Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil

Autores
Sánchez Morales, Jhon Freddy; González Bello, Orlando J.; Montes, Mario; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Monolithic catalysts were prepared using cordierite and Fecralloy as substrates, with Pd/Al2O3 catalyst deposited by a washcoating method. The samples were characterized and studied for the partial hydrogenation of sunflower oil at 373 K and 413 kPa. In comparative tests, at equal operating conditions and conversion, the structured catalysts presented a lower trans-isomers formation than the powder catalyst. After three consecutive tests, the ceramic monolith showed no change in activity or selectivity, whereas the metallic monolith showed a partial deactivation (10%), which is attributed to a loss of catalyst. © 2009 Elsevier B.V. All rights reserved.
Fil: Sánchez Morales, Jhon Freddy. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: González Bello, Orlando J.. Universidad del País Vasco; España
Fil: Montes, Mario. Universidad del País Vasco; España
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Cordierite
Fecralloy
Hydrogenation
Monolithic Catalyst
Pd
Sunflower Oil
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/57778
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oilSánchez Morales, Jhon FreddyGonzález Bello, Orlando J.Montes, MarioTonetto, Gabriela MartaDamiani, Daniel EduardoCordieriteFecralloyHydrogenationMonolithic CatalystPdSunflower Oilhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Monolithic catalysts were prepared using cordierite and Fecralloy as substrates, with Pd/Al2O3 catalyst deposited by a washcoating method. The samples were characterized and studied for the partial hydrogenation of sunflower oil at 373 K and 413 kPa. In comparative tests, at equal operating conditions and conversion, the structured catalysts presented a lower trans-isomers formation than the powder catalyst. After three consecutive tests, the ceramic monolith showed no change in activity or selectivity, whereas the metallic monolith showed a partial deactivation (10%), which is attributed to a loss of catalyst. © 2009 Elsevier B.V. All rights reserved.Fil: Sánchez Morales, Jhon Freddy. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: González Bello, Orlando J.. Universidad del País Vasco; EspañaFil: Montes, Mario. Universidad del País Vasco; EspañaFil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science2009-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/57778Sánchez Morales, Jhon Freddy; González Bello, Orlando J.; Montes, Mario; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil; Elsevier Science; Catalysis Communications; 10; 10; 5-2009; 1446-14491566-7367CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2009.03.016info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736709001198info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:58:42Zoai:ri.conicet.gov.ar:11336/57778instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:58:43.2CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil
title Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil
spellingShingle Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil
Sánchez Morales, Jhon Freddy
Cordierite
Fecralloy
Hydrogenation
Monolithic Catalyst
Pd
Sunflower Oil
title_short Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil
title_full Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil
title_fullStr Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil
title_full_unstemmed Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil
title_sort Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil
dc.creator.none.fl_str_mv Sánchez Morales, Jhon Freddy
González Bello, Orlando J.
Montes, Mario
Tonetto, Gabriela Marta
Damiani, Daniel Eduardo
author Sánchez Morales, Jhon Freddy
author_facet Sánchez Morales, Jhon Freddy
González Bello, Orlando J.
Montes, Mario
Tonetto, Gabriela Marta
Damiani, Daniel Eduardo
author_role author
author2 González Bello, Orlando J.
Montes, Mario
Tonetto, Gabriela Marta
Damiani, Daniel Eduardo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Cordierite
Fecralloy
Hydrogenation
Monolithic Catalyst
Pd
Sunflower Oil
topic Cordierite
Fecralloy
Hydrogenation
Monolithic Catalyst
Pd
Sunflower Oil
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Monolithic catalysts were prepared using cordierite and Fecralloy as substrates, with Pd/Al2O3 catalyst deposited by a washcoating method. The samples were characterized and studied for the partial hydrogenation of sunflower oil at 373 K and 413 kPa. In comparative tests, at equal operating conditions and conversion, the structured catalysts presented a lower trans-isomers formation than the powder catalyst. After three consecutive tests, the ceramic monolith showed no change in activity or selectivity, whereas the metallic monolith showed a partial deactivation (10%), which is attributed to a loss of catalyst. © 2009 Elsevier B.V. All rights reserved.
Fil: Sánchez Morales, Jhon Freddy. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: González Bello, Orlando J.. Universidad del País Vasco; España
Fil: Montes, Mario. Universidad del País Vasco; España
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description Monolithic catalysts were prepared using cordierite and Fecralloy as substrates, with Pd/Al2O3 catalyst deposited by a washcoating method. The samples were characterized and studied for the partial hydrogenation of sunflower oil at 373 K and 413 kPa. In comparative tests, at equal operating conditions and conversion, the structured catalysts presented a lower trans-isomers formation than the powder catalyst. After three consecutive tests, the ceramic monolith showed no change in activity or selectivity, whereas the metallic monolith showed a partial deactivation (10%), which is attributed to a loss of catalyst. © 2009 Elsevier B.V. All rights reserved.
publishDate 2009
dc.date.none.fl_str_mv 2009-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/57778
Sánchez Morales, Jhon Freddy; González Bello, Orlando J.; Montes, Mario; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil; Elsevier Science; Catalysis Communications; 10; 10; 5-2009; 1446-1449
1566-7367
CONICET Digital
CONICET
url http://hdl.handle.net/11336/57778
identifier_str_mv Sánchez Morales, Jhon Freddy; González Bello, Orlando J.; Montes, Mario; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil; Elsevier Science; Catalysis Communications; 10; 10; 5-2009; 1446-1449
1566-7367
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2009.03.016
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736709001198
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269536719470592
score 13.13397

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