Estimating models for predicting effective permeability of mixed matrix membranes
- Autores
- Gonzo, Elio Emilio; Parentis, Monica Liliana; Gottifredi, Juan Carlos Agustin
- Año de publicación
- 2006
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Mixed matrix membranes have become a highly potential unique materials in many engineering application to overcome limitations presented by other products. In this contribution, an improved form of Maxwell's equation (the extended Maxwell equation) based on the hard-sphere model fluid proposed by Chiew and Glandt [Y.C. Chiew, E.D. Glandt, The effect of structure on the conductivity of a dispersion, J. Colloid Interface Sci. 94 (1983) 90-104] is evolved. The resulting equation allows the estimation of the effective permeability of composite membranes as a function of the reduced permeation polarizability and the volume fraction of the filler. This method can be applied to estimate effective permeability of gases and liquids through mixed matrix membranes prepared with different polymer matrix, as continuous phase, and organic (polymer or liquid crystal mixture) or inorganic (zeolites, activated carbons) compounds as filler even at relatively high volume fractions of this compound. A comparison among estimated values of the effective permeability and experimental data reported in the literature generally shows good agreement although there are a number of observations that are not easily explained with any of these models. © 2005 Elsevier B.V. All rights reserved.
Fil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Parentis, Monica Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Gottifredi, Juan Carlos Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina - Materia
-
Maxwell Model
Membrane
Mixed Matrix
Permeation
Selectivity - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/66911
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Estimating models for predicting effective permeability of mixed matrix membranesGonzo, Elio EmilioParentis, Monica LilianaGottifredi, Juan Carlos AgustinMaxwell ModelMembraneMixed MatrixPermeationSelectivityhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Mixed matrix membranes have become a highly potential unique materials in many engineering application to overcome limitations presented by other products. In this contribution, an improved form of Maxwell's equation (the extended Maxwell equation) based on the hard-sphere model fluid proposed by Chiew and Glandt [Y.C. Chiew, E.D. Glandt, The effect of structure on the conductivity of a dispersion, J. Colloid Interface Sci. 94 (1983) 90-104] is evolved. The resulting equation allows the estimation of the effective permeability of composite membranes as a function of the reduced permeation polarizability and the volume fraction of the filler. This method can be applied to estimate effective permeability of gases and liquids through mixed matrix membranes prepared with different polymer matrix, as continuous phase, and organic (polymer or liquid crystal mixture) or inorganic (zeolites, activated carbons) compounds as filler even at relatively high volume fractions of this compound. A comparison among estimated values of the effective permeability and experimental data reported in the literature generally shows good agreement although there are a number of observations that are not easily explained with any of these models. © 2005 Elsevier B.V. All rights reserved.Fil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Parentis, Monica Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Gottifredi, Juan Carlos Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaElsevier Science2006-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66911Gonzo, Elio Emilio; Parentis, Monica Liliana; Gottifredi, Juan Carlos Agustin; Estimating models for predicting effective permeability of mixed matrix membranes; Elsevier Science; Journal of Membrane Science; 277; 1-2; 6-2006; 46-540376-7388CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.memsci.2005.10.007info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0376738805007349info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:24:24Zoai:ri.conicet.gov.ar:11336/66911instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:24:25.053CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Estimating models for predicting effective permeability of mixed matrix membranes |
title |
Estimating models for predicting effective permeability of mixed matrix membranes |
spellingShingle |
Estimating models for predicting effective permeability of mixed matrix membranes Gonzo, Elio Emilio Maxwell Model Membrane Mixed Matrix Permeation Selectivity |
title_short |
Estimating models for predicting effective permeability of mixed matrix membranes |
title_full |
Estimating models for predicting effective permeability of mixed matrix membranes |
title_fullStr |
Estimating models for predicting effective permeability of mixed matrix membranes |
title_full_unstemmed |
Estimating models for predicting effective permeability of mixed matrix membranes |
title_sort |
Estimating models for predicting effective permeability of mixed matrix membranes |
dc.creator.none.fl_str_mv |
Gonzo, Elio Emilio Parentis, Monica Liliana Gottifredi, Juan Carlos Agustin |
author |
Gonzo, Elio Emilio |
author_facet |
Gonzo, Elio Emilio Parentis, Monica Liliana Gottifredi, Juan Carlos Agustin |
author_role |
author |
author2 |
Parentis, Monica Liliana Gottifredi, Juan Carlos Agustin |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Maxwell Model Membrane Mixed Matrix Permeation Selectivity |
topic |
Maxwell Model Membrane Mixed Matrix Permeation Selectivity |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Mixed matrix membranes have become a highly potential unique materials in many engineering application to overcome limitations presented by other products. In this contribution, an improved form of Maxwell's equation (the extended Maxwell equation) based on the hard-sphere model fluid proposed by Chiew and Glandt [Y.C. Chiew, E.D. Glandt, The effect of structure on the conductivity of a dispersion, J. Colloid Interface Sci. 94 (1983) 90-104] is evolved. The resulting equation allows the estimation of the effective permeability of composite membranes as a function of the reduced permeation polarizability and the volume fraction of the filler. This method can be applied to estimate effective permeability of gases and liquids through mixed matrix membranes prepared with different polymer matrix, as continuous phase, and organic (polymer or liquid crystal mixture) or inorganic (zeolites, activated carbons) compounds as filler even at relatively high volume fractions of this compound. A comparison among estimated values of the effective permeability and experimental data reported in the literature generally shows good agreement although there are a number of observations that are not easily explained with any of these models. © 2005 Elsevier B.V. All rights reserved. Fil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina Fil: Parentis, Monica Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina Fil: Gottifredi, Juan Carlos Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina |
description |
Mixed matrix membranes have become a highly potential unique materials in many engineering application to overcome limitations presented by other products. In this contribution, an improved form of Maxwell's equation (the extended Maxwell equation) based on the hard-sphere model fluid proposed by Chiew and Glandt [Y.C. Chiew, E.D. Glandt, The effect of structure on the conductivity of a dispersion, J. Colloid Interface Sci. 94 (1983) 90-104] is evolved. The resulting equation allows the estimation of the effective permeability of composite membranes as a function of the reduced permeation polarizability and the volume fraction of the filler. This method can be applied to estimate effective permeability of gases and liquids through mixed matrix membranes prepared with different polymer matrix, as continuous phase, and organic (polymer or liquid crystal mixture) or inorganic (zeolites, activated carbons) compounds as filler even at relatively high volume fractions of this compound. A comparison among estimated values of the effective permeability and experimental data reported in the literature generally shows good agreement although there are a number of observations that are not easily explained with any of these models. © 2005 Elsevier B.V. All rights reserved. |
publishDate |
2006 |
dc.date.none.fl_str_mv |
2006-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/66911 Gonzo, Elio Emilio; Parentis, Monica Liliana; Gottifredi, Juan Carlos Agustin; Estimating models for predicting effective permeability of mixed matrix membranes; Elsevier Science; Journal of Membrane Science; 277; 1-2; 6-2006; 46-54 0376-7388 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/66911 |
identifier_str_mv |
Gonzo, Elio Emilio; Parentis, Monica Liliana; Gottifredi, Juan Carlos Agustin; Estimating models for predicting effective permeability of mixed matrix membranes; Elsevier Science; Journal of Membrane Science; 277; 1-2; 6-2006; 46-54 0376-7388 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.memsci.2005.10.007 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0376738805007349 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.22299 |