Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties

Autores
Jepsen, Julian; Milanese, Chiara; Puszkiel, Julián Atilio; Girella, Alessandro; Schiavo, Benedetto; Lozano, Gustavo A.; Capurso, Giovanni; Von Colbe, José M. Bellosta; Marini, Amedeo; Kabelac, Stephan; Dornheim, Martin; Klassen, Thomas
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Thermodynamic and heat transfer properties of the 2LiBH4-MgH2 composite (Li-RHC) system are experimentally determined and studied as a basis for the design and development of hydrogen storage tanks. Besides the determination and discussion of the properties, different measurement methods are applied and compared to each other. Regarding thermodynamics, reaction enthalpy and entropy are determined by pressure-concentration-isotherms and coupled manometric-calorimetric measurements. For thermal diffusivity calculation, the specific heat capacity is measured by high-pressure differential scanning calorimetry and the effective thermal conductivity is determined by the transient plane source technique and in situ thermocell. Based on the results obtained from the thermodynamics and the assessment of the heat transfer properties, the reaction mechanism of the Li-RHC and the issues related to the scale-up for larger hydrogen storage systems are discussed in detail.
Fil: Jepsen, Julian. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Milanese, Chiara. University of Pavia; Italia
Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Girella, Alessandro. University of Pavia; Italia
Fil: Schiavo, Benedetto. Universidad de Palermo; Argentina. Istituto per le Tecnologie Avanzate; Italia
Fil: Lozano, Gustavo A.. Helmholtz-Zentrum Geesthacht; Alemania. BASF; Alemania
Fil: Capurso, Giovanni. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Von Colbe, José M. Bellosta. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Marini, Amedeo. University of Pavia; Italia
Fil: Kabelac, Stephan. Leibniz Universität Hannover; Alemania
Fil: Dornheim, Martin. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Klassen, Thomas. Helmholtz-Zentrum Geesthacht; Alemania
Materia
BOROHYDRIDES
HYDROGEN STORAGE
LIBH4/MGH2
MATERIAL PROPERTIES
METAL HYDRIDES
REACTIVE HYDRIDE COMPOSITES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/97998
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/97998
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer propertiesJepsen, JulianMilanese, ChiaraPuszkiel, Julián AtilioGirella, AlessandroSchiavo, BenedettoLozano, Gustavo A.Capurso, GiovanniVon Colbe, José M. BellostaMarini, AmedeoKabelac, StephanDornheim, MartinKlassen, ThomasBOROHYDRIDESHYDROGEN STORAGELIBH4/MGH2MATERIAL PROPERTIESMETAL HYDRIDESREACTIVE HYDRIDE COMPOSITEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Thermodynamic and heat transfer properties of the 2LiBH4-MgH2 composite (Li-RHC) system are experimentally determined and studied as a basis for the design and development of hydrogen storage tanks. Besides the determination and discussion of the properties, different measurement methods are applied and compared to each other. Regarding thermodynamics, reaction enthalpy and entropy are determined by pressure-concentration-isotherms and coupled manometric-calorimetric measurements. For thermal diffusivity calculation, the specific heat capacity is measured by high-pressure differential scanning calorimetry and the effective thermal conductivity is determined by the transient plane source technique and in situ thermocell. Based on the results obtained from the thermodynamics and the assessment of the heat transfer properties, the reaction mechanism of the Li-RHC and the issues related to the scale-up for larger hydrogen storage systems are discussed in detail.Fil: Jepsen, Julian. Helmholtz-Zentrum Geesthacht; AlemaniaFil: Milanese, Chiara. University of Pavia; ItaliaFil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Helmholtz-Zentrum Geesthacht; AlemaniaFil: Girella, Alessandro. University of Pavia; ItaliaFil: Schiavo, Benedetto. Universidad de Palermo; Argentina. Istituto per le Tecnologie Avanzate; ItaliaFil: Lozano, Gustavo A.. Helmholtz-Zentrum Geesthacht; Alemania. BASF; AlemaniaFil: Capurso, Giovanni. Helmholtz-Zentrum Geesthacht; AlemaniaFil: Von Colbe, José M. Bellosta. Helmholtz-Zentrum Geesthacht; AlemaniaFil: Marini, Amedeo. University of Pavia; ItaliaFil: Kabelac, Stephan. Leibniz Universität Hannover; AlemaniaFil: Dornheim, Martin. Helmholtz-Zentrum Geesthacht; AlemaniaFil: Klassen, Thomas. Helmholtz-Zentrum Geesthacht; AlemaniaMDPI2018-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/97998Jepsen, Julian; Milanese, Chiara; Puszkiel, Julián Atilio; Girella, Alessandro; Schiavo, Benedetto; et al.; Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties; MDPI; Energies; 11; 5; 4-2018; 1-211996-1073CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.3390/en11051081info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1073/11/5/1081info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T10:10:47Zoai:ri.conicet.gov.ar:11336/97998instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 10:10:47.332CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties
title Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties
spellingShingle Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties
Jepsen, Julian
BOROHYDRIDES
HYDROGEN STORAGE
LIBH4/MGH2
MATERIAL PROPERTIES
METAL HYDRIDES
REACTIVE HYDRIDE COMPOSITES
title_short Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties
title_full Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties
title_fullStr Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties
title_full_unstemmed Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties
title_sort Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties
dc.creator.none.fl_str_mv Jepsen, Julian
Milanese, Chiara
Puszkiel, Julián Atilio
Girella, Alessandro
Schiavo, Benedetto
Lozano, Gustavo A.
Capurso, Giovanni
Von Colbe, José M. Bellosta
Marini, Amedeo
Kabelac, Stephan
Dornheim, Martin
Klassen, Thomas
author Jepsen, Julian
author_facet Jepsen, Julian
Milanese, Chiara
Puszkiel, Julián Atilio
Girella, Alessandro
Schiavo, Benedetto
Lozano, Gustavo A.
Capurso, Giovanni
Von Colbe, José M. Bellosta
Marini, Amedeo
Kabelac, Stephan
Dornheim, Martin
Klassen, Thomas
author_role author
author2 Milanese, Chiara
Puszkiel, Julián Atilio
Girella, Alessandro
Schiavo, Benedetto
Lozano, Gustavo A.
Capurso, Giovanni
Von Colbe, José M. Bellosta
Marini, Amedeo
Kabelac, Stephan
Dornheim, Martin
Klassen, Thomas
author2_role author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv BOROHYDRIDES
HYDROGEN STORAGE
LIBH4/MGH2
MATERIAL PROPERTIES
METAL HYDRIDES
REACTIVE HYDRIDE COMPOSITES
topic BOROHYDRIDES
HYDROGEN STORAGE
LIBH4/MGH2
MATERIAL PROPERTIES
METAL HYDRIDES
REACTIVE HYDRIDE COMPOSITES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Thermodynamic and heat transfer properties of the 2LiBH4-MgH2 composite (Li-RHC) system are experimentally determined and studied as a basis for the design and development of hydrogen storage tanks. Besides the determination and discussion of the properties, different measurement methods are applied and compared to each other. Regarding thermodynamics, reaction enthalpy and entropy are determined by pressure-concentration-isotherms and coupled manometric-calorimetric measurements. For thermal diffusivity calculation, the specific heat capacity is measured by high-pressure differential scanning calorimetry and the effective thermal conductivity is determined by the transient plane source technique and in situ thermocell. Based on the results obtained from the thermodynamics and the assessment of the heat transfer properties, the reaction mechanism of the Li-RHC and the issues related to the scale-up for larger hydrogen storage systems are discussed in detail.
Fil: Jepsen, Julian. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Milanese, Chiara. University of Pavia; Italia
Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Girella, Alessandro. University of Pavia; Italia
Fil: Schiavo, Benedetto. Universidad de Palermo; Argentina. Istituto per le Tecnologie Avanzate; Italia
Fil: Lozano, Gustavo A.. Helmholtz-Zentrum Geesthacht; Alemania. BASF; Alemania
Fil: Capurso, Giovanni. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Von Colbe, José M. Bellosta. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Marini, Amedeo. University of Pavia; Italia
Fil: Kabelac, Stephan. Leibniz Universität Hannover; Alemania
Fil: Dornheim, Martin. Helmholtz-Zentrum Geesthacht; Alemania
Fil: Klassen, Thomas. Helmholtz-Zentrum Geesthacht; Alemania
description Thermodynamic and heat transfer properties of the 2LiBH4-MgH2 composite (Li-RHC) system are experimentally determined and studied as a basis for the design and development of hydrogen storage tanks. Besides the determination and discussion of the properties, different measurement methods are applied and compared to each other. Regarding thermodynamics, reaction enthalpy and entropy are determined by pressure-concentration-isotherms and coupled manometric-calorimetric measurements. For thermal diffusivity calculation, the specific heat capacity is measured by high-pressure differential scanning calorimetry and the effective thermal conductivity is determined by the transient plane source technique and in situ thermocell. Based on the results obtained from the thermodynamics and the assessment of the heat transfer properties, the reaction mechanism of the Li-RHC and the issues related to the scale-up for larger hydrogen storage systems are discussed in detail.
publishDate 2018
dc.date.none.fl_str_mv 2018-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/97998
Jepsen, Julian; Milanese, Chiara; Puszkiel, Julián Atilio; Girella, Alessandro; Schiavo, Benedetto; et al.; Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties; MDPI; Energies; 11; 5; 4-2018; 1-21
1996-1073
CONICET Digital
CONICET
url http://hdl.handle.net/11336/97998
identifier_str_mv Jepsen, Julian; Milanese, Chiara; Puszkiel, Julián Atilio; Girella, Alessandro; Schiavo, Benedetto; et al.; Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (I) Thermodynamic and heat transfer properties; MDPI; Energies; 11; 5; 4-2018; 1-21
1996-1073
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.3390/en11051081
info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1073/11/5/1081
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.084122

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