Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone

Autores
Gañan, Nicolas Alberto; Dambolena, Jose Sebastian; Martini, Raquel Evangelina; Bottini, Susana Beatriz
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Low-menthol or dementholized oils can be regarded as potential sources of biocidal compounds, particularly monoterpenic ketones such as menthone, piperitone, piperitenone, pulegone and carvone. In this work, the recovery of piperitenone from peppermint oil by supercritical carbon dioxide fractionation is studied. Separation selectivity and gas loading measurements were performed in a semicontinuous high-pressure apparatus in order to evaluate the effect of temperature and solvent density on these properties. Semicontinuous fractionation was also carried out at a fixed temperature (313 K) and pressure (85 bar), collecting and analyzing extract samples until a purified piperitenone raffinate was obtained. The phase behavior of the system was modeled and predicted with the group contribution equation of state (GC-EOS). Good agreement with the experimental results was obtained. Finally, a continuous countercurrent multistage fractionation process was simulated, based on the GC-EOS model. The effect of operation temperature and pressure, solvent-to-feed ratio and reflux ratio was studied for different purity and recovery requirements and oil feed compositions.
Fil: Gañan, Nicolas Alberto. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Dambolena, Jose Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina. Universidad Nacional de Córdoba; Argentina
Fil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina
Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina
Materia
Peppermint Oil
Supercritical Fluid Fractionation
Gc-Eos
Countercurrent Fractionation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/10518
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenoneGañan, Nicolas AlbertoDambolena, Jose SebastianMartini, Raquel EvangelinaBottini, Susana BeatrizPeppermint OilSupercritical Fluid FractionationGc-EosCountercurrent Fractionationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Low-menthol or dementholized oils can be regarded as potential sources of biocidal compounds, particularly monoterpenic ketones such as menthone, piperitone, piperitenone, pulegone and carvone. In this work, the recovery of piperitenone from peppermint oil by supercritical carbon dioxide fractionation is studied. Separation selectivity and gas loading measurements were performed in a semicontinuous high-pressure apparatus in order to evaluate the effect of temperature and solvent density on these properties. Semicontinuous fractionation was also carried out at a fixed temperature (313 K) and pressure (85 bar), collecting and analyzing extract samples until a purified piperitenone raffinate was obtained. The phase behavior of the system was modeled and predicted with the group contribution equation of state (GC-EOS). Good agreement with the experimental results was obtained. Finally, a continuous countercurrent multistage fractionation process was simulated, based on the GC-EOS model. The effect of operation temperature and pressure, solvent-to-feed ratio and reflux ratio was studied for different purity and recovery requirements and oil feed compositions.Fil: Gañan, Nicolas Alberto. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba; ArgentinaFil: Dambolena, Jose Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina. Universidad Nacional de Córdoba; ArgentinaFil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; ArgentinaFil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; ArgentinaElsevier Science2015-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10518Gañan, Nicolas Alberto; Dambolena, Jose Sebastian; Martini, Raquel Evangelina; Bottini, Susana Beatriz; Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone; Elsevier Science; Journal of Supercritical Fluids; 98; 3-2015; 1-110896-8446enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S089684461400429Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.supflu.2014.12.018info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:13Zoai:ri.conicet.gov.ar:11336/10518instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:13.681CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone
title Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone
spellingShingle Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone
Gañan, Nicolas Alberto
Peppermint Oil
Supercritical Fluid Fractionation
Gc-Eos
Countercurrent Fractionation
title_short Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone
title_full Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone
title_fullStr Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone
title_full_unstemmed Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone
title_sort Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone
dc.creator.none.fl_str_mv Gañan, Nicolas Alberto
Dambolena, Jose Sebastian
Martini, Raquel Evangelina
Bottini, Susana Beatriz
author Gañan, Nicolas Alberto
author_facet Gañan, Nicolas Alberto
Dambolena, Jose Sebastian
Martini, Raquel Evangelina
Bottini, Susana Beatriz
author_role author
author2 Dambolena, Jose Sebastian
Martini, Raquel Evangelina
Bottini, Susana Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv Peppermint Oil
Supercritical Fluid Fractionation
Gc-Eos
Countercurrent Fractionation
topic Peppermint Oil
Supercritical Fluid Fractionation
Gc-Eos
Countercurrent Fractionation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Low-menthol or dementholized oils can be regarded as potential sources of biocidal compounds, particularly monoterpenic ketones such as menthone, piperitone, piperitenone, pulegone and carvone. In this work, the recovery of piperitenone from peppermint oil by supercritical carbon dioxide fractionation is studied. Separation selectivity and gas loading measurements were performed in a semicontinuous high-pressure apparatus in order to evaluate the effect of temperature and solvent density on these properties. Semicontinuous fractionation was also carried out at a fixed temperature (313 K) and pressure (85 bar), collecting and analyzing extract samples until a purified piperitenone raffinate was obtained. The phase behavior of the system was modeled and predicted with the group contribution equation of state (GC-EOS). Good agreement with the experimental results was obtained. Finally, a continuous countercurrent multistage fractionation process was simulated, based on the GC-EOS model. The effect of operation temperature and pressure, solvent-to-feed ratio and reflux ratio was studied for different purity and recovery requirements and oil feed compositions.
Fil: Gañan, Nicolas Alberto. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Dambolena, Jose Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina. Universidad Nacional de Córdoba; Argentina
Fil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina
Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina
description Low-menthol or dementholized oils can be regarded as potential sources of biocidal compounds, particularly monoterpenic ketones such as menthone, piperitone, piperitenone, pulegone and carvone. In this work, the recovery of piperitenone from peppermint oil by supercritical carbon dioxide fractionation is studied. Separation selectivity and gas loading measurements were performed in a semicontinuous high-pressure apparatus in order to evaluate the effect of temperature and solvent density on these properties. Semicontinuous fractionation was also carried out at a fixed temperature (313 K) and pressure (85 bar), collecting and analyzing extract samples until a purified piperitenone raffinate was obtained. The phase behavior of the system was modeled and predicted with the group contribution equation of state (GC-EOS). Good agreement with the experimental results was obtained. Finally, a continuous countercurrent multistage fractionation process was simulated, based on the GC-EOS model. The effect of operation temperature and pressure, solvent-to-feed ratio and reflux ratio was studied for different purity and recovery requirements and oil feed compositions.
publishDate 2015
dc.date.none.fl_str_mv 2015-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/10518
Gañan, Nicolas Alberto; Dambolena, Jose Sebastian; Martini, Raquel Evangelina; Bottini, Susana Beatriz; Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone; Elsevier Science; Journal of Supercritical Fluids; 98; 3-2015; 1-11
0896-8446
url http://hdl.handle.net/11336/10518
identifier_str_mv Gañan, Nicolas Alberto; Dambolena, Jose Sebastian; Martini, Raquel Evangelina; Bottini, Susana Beatriz; Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone; Elsevier Science; Journal of Supercritical Fluids; 98; 3-2015; 1-11
0896-8446
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S089684461400429X
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.supflu.2014.12.018
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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