Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles

Autores
Dangi, R. R.; Kumari, Maya; Khyaliya, Priyanka; Parellada, Eduardo Alberto; Neske, Adriana Neske; Ameta, K. L.
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The present study describes the synthesis of some novel arylidene cyclic chalcones 2-(4-substituted benzylidene)-6,6-diphenylimidazo[2,1-b][1,3]thiazole-3,5-diones and their transformation to 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a- dihydroimidazo[2´,1´:2,3][1,3]thiazolo[4,5-c][1,2]oxazol-7(6H)-ones via cyclization using hydroxylamine hydrochloride. The starting chalcones have been synthesized by the condensation of various aromatic aldehydes and methylene entity of synthesized imidazothiazole-3,5-diones which were obtained by the cyclization of 5,5-diphenyl-2-thioxoimidazolidin-4-ones and chloroacetic acid. The intermediate 5,5-diphenyl-2-thioxoimidazolidin-4-ones have been synthesized by the condensation of α-diketone (benzil) with thiourea in presence of ethanolic alkali followed by Pinacol-Pinacolone rearrangement. Structures of all the newly synthesized compounds were confirmed by chemical, analytical and spectral data.
Fil: Dangi, R. R.. Mody University Of Science And Technology; India
Fil: Kumari, Maya. Mody University Of Science And Technology; India
Fil: Khyaliya, Priyanka. Mody University Of Science And Technology; India
Fil: Parellada, Eduardo Alberto. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Orgánica. Cátedra de Química Orgánica III; Argentina
Fil: Neske, Adriana Neske. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Orgánica. Cátedra de Química Orgánica III; Argentina
Fil: Ameta, K. L.. Mody University Of Science And Technology; India
Materia
Chalcone
Diketone
Imidazole
Thiazole
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/108363
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/108363
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] IsoxazolesDangi, R. R.Kumari, MayaKhyaliya, PriyankaParellada, Eduardo AlbertoNeske, Adriana NeskeAmeta, K. L.ChalconeDiketoneImidazoleThiazolehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The present study describes the synthesis of some novel arylidene cyclic chalcones 2-(4-substituted benzylidene)-6,6-diphenylimidazo[2,1-b][1,3]thiazole-3,5-diones and their transformation to 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a- dihydroimidazo[2´,1´:2,3][1,3]thiazolo[4,5-c][1,2]oxazol-7(6H)-ones via cyclization using hydroxylamine hydrochloride. The starting chalcones have been synthesized by the condensation of various aromatic aldehydes and methylene entity of synthesized imidazothiazole-3,5-diones which were obtained by the cyclization of 5,5-diphenyl-2-thioxoimidazolidin-4-ones and chloroacetic acid. The intermediate 5,5-diphenyl-2-thioxoimidazolidin-4-ones have been synthesized by the condensation of α-diketone (benzil) with thiourea in presence of ethanolic alkali followed by Pinacol-Pinacolone rearrangement. Structures of all the newly synthesized compounds were confirmed by chemical, analytical and spectral data.Fil: Dangi, R. R.. Mody University Of Science And Technology; IndiaFil: Kumari, Maya. Mody University Of Science And Technology; IndiaFil: Khyaliya, Priyanka. Mody University Of Science And Technology; IndiaFil: Parellada, Eduardo Alberto. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Orgánica. Cátedra de Química Orgánica III; ArgentinaFil: Neske, Adriana Neske. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Orgánica. Cátedra de Química Orgánica III; ArgentinaFil: Ameta, K. L.. Mody University Of Science And Technology; IndiaIslamic Azad University Of Qaemshahr2016-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/108363Dangi, R. R.; Kumari, Maya; Khyaliya, Priyanka ; Parellada, Eduardo Alberto; Neske, Adriana Neske; et al.; Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles; Islamic Azad University Of Qaemshahr; Iranian Journal of Organic Chemistry; 8; 4; 9-2016; 1887-18932008-3599CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://iranjoc.qaemiau.ac.ir/article_541749_1b7e57d81656f39c49ca3f47b8d86192.pdfinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T10:38:10Zoai:ri.conicet.gov.ar:11336/108363instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 10:38:10.691CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles
title Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles
spellingShingle Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles
Dangi, R. R.
Chalcone
Diketone
Imidazole
Thiazole
title_short Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles
title_full Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles
title_fullStr Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles
title_full_unstemmed Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles
title_sort Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles
dc.creator.none.fl_str_mv Dangi, R. R.
Kumari, Maya
Khyaliya, Priyanka
Parellada, Eduardo Alberto
Neske, Adriana Neske
Ameta, K. L.
author Dangi, R. R.
author_facet Dangi, R. R.
Kumari, Maya
Khyaliya, Priyanka
Parellada, Eduardo Alberto
Neske, Adriana Neske
Ameta, K. L.
author_role author
author2 Kumari, Maya
Khyaliya, Priyanka
Parellada, Eduardo Alberto
Neske, Adriana Neske
Ameta, K. L.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Chalcone
Diketone
Imidazole
Thiazole
topic Chalcone
Diketone
Imidazole
Thiazole
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The present study describes the synthesis of some novel arylidene cyclic chalcones 2-(4-substituted benzylidene)-6,6-diphenylimidazo[2,1-b][1,3]thiazole-3,5-diones and their transformation to 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a- dihydroimidazo[2´,1´:2,3][1,3]thiazolo[4,5-c][1,2]oxazol-7(6H)-ones via cyclization using hydroxylamine hydrochloride. The starting chalcones have been synthesized by the condensation of various aromatic aldehydes and methylene entity of synthesized imidazothiazole-3,5-diones which were obtained by the cyclization of 5,5-diphenyl-2-thioxoimidazolidin-4-ones and chloroacetic acid. The intermediate 5,5-diphenyl-2-thioxoimidazolidin-4-ones have been synthesized by the condensation of α-diketone (benzil) with thiourea in presence of ethanolic alkali followed by Pinacol-Pinacolone rearrangement. Structures of all the newly synthesized compounds were confirmed by chemical, analytical and spectral data.
Fil: Dangi, R. R.. Mody University Of Science And Technology; India
Fil: Kumari, Maya. Mody University Of Science And Technology; India
Fil: Khyaliya, Priyanka. Mody University Of Science And Technology; India
Fil: Parellada, Eduardo Alberto. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Orgánica. Cátedra de Química Orgánica III; Argentina
Fil: Neske, Adriana Neske. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Orgánica. Cátedra de Química Orgánica III; Argentina
Fil: Ameta, K. L.. Mody University Of Science And Technology; India
description The present study describes the synthesis of some novel arylidene cyclic chalcones 2-(4-substituted benzylidene)-6,6-diphenylimidazo[2,1-b][1,3]thiazole-3,5-diones and their transformation to 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a- dihydroimidazo[2´,1´:2,3][1,3]thiazolo[4,5-c][1,2]oxazol-7(6H)-ones via cyclization using hydroxylamine hydrochloride. The starting chalcones have been synthesized by the condensation of various aromatic aldehydes and methylene entity of synthesized imidazothiazole-3,5-diones which were obtained by the cyclization of 5,5-diphenyl-2-thioxoimidazolidin-4-ones and chloroacetic acid. The intermediate 5,5-diphenyl-2-thioxoimidazolidin-4-ones have been synthesized by the condensation of α-diketone (benzil) with thiourea in presence of ethanolic alkali followed by Pinacol-Pinacolone rearrangement. Structures of all the newly synthesized compounds were confirmed by chemical, analytical and spectral data.
publishDate 2016
dc.date.none.fl_str_mv 2016-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/108363
Dangi, R. R.; Kumari, Maya; Khyaliya, Priyanka ; Parellada, Eduardo Alberto; Neske, Adriana Neske; et al.; Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles; Islamic Azad University Of Qaemshahr; Iranian Journal of Organic Chemistry; 8; 4; 9-2016; 1887-1893
2008-3599
CONICET Digital
CONICET
url http://hdl.handle.net/11336/108363
identifier_str_mv Dangi, R. R.; Kumari, Maya; Khyaliya, Priyanka ; Parellada, Eduardo Alberto; Neske, Adriana Neske; et al.; Synthesis of Some Novel Fused Substituted 3-(4-substitutedphenyl)-6,6-diphenyl-3,3a dihydroimidazo [2',1':2,3][1,3] thiazolo[4,5-c][1,2] Isoxazoles; Islamic Azad University Of Qaemshahr; Iranian Journal of Organic Chemistry; 8; 4; 9-2016; 1887-1893
2008-3599
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://iranjoc.qaemiau.ac.ir/article_541749_1b7e57d81656f39c49ca3f47b8d86192.pdf
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Islamic Azad University Of Qaemshahr
publisher.none.fl_str_mv Islamic Azad University Of Qaemshahr
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1847978073911197696
score 13.121305

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