altIdentifier/doi/10.1021/acsnano.0c06185info:eu-repo/semantics/altIdentifier/url/https://arxiv.org/ftp/arxiv/papers/2108/2108.10954.pdfinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:47Zoai:ri.conicet.gov.ar:11336/170794instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:47.332CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry |
| title |
In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry |
| spellingShingle |
In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry Barella, Mariano ANTI-STOKES NANOTHERMOMETRY GRAPHENE METAL PHOTOLUMINESCENCE METALLIC NANOPARTICLES OPTICAL PRINTING PLASMONICS THERMOPLASMONICS |
| title_short |
In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry |
| title_full |
In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry |
| title_fullStr |
In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry |
| title_full_unstemmed |
In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry |
| title_sort |
In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry |
| dc.creator.none.fl_str_mv |
Barella, Mariano Violi, Ianina Lucila Gargiulo, Julian Martínez, Luciana Paula Goschin, Florian Guglielmotti, Victoria Pallarola, Diego Andres Schlücker, Sebastian Pilo Pais, Mauricio Acuna, Guillermo P. Maier, Stefan A. Cortés, Emiliano Stefani, Fernando Daniel |
| author |
Barella, Mariano |
| author_facet |
Barella, Mariano Violi, Ianina Lucila Gargiulo, Julian Martínez, Luciana Paula Goschin, Florian Guglielmotti, Victoria Pallarola, Diego Andres Schlücker, Sebastian Pilo Pais, Mauricio Acuna, Guillermo P. Maier, Stefan A. Cortés, Emiliano Stefani, Fernando Daniel |
| author_role |
author |
| author2 |
Violi, Ianina Lucila Gargiulo, Julian Martínez, Luciana Paula Goschin, Florian Guglielmotti, Victoria Pallarola, Diego Andres Schlücker, Sebastian Pilo Pais, Mauricio Acuna, Guillermo P. Maier, Stefan A. Cortés, Emiliano Stefani, Fernando Daniel |
| author2_role |
author author author author author author author author author author author author |
| dc.subject.none.fl_str_mv |
ANTI-STOKES NANOTHERMOMETRY GRAPHENE METAL PHOTOLUMINESCENCE METALLIC NANOPARTICLES OPTICAL PRINTING PLASMONICS THERMOPLASMONICS |
| topic |
ANTI-STOKES NANOTHERMOMETRY GRAPHENE METAL PHOTOLUMINESCENCE METALLIC NANOPARTICLES OPTICAL PRINTING PLASMONICS THERMOPLASMONICS |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.10 https://purl.org/becyt/ford/2 |
| dc.description.none.fl_txt_mv |
Several fields of applications require a reliable characterization of the photothermal response and heat dissipation of nanoscopic systems, which remains a challenging task for both modeling and experimental measurements. Here, we present an implementation of anti-Stokes thermometry that enables the in situ photothermal characterization of individual nanoparticles (NPs) from a single hyperspectral photoluminescence confocal image. The method is label-free, potentially applicable to any NP with detectable anti-Stokes emission, and does not require any prior information about the NP itself or the surrounding media. With it, we first studied the photothermal response of spherical gold NPs of different sizes on glass substrates, immersed in water, and found that heat dissipation is mainly dominated by the water for NPs larger than 50 nm. Then, the role of the substrate was studied by comparing the photothermal response of 80 nm gold NPs on glass with sapphire and graphene, two materials with high thermal conductivity. For a given irradiance level, the NPs reach temperatures 18% lower on sapphire and 24% higher on graphene than on bare glass. The fact that the presence of a highly conductive material such as graphene leads to a poorer thermal dissipation demonstrates that interfacial thermal resistances play a very significant role in nanoscopic systems and emphasize the need for in situ experimental thermometry techniques. The developed method will allow addressing several open questions about the role of temperature in plasmon-assisted applications, especially ones where NPs of arbitrary shapes are present in complex matrixes and environments. Fil: Barella, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina Fil: Violi, Ianina Lucila. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina Fil: Gargiulo, Julian. Ludwig Maximilians Universitat; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Martínez, Luciana Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina Fil: Goschin, Florian. Ludwig Maximilians Universitat; Alemania Fil: Guglielmotti, Victoria. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Pallarola, Diego Andres. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Schlücker, Sebastian. Universitat Essen; Alemania Fil: Pilo Pais, Mauricio. University Of Fribourg; Suiza Fil: Acuna, Guillermo P.. University Of Fribourg; Suiza Fil: Maier, Stefan A.. Ludwig Maximilians Universitat; Alemania. Imperial College London; Reino Unido Fil: Cortés, Emiliano. Ludwig Maximilians Universitat; Alemania Fil: Stefani, Fernando Daniel. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina |
| description |
Several fields of applications require a reliable characterization of the photothermal response and heat dissipation of nanoscopic systems, which remains a challenging task for both modeling and experimental measurements. Here, we present an implementation of anti-Stokes thermometry that enables the in situ photothermal characterization of individual nanoparticles (NPs) from a single hyperspectral photoluminescence confocal image. The method is label-free, potentially applicable to any NP with detectable anti-Stokes emission, and does not require any prior information about the NP itself or the surrounding media. With it, we first studied the photothermal response of spherical gold NPs of different sizes on glass substrates, immersed in water, and found that heat dissipation is mainly dominated by the water for NPs larger than 50 nm. Then, the role of the substrate was studied by comparing the photothermal response of 80 nm gold NPs on glass with sapphire and graphene, two materials with high thermal conductivity. For a given irradiance level, the NPs reach temperatures 18% lower on sapphire and 24% higher on graphene than on bare glass. The fact that the presence of a highly conductive material such as graphene leads to a poorer thermal dissipation demonstrates that interfacial thermal resistances play a very significant role in nanoscopic systems and emphasize the need for in situ experimental thermometry techniques. The developed method will allow addressing several open questions about the role of temperature in plasmon-assisted applications, especially ones where NPs of arbitrary shapes are present in complex matrixes and environments. |
| publishDate |
2020 |
| dc.date.none.fl_str_mv |
2020-09-17 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://hdl.handle.net/11336/170794 Barella, Mariano; Violi, Ianina Lucila; Gargiulo, Julian; Martínez, Luciana Paula; Goschin, Florian; et al.; In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry; American Chemical Society; ACS Nano; 15; 2; 17-9-2020; 2458-2467 1936-0851 1936-086X CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/170794 |
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Barella, Mariano; Violi, Ianina Lucila; Gargiulo, Julian; Martínez, Luciana Paula; Goschin, Florian; et al.; In situ photothermal response of single gold nanoparticles through hyperspectral imaging anti-stokes thermometry; American Chemical Society; ACS Nano; 15; 2; 17-9-2020; 2458-2467 1936-0851 1936-086X CONICET Digital CONICET |
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eng |
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eng |
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American Chemical Society |
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American Chemical Society |
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