New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage

Autores
Cova, Federico Hector; Rönnebro, Ewa C. E.; Choi, Young Joon; Gennari, Fabiana Cristina; Arneodo Larochette, Pierre Paul
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The composite 2LiBH4:MgH2 has been studied as a potential hydrogen storage material due to its high storage capacity. The present work is aimed at clarifying the thermodynamic behavior of the system, especially within the temperature region above 400 °C. Different reaction paths which have important implication for storage applications during hydrogen absorption and desorption at various temperatures were revealed. At temperatures over 413°C, two different absorption pressure plateaus are observed. This indicates that two different reactions occur: Mg hydrogenation at higher pressures and the re-formation of LiBH4 from H2, LiH, and MgB2 at lower pressures. On the other hand, at temperatures below 413°C only one plateau is present in the system. During desorption, the double plateau can be observed at temperatures as low as 375°C. This effect restricts the applicability of this composite as a hydrogen storage material.
Fil: Cova, Federico Hector. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Rönnebro, Ewa C. E.. Pacific Northwest National Laboratory; Estados Unidos
Fil: Choi, Young Joon. Pacific Northwest National Laboratory; Estados Unidos. Globalfoundries; Estados Unidos
Fil: Gennari, Fabiana Cristina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Arneodo Larochette, Pierre Paul. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
REACTIVE HYDRIDE COMPOSITE
LITHIUM BOROHYDRIDE
THERMODYNAMIC
KINETICS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/54442
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/54442
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storageCova, Federico HectorRönnebro, Ewa C. E.Choi, Young JoonGennari, Fabiana CristinaArneodo Larochette, Pierre PaulREACTIVE HYDRIDE COMPOSITELITHIUM BOROHYDRIDETHERMODYNAMICKINETICShttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The composite 2LiBH4:MgH2 has been studied as a potential hydrogen storage material due to its high storage capacity. The present work is aimed at clarifying the thermodynamic behavior of the system, especially within the temperature region above 400 °C. Different reaction paths which have important implication for storage applications during hydrogen absorption and desorption at various temperatures were revealed. At temperatures over 413°C, two different absorption pressure plateaus are observed. This indicates that two different reactions occur: Mg hydrogenation at higher pressures and the re-formation of LiBH4 from H2, LiH, and MgB2 at lower pressures. On the other hand, at temperatures below 413°C only one plateau is present in the system. During desorption, the double plateau can be observed at temperatures as low as 375°C. This effect restricts the applicability of this composite as a hydrogen storage material.Fil: Cova, Federico Hector. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Rönnebro, Ewa C. E.. Pacific Northwest National Laboratory; Estados UnidosFil: Choi, Young Joon. Pacific Northwest National Laboratory; Estados Unidos. Globalfoundries; Estados UnidosFil: Gennari, Fabiana Cristina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Arneodo Larochette, Pierre Paul. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaAmerican Chemical Society2015-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/54442Cova, Federico Hector; Rönnebro, Ewa C. E.; Choi, Young Joon; Gennari, Fabiana Cristina; Arneodo Larochette, Pierre Paul; New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage; American Chemical Society; Journal of Physical Chemistry C; 119; 28; 7-2015; 15816-158221932-7447CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.5b02047info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.5b02047info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T10:35:17Zoai:ri.conicet.gov.ar:11336/54442instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 10:35:17.317CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage
title New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage
spellingShingle New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage
Cova, Federico Hector
REACTIVE HYDRIDE COMPOSITE
LITHIUM BOROHYDRIDE
THERMODYNAMIC
KINETICS
title_short New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage
title_full New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage
title_fullStr New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage
title_full_unstemmed New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage
title_sort New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage
dc.creator.none.fl_str_mv Cova, Federico Hector
Rönnebro, Ewa C. E.
Choi, Young Joon
Gennari, Fabiana Cristina
Arneodo Larochette, Pierre Paul
author Cova, Federico Hector
author_facet Cova, Federico Hector
Rönnebro, Ewa C. E.
Choi, Young Joon
Gennari, Fabiana Cristina
Arneodo Larochette, Pierre Paul
author_role author
author2 Rönnebro, Ewa C. E.
Choi, Young Joon
Gennari, Fabiana Cristina
Arneodo Larochette, Pierre Paul
author2_role author
author
author
author
dc.subject.none.fl_str_mv REACTIVE HYDRIDE COMPOSITE
LITHIUM BOROHYDRIDE
THERMODYNAMIC
KINETICS
topic REACTIVE HYDRIDE COMPOSITE
LITHIUM BOROHYDRIDE
THERMODYNAMIC
KINETICS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The composite 2LiBH4:MgH2 has been studied as a potential hydrogen storage material due to its high storage capacity. The present work is aimed at clarifying the thermodynamic behavior of the system, especially within the temperature region above 400 °C. Different reaction paths which have important implication for storage applications during hydrogen absorption and desorption at various temperatures were revealed. At temperatures over 413°C, two different absorption pressure plateaus are observed. This indicates that two different reactions occur: Mg hydrogenation at higher pressures and the re-formation of LiBH4 from H2, LiH, and MgB2 at lower pressures. On the other hand, at temperatures below 413°C only one plateau is present in the system. During desorption, the double plateau can be observed at temperatures as low as 375°C. This effect restricts the applicability of this composite as a hydrogen storage material.
Fil: Cova, Federico Hector. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Rönnebro, Ewa C. E.. Pacific Northwest National Laboratory; Estados Unidos
Fil: Choi, Young Joon. Pacific Northwest National Laboratory; Estados Unidos. Globalfoundries; Estados Unidos
Fil: Gennari, Fabiana Cristina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Arneodo Larochette, Pierre Paul. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional de Cuyo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description The composite 2LiBH4:MgH2 has been studied as a potential hydrogen storage material due to its high storage capacity. The present work is aimed at clarifying the thermodynamic behavior of the system, especially within the temperature region above 400 °C. Different reaction paths which have important implication for storage applications during hydrogen absorption and desorption at various temperatures were revealed. At temperatures over 413°C, two different absorption pressure plateaus are observed. This indicates that two different reactions occur: Mg hydrogenation at higher pressures and the re-formation of LiBH4 from H2, LiH, and MgB2 at lower pressures. On the other hand, at temperatures below 413°C only one plateau is present in the system. During desorption, the double plateau can be observed at temperatures as low as 375°C. This effect restricts the applicability of this composite as a hydrogen storage material.
publishDate 2015
dc.date.none.fl_str_mv 2015-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/54442
Cova, Federico Hector; Rönnebro, Ewa C. E.; Choi, Young Joon; Gennari, Fabiana Cristina; Arneodo Larochette, Pierre Paul; New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage; American Chemical Society; Journal of Physical Chemistry C; 119; 28; 7-2015; 15816-15822
1932-7447
CONICET Digital
CONICET
url http://hdl.handle.net/11336/54442
identifier_str_mv Cova, Federico Hector; Rönnebro, Ewa C. E.; Choi, Young Joon; Gennari, Fabiana Cristina; Arneodo Larochette, Pierre Paul; New insights into the thermodynamic behavior of 2LiBH4-MgH2 composite for hydrogen storage; American Chemical Society; Journal of Physical Chemistry C; 119; 28; 7-2015; 15816-15822
1932-7447
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.5b02047
info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.5b02047
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.087074

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