Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone
- Autores
- Gañan, Nicolas Alberto; Dambolena, Jose Sebastian; Martini, Raquel Evangelina; Bottini, Susana Beatriz
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Low-menthol or dementholized oils can be regarded as potential sources of biocidal compounds, particularly monoterpenic ketones such as menthone, piperitone, piperitenone, pulegone and carvone. In this work, the recovery of piperitenone from peppermint oil by supercritical carbon dioxide fractionation is studied. Separation selectivity and gas loading measurements were performed in a semicontinuous high-pressure apparatus in order to evaluate the effect of temperature and solvent density on these properties. Semicontinuous fractionation was also carried out at a fixed temperature (313 K) and pressure (85 bar), collecting and analyzing extract samples until a purified piperitenone raffinate was obtained. The phase behavior of the system was modeled and predicted with the group contribution equation of state (GC-EOS). Good agreement with the experimental results was obtained. Finally, a continuous countercurrent multistage fractionation process was simulated, based on the GC-EOS model. The effect of operation temperature and pressure, solvent-to-feed ratio and reflux ratio was studied for different purity and recovery requirements and oil feed compositions.
Fil: Gañan, Nicolas Alberto. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Dambolena, Jose Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina. Universidad Nacional de Córdoba; Argentina
Fil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina
Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina - Materia
-
Peppermint Oil
Supercritical Fluid Fractionation
Gc-Eos
Countercurrent Fractionation - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/10518
Ver los metadatos del registro completo
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Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenoneGañan, Nicolas AlbertoDambolena, Jose SebastianMartini, Raquel EvangelinaBottini, Susana BeatrizPeppermint OilSupercritical Fluid FractionationGc-EosCountercurrent Fractionationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Low-menthol or dementholized oils can be regarded as potential sources of biocidal compounds, particularly monoterpenic ketones such as menthone, piperitone, piperitenone, pulegone and carvone. In this work, the recovery of piperitenone from peppermint oil by supercritical carbon dioxide fractionation is studied. Separation selectivity and gas loading measurements were performed in a semicontinuous high-pressure apparatus in order to evaluate the effect of temperature and solvent density on these properties. Semicontinuous fractionation was also carried out at a fixed temperature (313 K) and pressure (85 bar), collecting and analyzing extract samples until a purified piperitenone raffinate was obtained. The phase behavior of the system was modeled and predicted with the group contribution equation of state (GC-EOS). Good agreement with the experimental results was obtained. Finally, a continuous countercurrent multistage fractionation process was simulated, based on the GC-EOS model. The effect of operation temperature and pressure, solvent-to-feed ratio and reflux ratio was studied for different purity and recovery requirements and oil feed compositions.Fil: Gañan, Nicolas Alberto. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba; ArgentinaFil: Dambolena, Jose Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina. Universidad Nacional de Córdoba; ArgentinaFil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; ArgentinaFil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; ArgentinaElsevier Science2015-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10518Gañan, Nicolas Alberto; Dambolena, Jose Sebastian; Martini, Raquel Evangelina; Bottini, Susana Beatriz; Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone; Elsevier Science; Journal of Supercritical Fluids; 98; 3-2015; 1-110896-8446enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S089684461400429Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.supflu.2014.12.018info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:48:14Zoai:ri.conicet.gov.ar:11336/10518instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:48:15.109CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone |
title |
Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone |
spellingShingle |
Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone Gañan, Nicolas Alberto Peppermint Oil Supercritical Fluid Fractionation Gc-Eos Countercurrent Fractionation |
title_short |
Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone |
title_full |
Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone |
title_fullStr |
Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone |
title_full_unstemmed |
Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone |
title_sort |
Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone |
dc.creator.none.fl_str_mv |
Gañan, Nicolas Alberto Dambolena, Jose Sebastian Martini, Raquel Evangelina Bottini, Susana Beatriz |
author |
Gañan, Nicolas Alberto |
author_facet |
Gañan, Nicolas Alberto Dambolena, Jose Sebastian Martini, Raquel Evangelina Bottini, Susana Beatriz |
author_role |
author |
author2 |
Dambolena, Jose Sebastian Martini, Raquel Evangelina Bottini, Susana Beatriz |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Peppermint Oil Supercritical Fluid Fractionation Gc-Eos Countercurrent Fractionation |
topic |
Peppermint Oil Supercritical Fluid Fractionation Gc-Eos Countercurrent Fractionation |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Low-menthol or dementholized oils can be regarded as potential sources of biocidal compounds, particularly monoterpenic ketones such as menthone, piperitone, piperitenone, pulegone and carvone. In this work, the recovery of piperitenone from peppermint oil by supercritical carbon dioxide fractionation is studied. Separation selectivity and gas loading measurements were performed in a semicontinuous high-pressure apparatus in order to evaluate the effect of temperature and solvent density on these properties. Semicontinuous fractionation was also carried out at a fixed temperature (313 K) and pressure (85 bar), collecting and analyzing extract samples until a purified piperitenone raffinate was obtained. The phase behavior of the system was modeled and predicted with the group contribution equation of state (GC-EOS). Good agreement with the experimental results was obtained. Finally, a continuous countercurrent multistage fractionation process was simulated, based on the GC-EOS model. The effect of operation temperature and pressure, solvent-to-feed ratio and reflux ratio was studied for different purity and recovery requirements and oil feed compositions. Fil: Gañan, Nicolas Alberto. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina Fil: Dambolena, Jose Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina. Universidad Nacional de Córdoba; Argentina Fil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina |
description |
Low-menthol or dementholized oils can be regarded as potential sources of biocidal compounds, particularly monoterpenic ketones such as menthone, piperitone, piperitenone, pulegone and carvone. In this work, the recovery of piperitenone from peppermint oil by supercritical carbon dioxide fractionation is studied. Separation selectivity and gas loading measurements were performed in a semicontinuous high-pressure apparatus in order to evaluate the effect of temperature and solvent density on these properties. Semicontinuous fractionation was also carried out at a fixed temperature (313 K) and pressure (85 bar), collecting and analyzing extract samples until a purified piperitenone raffinate was obtained. The phase behavior of the system was modeled and predicted with the group contribution equation of state (GC-EOS). Good agreement with the experimental results was obtained. Finally, a continuous countercurrent multistage fractionation process was simulated, based on the GC-EOS model. The effect of operation temperature and pressure, solvent-to-feed ratio and reflux ratio was studied for different purity and recovery requirements and oil feed compositions. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/10518 Gañan, Nicolas Alberto; Dambolena, Jose Sebastian; Martini, Raquel Evangelina; Bottini, Susana Beatriz; Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone; Elsevier Science; Journal of Supercritical Fluids; 98; 3-2015; 1-11 0896-8446 |
url |
http://hdl.handle.net/11336/10518 |
identifier_str_mv |
Gañan, Nicolas Alberto; Dambolena, Jose Sebastian; Martini, Raquel Evangelina; Bottini, Susana Beatriz; Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone; Elsevier Science; Journal of Supercritical Fluids; 98; 3-2015; 1-11 0896-8446 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S089684461400429X info:eu-repo/semantics/altIdentifier/doi/10.1016/j.supflu.2014.12.018 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268913072603136 |
score |
13.13397 |