Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry

Autores
Gargiulo, Julian; Herran, Matias; Violi, Ianina Lucila; Sousa Castillo, Ana; Martínez, Luciana Paula; Ezendam, Simone; Barella, Mariano; Giesler, Helene; Grzeschik, Roland; Schlücker, Sebastian; Maier, Stefan A.; Stefani, Fernando Daniel; Cortés, Emiliano
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Localized surface plasmons are lossy and generate heat. However, accurate measurement of the temperature of metallic nanoparticles under illumination remains an open challenge, creating difficulties in the interpretation of results across plasmonic applications. Particularly, there is a quest for understanding the role of temperature in plasmon-assisted catalysis. Bimetallic nanoparticles combining plasmonic with catalytic metals are raising increasing interest in artificial photosynthesis and the production of solar fuels. Here, we perform single-particle thermometry measurements to investigate the link between morphology and light-to-heat conversion of colloidal Au/Pd nanoparticles with two different configurations: core–shell and core-satellite. It is observed that the inclusion of Pd as a shell strongly reduces the photothermal response in comparison to the bare cores, while the inclusion of Pd as satellites keeps photothermal properties almost unaffected. These results contribute to a better understanding of energy conversion processes in plasmon-assisted catalysis.
Fil: Gargiulo, Julian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: Herran, Matias. Ludwig Maximilians Universitat; Alemania
Fil: Violi, Ianina Lucila. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Sousa Castillo, Ana. Ludwig Maximilians Universitat; Alemania
Fil: Martínez, Luciana Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Ezendam, Simone. Ludwig Maximilians Universitat; Alemania
Fil: Barella, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Giesler, Helene. Universitat Essen; Alemania
Fil: Grzeschik, Roland. Universitat Essen; Alemania
Fil: Schlücker, Sebastian. Universitat Essen; Alemania
Fil: Maier, Stefan A.. Monash University; Australia. Imperial College London; Reino Unido. Ludwig Maximilians Universitat; Alemania
Fil: Stefani, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Cortés, Emiliano. Ludwig Maximilians Universitat; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Materia
plasmonics
thermometry
plasmonic chemistry
photocatalysis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/223715
Acceder
id CONICETDig_04e908df147e499d6f28e3bf210df0ef
oai_identifier_str oai:ri.conicet.gov.ar:11336/223715
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometryGargiulo, JulianHerran, MatiasVioli, Ianina LucilaSousa Castillo, AnaMartínez, Luciana PaulaEzendam, SimoneBarella, MarianoGiesler, HeleneGrzeschik, RolandSchlücker, SebastianMaier, Stefan A.Stefani, Fernando DanielCortés, Emilianoplasmonicsthermometryplasmonic chemistryphotocatalysishttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Localized surface plasmons are lossy and generate heat. However, accurate measurement of the temperature of metallic nanoparticles under illumination remains an open challenge, creating difficulties in the interpretation of results across plasmonic applications. Particularly, there is a quest for understanding the role of temperature in plasmon-assisted catalysis. Bimetallic nanoparticles combining plasmonic with catalytic metals are raising increasing interest in artificial photosynthesis and the production of solar fuels. Here, we perform single-particle thermometry measurements to investigate the link between morphology and light-to-heat conversion of colloidal Au/Pd nanoparticles with two different configurations: core–shell and core-satellite. It is observed that the inclusion of Pd as a shell strongly reduces the photothermal response in comparison to the bare cores, while the inclusion of Pd as satellites keeps photothermal properties almost unaffected. These results contribute to a better understanding of energy conversion processes in plasmon-assisted catalysis.Fil: Gargiulo, Julian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; ArgentinaFil: Herran, Matias. Ludwig Maximilians Universitat; AlemaniaFil: Violi, Ianina Lucila. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; ArgentinaFil: Sousa Castillo, Ana. Ludwig Maximilians Universitat; AlemaniaFil: Martínez, Luciana Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; ArgentinaFil: Ezendam, Simone. Ludwig Maximilians Universitat; AlemaniaFil: Barella, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; ArgentinaFil: Giesler, Helene. Universitat Essen; AlemaniaFil: Grzeschik, Roland. Universitat Essen; AlemaniaFil: Schlücker, Sebastian. Universitat Essen; AlemaniaFil: Maier, Stefan A.. Monash University; Australia. Imperial College London; Reino Unido. Ludwig Maximilians Universitat; AlemaniaFil: Stefani, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; ArgentinaFil: Cortés, Emiliano. Ludwig Maximilians Universitat; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; ArgentinaSpringer2023-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/223715Gargiulo, Julian; Herran, Matias; Violi, Ianina Lucila; Sousa Castillo, Ana; Martínez, Luciana Paula; et al.; Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry; Springer; Nature Communications; 14; 1; 6-2023; 1-112041-1723CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.nature.com/articles/s41467-023-38982-9info:eu-repo/semantics/altIdentifier/doi/10.1038/s41467-023-38982-9info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:11:48Zoai:ri.conicet.gov.ar:11336/223715instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:11:48.883CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry
title Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry
spellingShingle Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry
Gargiulo, Julian
plasmonics
thermometry
plasmonic chemistry
photocatalysis
title_short Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry
title_full Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry
title_fullStr Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry
title_full_unstemmed Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry
title_sort Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry
dc.creator.none.fl_str_mv Gargiulo, Julian
Herran, Matias
Violi, Ianina Lucila
Sousa Castillo, Ana
Martínez, Luciana Paula
Ezendam, Simone
Barella, Mariano
Giesler, Helene
Grzeschik, Roland
Schlücker, Sebastian
Maier, Stefan A.
Stefani, Fernando Daniel
Cortés, Emiliano
author Gargiulo, Julian
author_facet Gargiulo, Julian
Herran, Matias
Violi, Ianina Lucila
Sousa Castillo, Ana
Martínez, Luciana Paula
Ezendam, Simone
Barella, Mariano
Giesler, Helene
Grzeschik, Roland
Schlücker, Sebastian
Maier, Stefan A.
Stefani, Fernando Daniel
Cortés, Emiliano
author_role author
author2 Herran, Matias
Violi, Ianina Lucila
Sousa Castillo, Ana
Martínez, Luciana Paula
Ezendam, Simone
Barella, Mariano
Giesler, Helene
Grzeschik, Roland
Schlücker, Sebastian
Maier, Stefan A.
Stefani, Fernando Daniel
Cortés, Emiliano
author2_role author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv plasmonics
thermometry
plasmonic chemistry
photocatalysis
topic plasmonics
thermometry
plasmonic chemistry
photocatalysis
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Localized surface plasmons are lossy and generate heat. However, accurate measurement of the temperature of metallic nanoparticles under illumination remains an open challenge, creating difficulties in the interpretation of results across plasmonic applications. Particularly, there is a quest for understanding the role of temperature in plasmon-assisted catalysis. Bimetallic nanoparticles combining plasmonic with catalytic metals are raising increasing interest in artificial photosynthesis and the production of solar fuels. Here, we perform single-particle thermometry measurements to investigate the link between morphology and light-to-heat conversion of colloidal Au/Pd nanoparticles with two different configurations: core–shell and core-satellite. It is observed that the inclusion of Pd as a shell strongly reduces the photothermal response in comparison to the bare cores, while the inclusion of Pd as satellites keeps photothermal properties almost unaffected. These results contribute to a better understanding of energy conversion processes in plasmon-assisted catalysis.
Fil: Gargiulo, Julian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: Herran, Matias. Ludwig Maximilians Universitat; Alemania
Fil: Violi, Ianina Lucila. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Sousa Castillo, Ana. Ludwig Maximilians Universitat; Alemania
Fil: Martínez, Luciana Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Ezendam, Simone. Ludwig Maximilians Universitat; Alemania
Fil: Barella, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Giesler, Helene. Universitat Essen; Alemania
Fil: Grzeschik, Roland. Universitat Essen; Alemania
Fil: Schlücker, Sebastian. Universitat Essen; Alemania
Fil: Maier, Stefan A.. Monash University; Australia. Imperial College London; Reino Unido. Ludwig Maximilians Universitat; Alemania
Fil: Stefani, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
Fil: Cortés, Emiliano. Ludwig Maximilians Universitat; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina
description Localized surface plasmons are lossy and generate heat. However, accurate measurement of the temperature of metallic nanoparticles under illumination remains an open challenge, creating difficulties in the interpretation of results across plasmonic applications. Particularly, there is a quest for understanding the role of temperature in plasmon-assisted catalysis. Bimetallic nanoparticles combining plasmonic with catalytic metals are raising increasing interest in artificial photosynthesis and the production of solar fuels. Here, we perform single-particle thermometry measurements to investigate the link between morphology and light-to-heat conversion of colloidal Au/Pd nanoparticles with two different configurations: core–shell and core-satellite. It is observed that the inclusion of Pd as a shell strongly reduces the photothermal response in comparison to the bare cores, while the inclusion of Pd as satellites keeps photothermal properties almost unaffected. These results contribute to a better understanding of energy conversion processes in plasmon-assisted catalysis.
publishDate 2023
dc.date.none.fl_str_mv 2023-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/223715
Gargiulo, Julian; Herran, Matias; Violi, Ianina Lucila; Sousa Castillo, Ana; Martínez, Luciana Paula; et al.; Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry; Springer; Nature Communications; 14; 1; 6-2023; 1-11
2041-1723
CONICET Digital
CONICET
url http://hdl.handle.net/11336/223715
identifier_str_mv Gargiulo, Julian; Herran, Matias; Violi, Ianina Lucila; Sousa Castillo, Ana; Martínez, Luciana Paula; et al.; Impact of bimetallic interface design on heat generation in plasmonic Au/Pd nanostructures studied by single-particle thermometry; Springer; Nature Communications; 14; 1; 6-2023; 1-11
2041-1723
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.nature.com/articles/s41467-023-38982-9
info:eu-repo/semantics/altIdentifier/doi/10.1038/s41467-023-38982-9
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083266430369792
score 13.22299

Publicaciones similares