Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties

Autores
Jepsen, Julian; Milanese, Chiara; Puszkiel, Julián Atilio; Girella, Alessandro; Schiavo, Benedetto; Lozano, Gustavo A.; Capurso, Giovanni; Von Colbe, José M. Bellosta; Marini, Amedeo; Kabelac, Stephan; Dornheim, Martin; Klassen, Thomas
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Reaction kinetic behaviour and cycling stability of the 2LiBH4-MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination and discussion about the properties; different measurement methods are applied and compared. The activation energies for both hydrogenation and dehydrogenation are determined by the Kissinger method and via the fitting of solid-state reaction kinetic models to isothermal volumetric measurements. Furthermore, the hydrogen absorption-desorption cycling stability is assessed by titration measurements. Finally, the kinetic behaviour and the reversible hydrogen storage capacity of the Li-RHC are discussed.
Fil: Jepsen, Julian. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Fil: Milanese, Chiara. Università degli Studi di Pavia; Italia
Fil: Puszkiel, Julián Atilio. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Girella, Alessandro. Università degli Studi di Pavia; Italia
Fil: Schiavo, Benedetto. Università degli Studi di Palermo; Italia
Fil: Lozano, Gustavo A.. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Fil: Capurso, Giovanni. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Fil: Von Colbe, José M. Bellosta. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Fil: Marini, Amedeo. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Kabelac, Stephan. Leibniz Universität Hannover; Alemania
Fil: Dornheim, Martin. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Fil: Klassen, Thomas. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Materia
BOROHYDRIDES
HYDROGEN STORAGE
LIBH4-MGH2
MATERIAL PROPERTIES
METAL HYDRIDES
REACTIVE HYDRIDE COMPOSITES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/98294
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/98294
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic propertiesJepsen, JulianMilanese, ChiaraPuszkiel, Julián AtilioGirella, AlessandroSchiavo, BenedettoLozano, Gustavo A.Capurso, GiovanniVon Colbe, José M. BellostaMarini, AmedeoKabelac, StephanDornheim, MartinKlassen, ThomasBOROHYDRIDESHYDROGEN STORAGELIBH4-MGH2MATERIAL PROPERTIESMETAL HYDRIDESREACTIVE HYDRIDE COMPOSITEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Reaction kinetic behaviour and cycling stability of the 2LiBH4-MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination and discussion about the properties; different measurement methods are applied and compared. The activation energies for both hydrogenation and dehydrogenation are determined by the Kissinger method and via the fitting of solid-state reaction kinetic models to isothermal volumetric measurements. Furthermore, the hydrogen absorption-desorption cycling stability is assessed by titration measurements. Finally, the kinetic behaviour and the reversible hydrogen storage capacity of the Li-RHC are discussed.Fil: Jepsen, Julian. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; AlemaniaFil: Milanese, Chiara. Università degli Studi di Pavia; ItaliaFil: Puszkiel, Julián Atilio. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Girella, Alessandro. Università degli Studi di Pavia; ItaliaFil: Schiavo, Benedetto. Università degli Studi di Palermo; ItaliaFil: Lozano, Gustavo A.. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; AlemaniaFil: Capurso, Giovanni. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; AlemaniaFil: Von Colbe, José M. Bellosta. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; AlemaniaFil: Marini, Amedeo. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Kabelac, Stephan. Leibniz Universität Hannover; AlemaniaFil: Dornheim, Martin. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; AlemaniaFil: Klassen, Thomas. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; AlemaniaMDPI AG2018-05-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/98294Jepsen, Julian; Milanese, Chiara; Puszkiel, Julián Atilio; Girella, Alessandro; Schiavo, Benedetto; et al.; Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties; MDPI AG; Energies; 11; 5; 7-5-2018; 1-151996-1073CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.mdpi.com/1996-1073/11/5/1170/htminfo:eu-repo/semantics/altIdentifier/doi/10.3390/en11051170info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:04:15Zoai:ri.conicet.gov.ar:11336/98294instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:04:16.211CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties
title Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties
spellingShingle Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties
Jepsen, Julian
BOROHYDRIDES
HYDROGEN STORAGE
LIBH4-MGH2
MATERIAL PROPERTIES
METAL HYDRIDES
REACTIVE HYDRIDE COMPOSITES
title_short Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties
title_full Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties
title_fullStr Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties
title_full_unstemmed Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties
title_sort Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties
dc.creator.none.fl_str_mv Jepsen, Julian
Milanese, Chiara
Puszkiel, Julián Atilio
Girella, Alessandro
Schiavo, Benedetto
Lozano, Gustavo A.
Capurso, Giovanni
Von Colbe, José M. Bellosta
Marini, Amedeo
Kabelac, Stephan
Dornheim, Martin
Klassen, Thomas
author Jepsen, Julian
author_facet Jepsen, Julian
Milanese, Chiara
Puszkiel, Julián Atilio
Girella, Alessandro
Schiavo, Benedetto
Lozano, Gustavo A.
Capurso, Giovanni
Von Colbe, José M. Bellosta
Marini, Amedeo
Kabelac, Stephan
Dornheim, Martin
Klassen, Thomas
author_role author
author2 Milanese, Chiara
Puszkiel, Julián Atilio
Girella, Alessandro
Schiavo, Benedetto
Lozano, Gustavo A.
Capurso, Giovanni
Von Colbe, José M. Bellosta
Marini, Amedeo
Kabelac, Stephan
Dornheim, Martin
Klassen, Thomas
author2_role author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv BOROHYDRIDES
HYDROGEN STORAGE
LIBH4-MGH2
MATERIAL PROPERTIES
METAL HYDRIDES
REACTIVE HYDRIDE COMPOSITES
topic BOROHYDRIDES
HYDROGEN STORAGE
LIBH4-MGH2
MATERIAL PROPERTIES
METAL HYDRIDES
REACTIVE HYDRIDE COMPOSITES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Reaction kinetic behaviour and cycling stability of the 2LiBH4-MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination and discussion about the properties; different measurement methods are applied and compared. The activation energies for both hydrogenation and dehydrogenation are determined by the Kissinger method and via the fitting of solid-state reaction kinetic models to isothermal volumetric measurements. Furthermore, the hydrogen absorption-desorption cycling stability is assessed by titration measurements. Finally, the kinetic behaviour and the reversible hydrogen storage capacity of the Li-RHC are discussed.
Fil: Jepsen, Julian. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Fil: Milanese, Chiara. Università degli Studi di Pavia; Italia
Fil: Puszkiel, Julián Atilio. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Girella, Alessandro. Università degli Studi di Pavia; Italia
Fil: Schiavo, Benedetto. Università degli Studi di Palermo; Italia
Fil: Lozano, Gustavo A.. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Fil: Capurso, Giovanni. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Fil: Von Colbe, José M. Bellosta. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Fil: Marini, Amedeo. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Kabelac, Stephan. Leibniz Universität Hannover; Alemania
Fil: Dornheim, Martin. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
Fil: Klassen, Thomas. Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung; Alemania
description Reaction kinetic behaviour and cycling stability of the 2LiBH4-MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination and discussion about the properties; different measurement methods are applied and compared. The activation energies for both hydrogenation and dehydrogenation are determined by the Kissinger method and via the fitting of solid-state reaction kinetic models to isothermal volumetric measurements. Furthermore, the hydrogen absorption-desorption cycling stability is assessed by titration measurements. Finally, the kinetic behaviour and the reversible hydrogen storage capacity of the Li-RHC are discussed.
publishDate 2018
dc.date.none.fl_str_mv 2018-05-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/98294
Jepsen, Julian; Milanese, Chiara; Puszkiel, Julián Atilio; Girella, Alessandro; Schiavo, Benedetto; et al.; Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties; MDPI AG; Energies; 11; 5; 7-5-2018; 1-15
1996-1073
CONICET Digital
CONICET
url http://hdl.handle.net/11336/98294
identifier_str_mv Jepsen, Julian; Milanese, Chiara; Puszkiel, Julián Atilio; Girella, Alessandro; Schiavo, Benedetto; et al.; Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties; MDPI AG; Energies; 11; 5; 7-5-2018; 1-15
1996-1073
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.mdpi.com/1996-1073/11/5/1170/htm
info:eu-repo/semantics/altIdentifier/doi/10.3390/en11051170
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI AG
publisher.none.fl_str_mv MDPI AG
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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