Curing kinetics of a furan resin and its nanocomposites

Autores
Rivero, Guadalupe; Pettarin, Valeria; Vazquez, Analia; Manfredi, Liliana Beatriz
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A furan resin was synthesized from furfural and phenol and it was expected to have similar properties to the commonly used phenolic resins because the former was obtained by the replacement of formaldehyde by furfural, reducing the dangerous formaldehyde emissions. In the present work, nanocomposites were obtained by the in situ addition of 2% of different types of clays to the furan resin to enhance the polymer performance. Montmorillonite natural clay Cloisite® Na+ and the chemically modified ones, Cloisite® 30B and Cloisite® 10A were used. A clay dispersion comparison among the nanocomposites was performed. The curing kinetics of the furan resin and its composites was characterized by Differential Scanning Calorimetry. Free kinetic models were applied in order to obtain and compare the activation energy of each process. Vyazovkin numerical analysis was found to provide the most accurate method to analyze the variation of the activation energy (E) with the reaction conversion. Some differences arise in the activation energy vs. conversion profile among the materials studied. These differences were related to the variations in the viscosity and the chemical groups with the evolution of the curing reaction, followed by infrared spectroscopy. The nanocomposites containing the organically modified clays showed an additional peak in the last stage of the curing process due to parallel reactions including the beginning of the organic modifier decomposition.
Fil: Rivero, Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Fil: Pettarin, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Fil: Vazquez, Analia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; Argentina; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; Argentina
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Materia
Furan Resin
Clay
Nanocomposite
Kinetic
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/14741
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/14741
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Curing kinetics of a furan resin and its nanocompositesRivero, GuadalupePettarin, ValeriaVazquez, AnaliaManfredi, Liliana BeatrizFuran ResinClayNanocompositeKinetichttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2A furan resin was synthesized from furfural and phenol and it was expected to have similar properties to the commonly used phenolic resins because the former was obtained by the replacement of formaldehyde by furfural, reducing the dangerous formaldehyde emissions. In the present work, nanocomposites were obtained by the in situ addition of 2% of different types of clays to the furan resin to enhance the polymer performance. Montmorillonite natural clay Cloisite® Na+ and the chemically modified ones, Cloisite® 30B and Cloisite® 10A were used. A clay dispersion comparison among the nanocomposites was performed. The curing kinetics of the furan resin and its composites was characterized by Differential Scanning Calorimetry. Free kinetic models were applied in order to obtain and compare the activation energy of each process. Vyazovkin numerical analysis was found to provide the most accurate method to analyze the variation of the activation energy (E) with the reaction conversion. Some differences arise in the activation energy vs. conversion profile among the materials studied. These differences were related to the variations in the viscosity and the chemical groups with the evolution of the curing reaction, followed by infrared spectroscopy. The nanocomposites containing the organically modified clays showed an additional peak in the last stage of the curing process due to parallel reactions including the beginning of the organic modifier decomposition.Fil: Rivero, Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; ArgentinaFil: Pettarin, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; ArgentinaFil: Vazquez, Analia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; Argentina; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; ArgentinaFil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; ArgentinaElsevier Science2011-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/14741Rivero, Guadalupe; Pettarin, Valeria; Vazquez, Analia; Manfredi, Liliana Beatriz; Curing kinetics of a furan resin and its nanocomposites; Elsevier Science; Thermochimica Acta; 516; 1-2; 3-2011; 79-870040-6031enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S004060311100044Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.tca.2011.01.022info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:04:58Zoai:ri.conicet.gov.ar:11336/14741instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:04:58.867CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Curing kinetics of a furan resin and its nanocomposites
title Curing kinetics of a furan resin and its nanocomposites
spellingShingle Curing kinetics of a furan resin and its nanocomposites
Rivero, Guadalupe
Furan Resin
Clay
Nanocomposite
Kinetic
title_short Curing kinetics of a furan resin and its nanocomposites
title_full Curing kinetics of a furan resin and its nanocomposites
title_fullStr Curing kinetics of a furan resin and its nanocomposites
title_full_unstemmed Curing kinetics of a furan resin and its nanocomposites
title_sort Curing kinetics of a furan resin and its nanocomposites
dc.creator.none.fl_str_mv Rivero, Guadalupe
Pettarin, Valeria
Vazquez, Analia
Manfredi, Liliana Beatriz
author Rivero, Guadalupe
author_facet Rivero, Guadalupe
Pettarin, Valeria
Vazquez, Analia
Manfredi, Liliana Beatriz
author_role author
author2 Pettarin, Valeria
Vazquez, Analia
Manfredi, Liliana Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv Furan Resin
Clay
Nanocomposite
Kinetic
topic Furan Resin
Clay
Nanocomposite
Kinetic
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A furan resin was synthesized from furfural and phenol and it was expected to have similar properties to the commonly used phenolic resins because the former was obtained by the replacement of formaldehyde by furfural, reducing the dangerous formaldehyde emissions. In the present work, nanocomposites were obtained by the in situ addition of 2% of different types of clays to the furan resin to enhance the polymer performance. Montmorillonite natural clay Cloisite® Na+ and the chemically modified ones, Cloisite® 30B and Cloisite® 10A were used. A clay dispersion comparison among the nanocomposites was performed. The curing kinetics of the furan resin and its composites was characterized by Differential Scanning Calorimetry. Free kinetic models were applied in order to obtain and compare the activation energy of each process. Vyazovkin numerical analysis was found to provide the most accurate method to analyze the variation of the activation energy (E) with the reaction conversion. Some differences arise in the activation energy vs. conversion profile among the materials studied. These differences were related to the variations in the viscosity and the chemical groups with the evolution of the curing reaction, followed by infrared spectroscopy. The nanocomposites containing the organically modified clays showed an additional peak in the last stage of the curing process due to parallel reactions including the beginning of the organic modifier decomposition.
Fil: Rivero, Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Fil: Pettarin, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Fil: Vazquez, Analia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; Argentina; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física. Laboratorio de Polímeros y Materiales Compuestos; Argentina
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
description A furan resin was synthesized from furfural and phenol and it was expected to have similar properties to the commonly used phenolic resins because the former was obtained by the replacement of formaldehyde by furfural, reducing the dangerous formaldehyde emissions. In the present work, nanocomposites were obtained by the in situ addition of 2% of different types of clays to the furan resin to enhance the polymer performance. Montmorillonite natural clay Cloisite® Na+ and the chemically modified ones, Cloisite® 30B and Cloisite® 10A were used. A clay dispersion comparison among the nanocomposites was performed. The curing kinetics of the furan resin and its composites was characterized by Differential Scanning Calorimetry. Free kinetic models were applied in order to obtain and compare the activation energy of each process. Vyazovkin numerical analysis was found to provide the most accurate method to analyze the variation of the activation energy (E) with the reaction conversion. Some differences arise in the activation energy vs. conversion profile among the materials studied. These differences were related to the variations in the viscosity and the chemical groups with the evolution of the curing reaction, followed by infrared spectroscopy. The nanocomposites containing the organically modified clays showed an additional peak in the last stage of the curing process due to parallel reactions including the beginning of the organic modifier decomposition.
publishDate 2011
dc.date.none.fl_str_mv 2011-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/14741
Rivero, Guadalupe; Pettarin, Valeria; Vazquez, Analia; Manfredi, Liliana Beatriz; Curing kinetics of a furan resin and its nanocomposites; Elsevier Science; Thermochimica Acta; 516; 1-2; 3-2011; 79-87
0040-6031
url http://hdl.handle.net/11336/14741
identifier_str_mv Rivero, Guadalupe; Pettarin, Valeria; Vazquez, Analia; Manfredi, Liliana Beatriz; Curing kinetics of a furan resin and its nanocomposites; Elsevier Science; Thermochimica Acta; 516; 1-2; 3-2011; 79-87
0040-6031
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S004060311100044X
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tca.2011.01.022
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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