Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil
- Autores
- Boldrini, Diego Emmanuel; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Partial hydrogenation of sunflower oil was studied over Pd/Al2O3/Al catalysts in a monolithic stirred reactor. The catalyst showed similar or even better activity and selectivity than conventional Pd/Al2O3 catalysts. However, in consecutive runs, a continuous decreasing activity was observed. In order to understand the deactivation phenomena, fresh and spent catalysts were characterized using temperature programmed reduction, N2 adsorption isotherms, dynamic H2 chemisorption, transmission electron microscopy (TEM), atomic absorption spectroscopy, inductively coupled plasma spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy, ultrasound adherence tests, and X-ray photoelectron spectroscopy. Furthermore, an extensive number of catalytic tests under different operating conditions were carried out. The loss in activity was proportional to the reduction in metal dispersion. The decrease in Pd dispersion was due to the coverage of the Pd surface. The deactivation occurred due to fouling with reaction residues most probably coming from polymerization and/or cross-linking reactions. The catalysts can be regenerated ex situ using a careful desorption–washing–calcination process, although this requires further research because the temperatures required are too high for Al.
Fil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina - Materia
-
Monolithic Catalyst
Hydrogenation
Vegetable Oil
Palladium
Deactivation
Oil Polymerization
Catalyst Regeneration - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/23549
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Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oilBoldrini, Diego EmmanuelTonetto, Gabriela MartaDamiani, Daniel EduardoMonolithic CatalystHydrogenationVegetable OilPalladiumDeactivationOil PolymerizationCatalyst Regenerationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Partial hydrogenation of sunflower oil was studied over Pd/Al2O3/Al catalysts in a monolithic stirred reactor. The catalyst showed similar or even better activity and selectivity than conventional Pd/Al2O3 catalysts. However, in consecutive runs, a continuous decreasing activity was observed. In order to understand the deactivation phenomena, fresh and spent catalysts were characterized using temperature programmed reduction, N2 adsorption isotherms, dynamic H2 chemisorption, transmission electron microscopy (TEM), atomic absorption spectroscopy, inductively coupled plasma spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy, ultrasound adherence tests, and X-ray photoelectron spectroscopy. Furthermore, an extensive number of catalytic tests under different operating conditions were carried out. The loss in activity was proportional to the reduction in metal dispersion. The decrease in Pd dispersion was due to the coverage of the Pd surface. The deactivation occurred due to fouling with reaction residues most probably coming from polymerization and/or cross-linking reactions. The catalysts can be regenerated ex situ using a careful desorption–washing–calcination process, although this requires further research because the temperatures required are too high for Al.Fil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science Sa2014-02-14info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/23549Boldrini, Diego Emmanuel; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil; Elsevier Science Sa; Chemical Engineering Journal; 270; 14-2-2014; 378-3841385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2015.02.029info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894715002272info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:07:43Zoai:ri.conicet.gov.ar:11336/23549instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:07:43.788CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil |
title |
Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil |
spellingShingle |
Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil Boldrini, Diego Emmanuel Monolithic Catalyst Hydrogenation Vegetable Oil Palladium Deactivation Oil Polymerization Catalyst Regeneration |
title_short |
Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil |
title_full |
Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil |
title_fullStr |
Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil |
title_full_unstemmed |
Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil |
title_sort |
Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil |
dc.creator.none.fl_str_mv |
Boldrini, Diego Emmanuel Tonetto, Gabriela Marta Damiani, Daniel Eduardo |
author |
Boldrini, Diego Emmanuel |
author_facet |
Boldrini, Diego Emmanuel Tonetto, Gabriela Marta Damiani, Daniel Eduardo |
author_role |
author |
author2 |
Tonetto, Gabriela Marta Damiani, Daniel Eduardo |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Monolithic Catalyst Hydrogenation Vegetable Oil Palladium Deactivation Oil Polymerization Catalyst Regeneration |
topic |
Monolithic Catalyst Hydrogenation Vegetable Oil Palladium Deactivation Oil Polymerization Catalyst Regeneration |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Partial hydrogenation of sunflower oil was studied over Pd/Al2O3/Al catalysts in a monolithic stirred reactor. The catalyst showed similar or even better activity and selectivity than conventional Pd/Al2O3 catalysts. However, in consecutive runs, a continuous decreasing activity was observed. In order to understand the deactivation phenomena, fresh and spent catalysts were characterized using temperature programmed reduction, N2 adsorption isotherms, dynamic H2 chemisorption, transmission electron microscopy (TEM), atomic absorption spectroscopy, inductively coupled plasma spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy, ultrasound adherence tests, and X-ray photoelectron spectroscopy. Furthermore, an extensive number of catalytic tests under different operating conditions were carried out. The loss in activity was proportional to the reduction in metal dispersion. The decrease in Pd dispersion was due to the coverage of the Pd surface. The deactivation occurred due to fouling with reaction residues most probably coming from polymerization and/or cross-linking reactions. The catalysts can be regenerated ex situ using a careful desorption–washing–calcination process, although this requires further research because the temperatures required are too high for Al. Fil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina |
description |
Partial hydrogenation of sunflower oil was studied over Pd/Al2O3/Al catalysts in a monolithic stirred reactor. The catalyst showed similar or even better activity and selectivity than conventional Pd/Al2O3 catalysts. However, in consecutive runs, a continuous decreasing activity was observed. In order to understand the deactivation phenomena, fresh and spent catalysts were characterized using temperature programmed reduction, N2 adsorption isotherms, dynamic H2 chemisorption, transmission electron microscopy (TEM), atomic absorption spectroscopy, inductively coupled plasma spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy, ultrasound adherence tests, and X-ray photoelectron spectroscopy. Furthermore, an extensive number of catalytic tests under different operating conditions were carried out. The loss in activity was proportional to the reduction in metal dispersion. The decrease in Pd dispersion was due to the coverage of the Pd surface. The deactivation occurred due to fouling with reaction residues most probably coming from polymerization and/or cross-linking reactions. The catalysts can be regenerated ex situ using a careful desorption–washing–calcination process, although this requires further research because the temperatures required are too high for Al. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-02-14 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/23549 Boldrini, Diego Emmanuel; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil; Elsevier Science Sa; Chemical Engineering Journal; 270; 14-2-2014; 378-384 1385-8947 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/23549 |
identifier_str_mv |
Boldrini, Diego Emmanuel; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Experimental study of the deactivation of Pd on anodized aluminum monoliths during the partial hydrogenation of vegetable oil; Elsevier Science Sa; Chemical Engineering Journal; 270; 14-2-2014; 378-384 1385-8947 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2015.02.029 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894715002272 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science Sa |
publisher.none.fl_str_mv |
Elsevier Science Sa |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842270015176310784 |
score |
13.13397 |