Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour

Autores
Rivero, Guadalupe; Villanueva, Sara; Manfredi, Liliana Beatriz
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Nanocomposites based on a furan resin and different types of clays were obtained. Their thermal and fire behaviours were compared with traditional phenolic resins, which are known by their excellent flame resistance. Three types of montmorillonite clays were in situ added to the thermosetting matrix. A cone calorimeter and a smoke chamber were used to evaluate the performance of the materials against fire and their smokes generation. Global parameters were calculated for comparison purposes. Fires derived from the furan resin combustion grow faster than the phenolic ones, but they are extinguished more rapidly. This effect is enhanced by the incorporation of inorganic nanofillers. The only addition of any clay causes shorter fires but slightly speeds up the degradation process. A homogeneous nanofiller dispersion was found to be crucial to achieve good fire behaviour. Nevertheless, formaterials with similar dispersion, the crosslinking degree of the polymer matrix appears as a secondary factor that determines slighter differences in the performance. Nanocomposites with organomodified clays showed a quite similar fire performance, though the composite containing the clay (Southern Clay Products, Inc., Louisville, Ky, USA) Cloisite®30B showed the best performance taking into account both the fire risk and the smoke evolution and obscuration.
Fil: Rivero, Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Villanueva, Sara. Unidad de Construcción; España
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Furan Resin
Clay
Fire Behaviour
Smoke Evolution
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5184
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviourRivero, GuadalupeVillanueva, SaraManfredi, Liliana BeatrizFuran ResinClayFire BehaviourSmoke Evolutionhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Nanocomposites based on a furan resin and different types of clays were obtained. Their thermal and fire behaviours were compared with traditional phenolic resins, which are known by their excellent flame resistance. Three types of montmorillonite clays were in situ added to the thermosetting matrix. A cone calorimeter and a smoke chamber were used to evaluate the performance of the materials against fire and their smokes generation. Global parameters were calculated for comparison purposes. Fires derived from the furan resin combustion grow faster than the phenolic ones, but they are extinguished more rapidly. This effect is enhanced by the incorporation of inorganic nanofillers. The only addition of any clay causes shorter fires but slightly speeds up the degradation process. A homogeneous nanofiller dispersion was found to be crucial to achieve good fire behaviour. Nevertheless, formaterials with similar dispersion, the crosslinking degree of the polymer matrix appears as a secondary factor that determines slighter differences in the performance. Nanocomposites with organomodified clays showed a quite similar fire performance, though the composite containing the clay (Southern Clay Products, Inc., Louisville, Ky, USA) Cloisite®30B showed the best performance taking into account both the fire risk and the smoke evolution and obscuration.Fil: Rivero, Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Villanueva, Sara. Unidad de Construcción; EspañaFil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaWiley2014-09-22info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5184Rivero, Guadalupe; Villanueva, Sara; Manfredi, Liliana Beatriz; Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour; Wiley; Fire and Materials; 38; 6; 22-9-2014; 683-6940308-0501enginfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/issn/0308-0501info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/fam.2209/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/fam.2209info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:14:00Zoai:ri.conicet.gov.ar:11336/5184instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:14:00.569CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour
title Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour
spellingShingle Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour
Rivero, Guadalupe
Furan Resin
Clay
Fire Behaviour
Smoke Evolution
title_short Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour
title_full Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour
title_fullStr Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour
title_full_unstemmed Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour
title_sort Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour
dc.creator.none.fl_str_mv Rivero, Guadalupe
Villanueva, Sara
Manfredi, Liliana Beatriz
author Rivero, Guadalupe
author_facet Rivero, Guadalupe
Villanueva, Sara
Manfredi, Liliana Beatriz
author_role author
author2 Villanueva, Sara
Manfredi, Liliana Beatriz
author2_role author
author
dc.subject.none.fl_str_mv Furan Resin
Clay
Fire Behaviour
Smoke Evolution
topic Furan Resin
Clay
Fire Behaviour
Smoke Evolution
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Nanocomposites based on a furan resin and different types of clays were obtained. Their thermal and fire behaviours were compared with traditional phenolic resins, which are known by their excellent flame resistance. Three types of montmorillonite clays were in situ added to the thermosetting matrix. A cone calorimeter and a smoke chamber were used to evaluate the performance of the materials against fire and their smokes generation. Global parameters were calculated for comparison purposes. Fires derived from the furan resin combustion grow faster than the phenolic ones, but they are extinguished more rapidly. This effect is enhanced by the incorporation of inorganic nanofillers. The only addition of any clay causes shorter fires but slightly speeds up the degradation process. A homogeneous nanofiller dispersion was found to be crucial to achieve good fire behaviour. Nevertheless, formaterials with similar dispersion, the crosslinking degree of the polymer matrix appears as a secondary factor that determines slighter differences in the performance. Nanocomposites with organomodified clays showed a quite similar fire performance, though the composite containing the clay (Southern Clay Products, Inc., Louisville, Ky, USA) Cloisite®30B showed the best performance taking into account both the fire risk and the smoke evolution and obscuration.
Fil: Rivero, Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Villanueva, Sara. Unidad de Construcción; España
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description Nanocomposites based on a furan resin and different types of clays were obtained. Their thermal and fire behaviours were compared with traditional phenolic resins, which are known by their excellent flame resistance. Three types of montmorillonite clays were in situ added to the thermosetting matrix. A cone calorimeter and a smoke chamber were used to evaluate the performance of the materials against fire and their smokes generation. Global parameters were calculated for comparison purposes. Fires derived from the furan resin combustion grow faster than the phenolic ones, but they are extinguished more rapidly. This effect is enhanced by the incorporation of inorganic nanofillers. The only addition of any clay causes shorter fires but slightly speeds up the degradation process. A homogeneous nanofiller dispersion was found to be crucial to achieve good fire behaviour. Nevertheless, formaterials with similar dispersion, the crosslinking degree of the polymer matrix appears as a secondary factor that determines slighter differences in the performance. Nanocomposites with organomodified clays showed a quite similar fire performance, though the composite containing the clay (Southern Clay Products, Inc., Louisville, Ky, USA) Cloisite®30B showed the best performance taking into account both the fire risk and the smoke evolution and obscuration.
publishDate 2014
dc.date.none.fl_str_mv 2014-09-22
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5184
Rivero, Guadalupe; Villanueva, Sara; Manfredi, Liliana Beatriz; Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour; Wiley; Fire and Materials; 38; 6; 22-9-2014; 683-694
0308-0501
url http://hdl.handle.net/11336/5184
identifier_str_mv Rivero, Guadalupe; Villanueva, Sara; Manfredi, Liliana Beatriz; Furan resin as a replacement of phenolics: influence of the clay addition on its thermal degradation and fire behaviour; Wiley; Fire and Materials; 38; 6; 22-9-2014; 683-694
0308-0501
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/issn/0308-0501
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/fam.2209/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/fam.2209
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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