Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil

Autores
Sánchez Morales, Jhon Freddy; Boldrini, Diego Emmanuel; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The present work explores the viability of introducing improvements to the conventional process of hydrogenation using structured catalysts. Monolithic catalysts of anodized aluminum were prepared and characterized. They were impregnated with palladium and used as monolithic stirrers in the sunflower oil hydrogenation reaction at 100 °C and 413. kPa.The monolithic catalysts showed to be active, with a 50% C. C conversion in 30. min. When consecutive tests were performed, a loss of activity was observed, decreasing 80% in the sixth test, which is attributed to the presence of carbonaceous residues.
Fil: Sánchez Morales, Jhon Freddy. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
ALUMINUM MONOLITHS
DEACTIVATION
OIL HYDROGENATION
PALLADIUM
STRUCTURED CATALYSTS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/133363
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oilSánchez Morales, Jhon FreddyBoldrini, Diego EmmanuelTonetto, Gabriela MartaDamiani, Daniel EduardoALUMINUM MONOLITHSDEACTIVATIONOIL HYDROGENATIONPALLADIUMSTRUCTURED CATALYSTShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The present work explores the viability of introducing improvements to the conventional process of hydrogenation using structured catalysts. Monolithic catalysts of anodized aluminum were prepared and characterized. They were impregnated with palladium and used as monolithic stirrers in the sunflower oil hydrogenation reaction at 100 °C and 413. kPa.The monolithic catalysts showed to be active, with a 50% C. C conversion in 30. min. When consecutive tests were performed, a loss of activity was observed, decreasing 80% in the sixth test, which is attributed to the presence of carbonaceous residues.Fil: Sánchez Morales, Jhon Freddy. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science SA2011-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/133363Sánchez Morales, Jhon Freddy; Boldrini, Diego Emmanuel; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil; Elsevier Science SA; Chemical Engineering Journal; 167; 1; 2-2011; 355-3611385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S1385894711000222info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2010.12.085info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:10Zoai:ri.conicet.gov.ar:11336/133363instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:11.273CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil
title Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil
spellingShingle Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil
Sánchez Morales, Jhon Freddy
ALUMINUM MONOLITHS
DEACTIVATION
OIL HYDROGENATION
PALLADIUM
STRUCTURED CATALYSTS
title_short Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil
title_full Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil
title_fullStr Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil
title_full_unstemmed Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil
title_sort Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil
dc.creator.none.fl_str_mv Sánchez Morales, Jhon Freddy
Boldrini, Diego Emmanuel
Tonetto, Gabriela Marta
Damiani, Daniel Eduardo
author Sánchez Morales, Jhon Freddy
author_facet Sánchez Morales, Jhon Freddy
Boldrini, Diego Emmanuel
Tonetto, Gabriela Marta
Damiani, Daniel Eduardo
author_role author
author2 Boldrini, Diego Emmanuel
Tonetto, Gabriela Marta
Damiani, Daniel Eduardo
author2_role author
author
author
dc.subject.none.fl_str_mv ALUMINUM MONOLITHS
DEACTIVATION
OIL HYDROGENATION
PALLADIUM
STRUCTURED CATALYSTS
topic ALUMINUM MONOLITHS
DEACTIVATION
OIL HYDROGENATION
PALLADIUM
STRUCTURED CATALYSTS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The present work explores the viability of introducing improvements to the conventional process of hydrogenation using structured catalysts. Monolithic catalysts of anodized aluminum were prepared and characterized. They were impregnated with palladium and used as monolithic stirrers in the sunflower oil hydrogenation reaction at 100 °C and 413. kPa.The monolithic catalysts showed to be active, with a 50% C. C conversion in 30. min. When consecutive tests were performed, a loss of activity was observed, decreasing 80% in the sixth test, which is attributed to the presence of carbonaceous residues.
Fil: Sánchez Morales, Jhon Freddy. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description The present work explores the viability of introducing improvements to the conventional process of hydrogenation using structured catalysts. Monolithic catalysts of anodized aluminum were prepared and characterized. They were impregnated with palladium and used as monolithic stirrers in the sunflower oil hydrogenation reaction at 100 °C and 413. kPa.The monolithic catalysts showed to be active, with a 50% C. C conversion in 30. min. When consecutive tests were performed, a loss of activity was observed, decreasing 80% in the sixth test, which is attributed to the presence of carbonaceous residues.
publishDate 2011
dc.date.none.fl_str_mv 2011-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/133363
Sánchez Morales, Jhon Freddy; Boldrini, Diego Emmanuel; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil; Elsevier Science SA; Chemical Engineering Journal; 167; 1; 2-2011; 355-361
1385-8947
CONICET Digital
CONICET
url http://hdl.handle.net/11336/133363
identifier_str_mv Sánchez Morales, Jhon Freddy; Boldrini, Diego Emmanuel; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Palladium catalyst on anodized aluminum monoliths for the partial hydrogenation of vegetable oil; Elsevier Science SA; Chemical Engineering Journal; 167; 1; 2-2011; 355-361
1385-8947
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S1385894711000222
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2010.12.085
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842270072320557056
score 13.13397

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