Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors
- Autores
- Van Mierloo, Sarah; Vasseur, Karolien; Van Den Brande, Niko; Boyukbayram, Ayse E.; Ruttens, Bart; Rodríguez, Silvio David; Botek, Edith; Liégeois, Vincent; D'Haen, Jan; Adriaensens, Peter J.; Heremans, Paul; Champagne, Benoît; Van Assche, Guy; Lutsen, Laurence; Vanderzande, Dirk J.; Maes, Wouter
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A series of 5′-aryl-substituted 2, 5-bis(3′-hexylthiophen- 2′-yl)thiazolo[5, 4-d]thiazole derivatives was synthesized and these expanded semiconductors were investigated as active materials for solution-processable organic field-effect transistors. Field-effect mobilities of up to 10 -3 cm 2V -1s -1 were obtained, representing the first reasonable FET behavior for highly soluble thiazolo[5, 4-d]thiazole-based small organic compounds suitable for printable electronics. Thermal and electrooptical material properties were studied by thermogravimetric analysis, differential scanning calorimetry, cyclic voltammetry, and UV/Vis spectroscopy. Trends in thermal and optical data were supported by (time-dependent) density functional theory calculations. Additional X-ray diffraction, atomic force microscopy, and scanning electron microscopy studies provided insight in the relationship between the molecular structures, film morphologies, and FET performances. The fibrillar microcrystalline structure observed for the best-performing thienyl-substituted material was linked to the high mobility.
Fil: Van Mierloo, Sarah. Hasselt University; Bélgica
Fil: Vasseur, Karolien. Katholikie Universiteit Leuven; Bélgica
Fil: Van Den Brande, Niko. Vrije Unviversiteit Brussel; Bélgica
Fil: Boyukbayram, Ayse E.. Hasselt University; Bélgica
Fil: Ruttens, Bart. Hasselt University; Bélgica
Fil: Rodríguez, Silvio David. Hasselt University; Bélgica. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Biodiversidad y Biología Experimental y Aplicada. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Biodiversidad y Biología Experimental y Aplicada; Argentina
Fil: Botek, Edith. Université de Namur; Bélgica
Fil: Liégeois, Vincent. Université de Namur; Bélgica
Fil: D'Haen, Jan. Hasselt University; Bélgica
Fil: Adriaensens, Peter J.. Hasselt University; Bélgica
Fil: Heremans, Paul. Katholikie Universiteit Leuven; Bélgica
Fil: Champagne, Benoît. Université de Namur; Bélgica
Fil: Van Assche, Guy. Vrije Unviversiteit Brussel; Bélgica
Fil: Lutsen, Laurence. Hasselt University; Bélgica
Fil: Vanderzande, Dirk J.. Hasselt University; Bélgica
Fil: Maes, Wouter. Hasselt University; Bélgica. Katholikie Universiteit Leuven; Bélgica - Materia
-
CONDUCTING MATERIALS
FIELD-EFFECT TRANSISTORS
ORGANIC ELECTRONICS
THIAZOLO[5,4-D]THIAZOLES
THIN FILM MORPHOLOGY - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/216245
Ver los metadatos del registro completo
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Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistorsVan Mierloo, SarahVasseur, KarolienVan Den Brande, NikoBoyukbayram, Ayse E.Ruttens, BartRodríguez, Silvio DavidBotek, EdithLiégeois, VincentD'Haen, JanAdriaensens, Peter J.Heremans, PaulChampagne, BenoîtVan Assche, GuyLutsen, LaurenceVanderzande, Dirk J.Maes, WouterCONDUCTING MATERIALSFIELD-EFFECT TRANSISTORSORGANIC ELECTRONICSTHIAZOLO[5,4-D]THIAZOLESTHIN FILM MORPHOLOGYhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A series of 5′-aryl-substituted 2, 5-bis(3′-hexylthiophen- 2′-yl)thiazolo[5, 4-d]thiazole derivatives was synthesized and these expanded semiconductors were investigated as active materials for solution-processable organic field-effect transistors. Field-effect mobilities of up to 10 -3 cm 2V -1s -1 were obtained, representing the first reasonable FET behavior for highly soluble thiazolo[5, 4-d]thiazole-based small organic compounds suitable for printable electronics. Thermal and electrooptical material properties were studied by thermogravimetric analysis, differential scanning calorimetry, cyclic voltammetry, and UV/Vis spectroscopy. Trends in thermal and optical data were supported by (time-dependent) density functional theory calculations. Additional X-ray diffraction, atomic force microscopy, and scanning electron microscopy studies provided insight in the relationship between the molecular structures, film morphologies, and FET performances. The fibrillar microcrystalline structure observed for the best-performing thienyl-substituted material was linked to the high mobility.Fil: Van Mierloo, Sarah. Hasselt University; BélgicaFil: Vasseur, Karolien. Katholikie Universiteit Leuven; BélgicaFil: Van Den Brande, Niko. Vrije Unviversiteit Brussel; BélgicaFil: Boyukbayram, Ayse E.. Hasselt University; BélgicaFil: Ruttens, Bart. Hasselt University; BélgicaFil: Rodríguez, Silvio David. Hasselt University; Bélgica. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Biodiversidad y Biología Experimental y Aplicada. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Biodiversidad y Biología Experimental y Aplicada; ArgentinaFil: Botek, Edith. Université de Namur; BélgicaFil: Liégeois, Vincent. Université de Namur; BélgicaFil: D'Haen, Jan. Hasselt University; BélgicaFil: Adriaensens, Peter J.. Hasselt University; BélgicaFil: Heremans, Paul. Katholikie Universiteit Leuven; BélgicaFil: Champagne, Benoît. Université de Namur; BélgicaFil: Van Assche, Guy. Vrije Unviversiteit Brussel; BélgicaFil: Lutsen, Laurence. Hasselt University; BélgicaFil: Vanderzande, Dirk J.. Hasselt University; BélgicaFil: Maes, Wouter. Hasselt University; Bélgica. Katholikie Universiteit Leuven; BélgicaWiley2012-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/216245Van Mierloo, Sarah; Vasseur, Karolien; Van Den Brande, Niko; Boyukbayram, Ayse E.; Ruttens, Bart; et al.; Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors; Wiley; ChemplusChem; 77; 10; 6-2012; 923-9302192-6506CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cplu.201200132info:eu-repo/semantics/altIdentifier/doi/10.1002/cplu.201200132info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:31:52Zoai:ri.conicet.gov.ar:11336/216245instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:31:53.084CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| title |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| spellingShingle |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors Van Mierloo, Sarah CONDUCTING MATERIALS FIELD-EFFECT TRANSISTORS ORGANIC ELECTRONICS THIAZOLO[5,4-D]THIAZOLES THIN FILM MORPHOLOGY |
| title_short |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| title_full |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| title_fullStr |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| title_full_unstemmed |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| title_sort |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| dc.creator.none.fl_str_mv |
Van Mierloo, Sarah Vasseur, Karolien Van Den Brande, Niko Boyukbayram, Ayse E. Ruttens, Bart Rodríguez, Silvio David Botek, Edith Liégeois, Vincent D'Haen, Jan Adriaensens, Peter J. Heremans, Paul Champagne, Benoît Van Assche, Guy Lutsen, Laurence Vanderzande, Dirk J. Maes, Wouter |
| author |
Van Mierloo, Sarah |
| author_facet |
Van Mierloo, Sarah Vasseur, Karolien Van Den Brande, Niko Boyukbayram, Ayse E. Ruttens, Bart Rodríguez, Silvio David Botek, Edith Liégeois, Vincent D'Haen, Jan Adriaensens, Peter J. Heremans, Paul Champagne, Benoît Van Assche, Guy Lutsen, Laurence Vanderzande, Dirk J. Maes, Wouter |
| author_role |
author |
| author2 |
Vasseur, Karolien Van Den Brande, Niko Boyukbayram, Ayse E. Ruttens, Bart Rodríguez, Silvio David Botek, Edith Liégeois, Vincent D'Haen, Jan Adriaensens, Peter J. Heremans, Paul Champagne, Benoît Van Assche, Guy Lutsen, Laurence Vanderzande, Dirk J. Maes, Wouter |
| author2_role |
author author author author author author author author author author author author author author author |
| dc.subject.none.fl_str_mv |
CONDUCTING MATERIALS FIELD-EFFECT TRANSISTORS ORGANIC ELECTRONICS THIAZOLO[5,4-D]THIAZOLES THIN FILM MORPHOLOGY |
| topic |
CONDUCTING MATERIALS FIELD-EFFECT TRANSISTORS ORGANIC ELECTRONICS THIAZOLO[5,4-D]THIAZOLES THIN FILM MORPHOLOGY |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| dc.description.none.fl_txt_mv |
A series of 5′-aryl-substituted 2, 5-bis(3′-hexylthiophen- 2′-yl)thiazolo[5, 4-d]thiazole derivatives was synthesized and these expanded semiconductors were investigated as active materials for solution-processable organic field-effect transistors. Field-effect mobilities of up to 10 -3 cm 2V -1s -1 were obtained, representing the first reasonable FET behavior for highly soluble thiazolo[5, 4-d]thiazole-based small organic compounds suitable for printable electronics. Thermal and electrooptical material properties were studied by thermogravimetric analysis, differential scanning calorimetry, cyclic voltammetry, and UV/Vis spectroscopy. Trends in thermal and optical data were supported by (time-dependent) density functional theory calculations. Additional X-ray diffraction, atomic force microscopy, and scanning electron microscopy studies provided insight in the relationship between the molecular structures, film morphologies, and FET performances. The fibrillar microcrystalline structure observed for the best-performing thienyl-substituted material was linked to the high mobility. Fil: Van Mierloo, Sarah. Hasselt University; Bélgica Fil: Vasseur, Karolien. Katholikie Universiteit Leuven; Bélgica Fil: Van Den Brande, Niko. Vrije Unviversiteit Brussel; Bélgica Fil: Boyukbayram, Ayse E.. Hasselt University; Bélgica Fil: Ruttens, Bart. Hasselt University; Bélgica Fil: Rodríguez, Silvio David. Hasselt University; Bélgica. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Biodiversidad y Biología Experimental y Aplicada. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Biodiversidad y Biología Experimental y Aplicada; Argentina Fil: Botek, Edith. Université de Namur; Bélgica Fil: Liégeois, Vincent. Université de Namur; Bélgica Fil: D'Haen, Jan. Hasselt University; Bélgica Fil: Adriaensens, Peter J.. Hasselt University; Bélgica Fil: Heremans, Paul. Katholikie Universiteit Leuven; Bélgica Fil: Champagne, Benoît. Université de Namur; Bélgica Fil: Van Assche, Guy. Vrije Unviversiteit Brussel; Bélgica Fil: Lutsen, Laurence. Hasselt University; Bélgica Fil: Vanderzande, Dirk J.. Hasselt University; Bélgica Fil: Maes, Wouter. Hasselt University; Bélgica. Katholikie Universiteit Leuven; Bélgica |
| description |
A series of 5′-aryl-substituted 2, 5-bis(3′-hexylthiophen- 2′-yl)thiazolo[5, 4-d]thiazole derivatives was synthesized and these expanded semiconductors were investigated as active materials for solution-processable organic field-effect transistors. Field-effect mobilities of up to 10 -3 cm 2V -1s -1 were obtained, representing the first reasonable FET behavior for highly soluble thiazolo[5, 4-d]thiazole-based small organic compounds suitable for printable electronics. Thermal and electrooptical material properties were studied by thermogravimetric analysis, differential scanning calorimetry, cyclic voltammetry, and UV/Vis spectroscopy. Trends in thermal and optical data were supported by (time-dependent) density functional theory calculations. Additional X-ray diffraction, atomic force microscopy, and scanning electron microscopy studies provided insight in the relationship between the molecular structures, film morphologies, and FET performances. The fibrillar microcrystalline structure observed for the best-performing thienyl-substituted material was linked to the high mobility. |
| publishDate |
2012 |
| dc.date.none.fl_str_mv |
2012-06 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/216245 Van Mierloo, Sarah; Vasseur, Karolien; Van Den Brande, Niko; Boyukbayram, Ayse E.; Ruttens, Bart; et al.; Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors; Wiley; ChemplusChem; 77; 10; 6-2012; 923-930 2192-6506 CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/216245 |
| identifier_str_mv |
Van Mierloo, Sarah; Vasseur, Karolien; Van Den Brande, Niko; Boyukbayram, Ayse E.; Ruttens, Bart; et al.; Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors; Wiley; ChemplusChem; 77; 10; 6-2012; 923-930 2192-6506 CONICET Digital CONICET |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
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info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cplu.201200132 info:eu-repo/semantics/altIdentifier/doi/10.1002/cplu.201200132 |
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info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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openAccess |
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https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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application/pdf application/pdf application/pdf |
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Wiley |
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Wiley |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
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dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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