Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization

Autores
Rivero, Guadalupe; Fasce, Laura Alejandra; Cere, Silvia; Manfredi, Liliana Beatriz
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Phenolic coatings are usually a convenient and economical way to protect metallic materials against wear and corrosion. Furan resins are analogous to phenolics, as they are obtained by replacing formaldehyde by furfural in their formulation. In this work, a furan resin based on furfural and phenol was synthesized and used as an aluminum coating. Thus, toxic emissions of formaldehyde were avoided, while a biobased derivative was used instead. The performance of the proposed resin was compared with the one of a traditional phenolic resin. Physicochemical characteristics including chemical structure, surface polarity and glass transition temperature were evaluated by means of Fourier transform infrared spectroscopy, contact angle measurements and dynamic-mechanical analysis, respectively. Nanomechanical and nanotribological properties were assessed by depth sensing indentation techniques. As well, the corrosion resistance of the furan coating was determined by potentiodynamic polarization tests. The obtained results validate the furan resin as a feasible alternative to phenolics to protect aluminum.
Fil: Rivero, Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Cere, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Furan Resins
Phenolic Resins
Nanoindentation
Protective Organic Coatings
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/4944
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/4944
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterizationRivero, GuadalupeFasce, Laura AlejandraCere, SilviaManfredi, Liliana BeatrizFuran ResinsPhenolic ResinsNanoindentationProtective Organic Coatingshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Phenolic coatings are usually a convenient and economical way to protect metallic materials against wear and corrosion. Furan resins are analogous to phenolics, as they are obtained by replacing formaldehyde by furfural in their formulation. In this work, a furan resin based on furfural and phenol was synthesized and used as an aluminum coating. Thus, toxic emissions of formaldehyde were avoided, while a biobased derivative was used instead. The performance of the proposed resin was compared with the one of a traditional phenolic resin. Physicochemical characteristics including chemical structure, surface polarity and glass transition temperature were evaluated by means of Fourier transform infrared spectroscopy, contact angle measurements and dynamic-mechanical analysis, respectively. Nanomechanical and nanotribological properties were assessed by depth sensing indentation techniques. As well, the corrosion resistance of the furan coating was determined by potentiodynamic polarization tests. The obtained results validate the furan resin as a feasible alternative to phenolics to protect aluminum.Fil: Rivero, Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Cere, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaElsevier2013-10-27info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/4944Rivero, Guadalupe; Fasce, Laura Alejandra; Cere, Silvia; Manfredi, Liliana Beatriz; Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization; Elsevier; Progress In Organic Coatings; 77; 1; 27-10-2013; 247-2560300-9440enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0300944013002609info:eu-repo/semantics/altIdentifier/issn/0300-9440info:eu-repo/semantics/altIdentifier/doi/10.1016/j.porgcoat.2013.09.015info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:21:11Zoai:ri.conicet.gov.ar:11336/4944instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:21:11.555CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization
title Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization
spellingShingle Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization
Rivero, Guadalupe
Furan Resins
Phenolic Resins
Nanoindentation
Protective Organic Coatings
title_short Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization
title_full Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization
title_fullStr Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization
title_full_unstemmed Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization
title_sort Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization
dc.creator.none.fl_str_mv Rivero, Guadalupe
Fasce, Laura Alejandra
Cere, Silvia
Manfredi, Liliana Beatriz
author Rivero, Guadalupe
author_facet Rivero, Guadalupe
Fasce, Laura Alejandra
Cere, Silvia
Manfredi, Liliana Beatriz
author_role author
author2 Fasce, Laura Alejandra
Cere, Silvia
Manfredi, Liliana Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv Furan Resins
Phenolic Resins
Nanoindentation
Protective Organic Coatings
topic Furan Resins
Phenolic Resins
Nanoindentation
Protective Organic Coatings
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Phenolic coatings are usually a convenient and economical way to protect metallic materials against wear and corrosion. Furan resins are analogous to phenolics, as they are obtained by replacing formaldehyde by furfural in their formulation. In this work, a furan resin based on furfural and phenol was synthesized and used as an aluminum coating. Thus, toxic emissions of formaldehyde were avoided, while a biobased derivative was used instead. The performance of the proposed resin was compared with the one of a traditional phenolic resin. Physicochemical characteristics including chemical structure, surface polarity and glass transition temperature were evaluated by means of Fourier transform infrared spectroscopy, contact angle measurements and dynamic-mechanical analysis, respectively. Nanomechanical and nanotribological properties were assessed by depth sensing indentation techniques. As well, the corrosion resistance of the furan coating was determined by potentiodynamic polarization tests. The obtained results validate the furan resin as a feasible alternative to phenolics to protect aluminum.
Fil: Rivero, Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Cere, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description Phenolic coatings are usually a convenient and economical way to protect metallic materials against wear and corrosion. Furan resins are analogous to phenolics, as they are obtained by replacing formaldehyde by furfural in their formulation. In this work, a furan resin based on furfural and phenol was synthesized and used as an aluminum coating. Thus, toxic emissions of formaldehyde were avoided, while a biobased derivative was used instead. The performance of the proposed resin was compared with the one of a traditional phenolic resin. Physicochemical characteristics including chemical structure, surface polarity and glass transition temperature were evaluated by means of Fourier transform infrared spectroscopy, contact angle measurements and dynamic-mechanical analysis, respectively. Nanomechanical and nanotribological properties were assessed by depth sensing indentation techniques. As well, the corrosion resistance of the furan coating was determined by potentiodynamic polarization tests. The obtained results validate the furan resin as a feasible alternative to phenolics to protect aluminum.
publishDate 2013
dc.date.none.fl_str_mv 2013-10-27
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/4944
Rivero, Guadalupe; Fasce, Laura Alejandra; Cere, Silvia; Manfredi, Liliana Beatriz; Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization; Elsevier; Progress In Organic Coatings; 77; 1; 27-10-2013; 247-256
0300-9440
url http://hdl.handle.net/11336/4944
identifier_str_mv Rivero, Guadalupe; Fasce, Laura Alejandra; Cere, Silvia; Manfredi, Liliana Beatriz; Furan resins as replacement of phenolic protective coatings: Structural, mechanical and functional characterization; Elsevier; Progress In Organic Coatings; 77; 1; 27-10-2013; 247-256
0300-9440
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0300944013002609
info:eu-repo/semantics/altIdentifier/issn/0300-9440
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.porgcoat.2013.09.015
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.48226

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