Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation

Autores
Fasce, Laura Alejandra; Bocero, Franco; Ramos, Cinthia Paula; Inchaurrondo, Natalia Soledad
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The catalytic ozonation of bisphenol A (BPA) was performed using an industrial solid waste ascatalyst: electric arc furnace slag (EAFS). The characterization of the catalyst (SEM/EDS, XRD,surface area, pHPZC and Mössbauer spectroscopy) showed low surface area, alkaline nature and acomposition rich in Fe, Ca, Si, C oxides, with minor content of Mg, Mn and Al. Ozonationexperiments were carried out in a semi-batch reactor at room temperature at different initial pHconditions: from alkaline (natural pH 10.5) to acidic (controlled pH 3) aqueous media. Catalyticozonation experiments showed complete BPA removal and remarkable total organic carbonconversions (62-80%) over the broad pH range explored. The highest mineralization levels wereobtained under basic pH, which was attributed to the generation of hydroxyl radical given by thepresence of OHand precipitation reactions of intermediates promoted by Ca oxides. Under acidicconditions the presence of EAFS notoriously enhanced BPA mineralization compared to singleozonation, due to the activity of leached species. The stability of the material was tested in 4 ozonation cycles. EAFS activity was mostly sustained under acidic conditions while a reduction was observed under uncontrolled pH condition, which was associated with a marked pH decrease. However, the residual activity still allowed complete BPA degradation and high mineralization levels (> 50 %). EAFS is a low-cost material that exhibits high activity and reasonable stability in catalytic ozonation of BPA. The valorization of this waste constitutes a technological alternative that could benefit both metallurgical and water treatment plants.
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Bocero, Franco. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Constituyentes | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Constituyentes; Argentina
Fil: Inchaurrondo, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
electric arc furnace slag
ozonation
catalysis
emerging pollutants
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/230475
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/230475
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic OzonationFasce, Laura AlejandraBocero, FrancoRamos, Cinthia PaulaInchaurrondo, Natalia Soledadelectric arc furnace slagozonationcatalysisemerging pollutantshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The catalytic ozonation of bisphenol A (BPA) was performed using an industrial solid waste ascatalyst: electric arc furnace slag (EAFS). The characterization of the catalyst (SEM/EDS, XRD,surface area, pHPZC and Mössbauer spectroscopy) showed low surface area, alkaline nature and acomposition rich in Fe, Ca, Si, C oxides, with minor content of Mg, Mn and Al. Ozonationexperiments were carried out in a semi-batch reactor at room temperature at different initial pHconditions: from alkaline (natural pH 10.5) to acidic (controlled pH 3) aqueous media. Catalyticozonation experiments showed complete BPA removal and remarkable total organic carbonconversions (62-80%) over the broad pH range explored. The highest mineralization levels wereobtained under basic pH, which was attributed to the generation of hydroxyl radical given by thepresence of OHand precipitation reactions of intermediates promoted by Ca oxides. Under acidicconditions the presence of EAFS notoriously enhanced BPA mineralization compared to singleozonation, due to the activity of leached species. The stability of the material was tested in 4 ozonation cycles. EAFS activity was mostly sustained under acidic conditions while a reduction was observed under uncontrolled pH condition, which was associated with a marked pH decrease. However, the residual activity still allowed complete BPA degradation and high mineralization levels (> 50 %). EAFS is a low-cost material that exhibits high activity and reasonable stability in catalytic ozonation of BPA. The valorization of this waste constitutes a technological alternative that could benefit both metallurgical and water treatment plants.Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Bocero, Franco. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Constituyentes | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Constituyentes; ArgentinaFil: Inchaurrondo, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier2023-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/230475Fasce, Laura Alejandra; Bocero, Franco; Ramos, Cinthia Paula; Inchaurrondo, Natalia Soledad; Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation; Elsevier; Chemical Engineering Journal Advances; 16; 11-2023; 1-232666-8211CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S2666821123001333info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceja.2023.100576info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:46:33Zoai:ri.conicet.gov.ar:11336/230475instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:46:34.022CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation
title Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation
spellingShingle Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation
Fasce, Laura Alejandra
electric arc furnace slag
ozonation
catalysis
emerging pollutants
title_short Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation
title_full Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation
title_fullStr Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation
title_full_unstemmed Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation
title_sort Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation
dc.creator.none.fl_str_mv Fasce, Laura Alejandra
Bocero, Franco
Ramos, Cinthia Paula
Inchaurrondo, Natalia Soledad
author Fasce, Laura Alejandra
author_facet Fasce, Laura Alejandra
Bocero, Franco
Ramos, Cinthia Paula
Inchaurrondo, Natalia Soledad
author_role author
author2 Bocero, Franco
Ramos, Cinthia Paula
Inchaurrondo, Natalia Soledad
author2_role author
author
author
dc.subject.none.fl_str_mv electric arc furnace slag
ozonation
catalysis
emerging pollutants
topic electric arc furnace slag
ozonation
catalysis
emerging pollutants
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The catalytic ozonation of bisphenol A (BPA) was performed using an industrial solid waste ascatalyst: electric arc furnace slag (EAFS). The characterization of the catalyst (SEM/EDS, XRD,surface area, pHPZC and Mössbauer spectroscopy) showed low surface area, alkaline nature and acomposition rich in Fe, Ca, Si, C oxides, with minor content of Mg, Mn and Al. Ozonationexperiments were carried out in a semi-batch reactor at room temperature at different initial pHconditions: from alkaline (natural pH 10.5) to acidic (controlled pH 3) aqueous media. Catalyticozonation experiments showed complete BPA removal and remarkable total organic carbonconversions (62-80%) over the broad pH range explored. The highest mineralization levels wereobtained under basic pH, which was attributed to the generation of hydroxyl radical given by thepresence of OHand precipitation reactions of intermediates promoted by Ca oxides. Under acidicconditions the presence of EAFS notoriously enhanced BPA mineralization compared to singleozonation, due to the activity of leached species. The stability of the material was tested in 4 ozonation cycles. EAFS activity was mostly sustained under acidic conditions while a reduction was observed under uncontrolled pH condition, which was associated with a marked pH decrease. However, the residual activity still allowed complete BPA degradation and high mineralization levels (> 50 %). EAFS is a low-cost material that exhibits high activity and reasonable stability in catalytic ozonation of BPA. The valorization of this waste constitutes a technological alternative that could benefit both metallurgical and water treatment plants.
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Bocero, Franco. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Constituyentes | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Constituyentes; Argentina
Fil: Inchaurrondo, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description The catalytic ozonation of bisphenol A (BPA) was performed using an industrial solid waste ascatalyst: electric arc furnace slag (EAFS). The characterization of the catalyst (SEM/EDS, XRD,surface area, pHPZC and Mössbauer spectroscopy) showed low surface area, alkaline nature and acomposition rich in Fe, Ca, Si, C oxides, with minor content of Mg, Mn and Al. Ozonationexperiments were carried out in a semi-batch reactor at room temperature at different initial pHconditions: from alkaline (natural pH 10.5) to acidic (controlled pH 3) aqueous media. Catalyticozonation experiments showed complete BPA removal and remarkable total organic carbonconversions (62-80%) over the broad pH range explored. The highest mineralization levels wereobtained under basic pH, which was attributed to the generation of hydroxyl radical given by thepresence of OHand precipitation reactions of intermediates promoted by Ca oxides. Under acidicconditions the presence of EAFS notoriously enhanced BPA mineralization compared to singleozonation, due to the activity of leached species. The stability of the material was tested in 4 ozonation cycles. EAFS activity was mostly sustained under acidic conditions while a reduction was observed under uncontrolled pH condition, which was associated with a marked pH decrease. However, the residual activity still allowed complete BPA degradation and high mineralization levels (> 50 %). EAFS is a low-cost material that exhibits high activity and reasonable stability in catalytic ozonation of BPA. The valorization of this waste constitutes a technological alternative that could benefit both metallurgical and water treatment plants.
publishDate 2023
dc.date.none.fl_str_mv 2023-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/230475
Fasce, Laura Alejandra; Bocero, Franco; Ramos, Cinthia Paula; Inchaurrondo, Natalia Soledad; Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation; Elsevier; Chemical Engineering Journal Advances; 16; 11-2023; 1-23
2666-8211
CONICET Digital
CONICET
url http://hdl.handle.net/11336/230475
identifier_str_mv Fasce, Laura Alejandra; Bocero, Franco; Ramos, Cinthia Paula; Inchaurrondo, Natalia Soledad; Enhanced mineralization of bisphenol A by Electric Arc Furnace Slag: Catalytic Ozonation; Elsevier; Chemical Engineering Journal Advances; 16; 11-2023; 1-23
2666-8211
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S2666821123001333
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceja.2023.100576
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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