Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization
- Autores
- Akdemir, Meryem S.; Simian, Marina; Theato, Patrick; Mutlu, Hatice
- Año de publicación
- 2022
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Over the years, nitrogen-rich functional groups like tetrazole and its derivatives have received increasing interest in the chemistry of small molecules. There is a continuously growing interest in polymers decorated with nitrogen for potential biomedical applications because of their broad range of biological properties, such as being antibacterial, anticarcinogenic, and anti-inflammatory. On this premise, a new synthesis route is reported for nitrogen-decorated polymers via the combination of Ugi-azide four-multicomponent reaction (UA-4MCR) and thiol-ene polymerization. Accordingly, α,ω-diene monomers decorated with (bis-)1,5-disubstituted-1H-tetrazoles (bis-1,5-DS-Ts) are synthesized by using the UA-4MCR. Subsequently, the light-induced thiol-ene polymerization facilitates the efficient synthesis of novel tetrazole-decorated polymers with apparent number average molecular mass (Mn) up to 62 000 g mol−1, which are characterized for their chemical, thermal, and optical properties. The comprehensive characterization of the synthesized polymers is paving the way toward a wealth of opportunities, ranging from biomaterials to energy storage−relevant materials.
Fil: Akdemir, Meryem S.. Karlsruhe Institute of Technology; Alemania
Fil: Simian, Marina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Theato, Patrick. Karlsruhe Institute of Technology; Alemania
Fil: Mutlu, Hatice. Centre National de la Recherche Scientifique; Francia - Materia
-
polymers decorated with nitrogen
biomedical applications
Ugi-azide four-multicomponent reaction
thiol-ene polymerization - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/239414
Ver los metadatos del registro completo
id |
CONICETDig_be3231b50803b0c3b38a252187704bb8 |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/239414 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene PolymerizationAkdemir, Meryem S.Simian, MarinaTheato, PatrickMutlu, Haticepolymers decorated with nitrogenbiomedical applicationsUgi-azide four-multicomponent reactionthiol-ene polymerizationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Over the years, nitrogen-rich functional groups like tetrazole and its derivatives have received increasing interest in the chemistry of small molecules. There is a continuously growing interest in polymers decorated with nitrogen for potential biomedical applications because of their broad range of biological properties, such as being antibacterial, anticarcinogenic, and anti-inflammatory. On this premise, a new synthesis route is reported for nitrogen-decorated polymers via the combination of Ugi-azide four-multicomponent reaction (UA-4MCR) and thiol-ene polymerization. Accordingly, α,ω-diene monomers decorated with (bis-)1,5-disubstituted-1H-tetrazoles (bis-1,5-DS-Ts) are synthesized by using the UA-4MCR. Subsequently, the light-induced thiol-ene polymerization facilitates the efficient synthesis of novel tetrazole-decorated polymers with apparent number average molecular mass (Mn) up to 62 000 g mol−1, which are characterized for their chemical, thermal, and optical properties. The comprehensive characterization of the synthesized polymers is paving the way toward a wealth of opportunities, ranging from biomaterials to energy storage−relevant materials.Fil: Akdemir, Meryem S.. Karlsruhe Institute of Technology; AlemaniaFil: Simian, Marina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Theato, Patrick. Karlsruhe Institute of Technology; AlemaniaFil: Mutlu, Hatice. Centre National de la Recherche Scientifique; FranciaWiley VCH Verlag2022-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/239414Akdemir, Meryem S.; Simian, Marina; Theato, Patrick; Mutlu, Hatice; Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 224; 3; 12-2022; 1-101022-1352CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/macp.202200371info:eu-repo/semantics/altIdentifier/doi/10.1002/macp.202200371info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:56:20Zoai:ri.conicet.gov.ar:11336/239414instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:56:20.706CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization |
title |
Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization |
spellingShingle |
Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization Akdemir, Meryem S. polymers decorated with nitrogen biomedical applications Ugi-azide four-multicomponent reaction thiol-ene polymerization |
title_short |
Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization |
title_full |
Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization |
title_fullStr |
Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization |
title_full_unstemmed |
Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization |
title_sort |
Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization |
dc.creator.none.fl_str_mv |
Akdemir, Meryem S. Simian, Marina Theato, Patrick Mutlu, Hatice |
author |
Akdemir, Meryem S. |
author_facet |
Akdemir, Meryem S. Simian, Marina Theato, Patrick Mutlu, Hatice |
author_role |
author |
author2 |
Simian, Marina Theato, Patrick Mutlu, Hatice |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
polymers decorated with nitrogen biomedical applications Ugi-azide four-multicomponent reaction thiol-ene polymerization |
topic |
polymers decorated with nitrogen biomedical applications Ugi-azide four-multicomponent reaction thiol-ene polymerization |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Over the years, nitrogen-rich functional groups like tetrazole and its derivatives have received increasing interest in the chemistry of small molecules. There is a continuously growing interest in polymers decorated with nitrogen for potential biomedical applications because of their broad range of biological properties, such as being antibacterial, anticarcinogenic, and anti-inflammatory. On this premise, a new synthesis route is reported for nitrogen-decorated polymers via the combination of Ugi-azide four-multicomponent reaction (UA-4MCR) and thiol-ene polymerization. Accordingly, α,ω-diene monomers decorated with (bis-)1,5-disubstituted-1H-tetrazoles (bis-1,5-DS-Ts) are synthesized by using the UA-4MCR. Subsequently, the light-induced thiol-ene polymerization facilitates the efficient synthesis of novel tetrazole-decorated polymers with apparent number average molecular mass (Mn) up to 62 000 g mol−1, which are characterized for their chemical, thermal, and optical properties. The comprehensive characterization of the synthesized polymers is paving the way toward a wealth of opportunities, ranging from biomaterials to energy storage−relevant materials. Fil: Akdemir, Meryem S.. Karlsruhe Institute of Technology; Alemania Fil: Simian, Marina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Theato, Patrick. Karlsruhe Institute of Technology; Alemania Fil: Mutlu, Hatice. Centre National de la Recherche Scientifique; Francia |
description |
Over the years, nitrogen-rich functional groups like tetrazole and its derivatives have received increasing interest in the chemistry of small molecules. There is a continuously growing interest in polymers decorated with nitrogen for potential biomedical applications because of their broad range of biological properties, such as being antibacterial, anticarcinogenic, and anti-inflammatory. On this premise, a new synthesis route is reported for nitrogen-decorated polymers via the combination of Ugi-azide four-multicomponent reaction (UA-4MCR) and thiol-ene polymerization. Accordingly, α,ω-diene monomers decorated with (bis-)1,5-disubstituted-1H-tetrazoles (bis-1,5-DS-Ts) are synthesized by using the UA-4MCR. Subsequently, the light-induced thiol-ene polymerization facilitates the efficient synthesis of novel tetrazole-decorated polymers with apparent number average molecular mass (Mn) up to 62 000 g mol−1, which are characterized for their chemical, thermal, and optical properties. The comprehensive characterization of the synthesized polymers is paving the way toward a wealth of opportunities, ranging from biomaterials to energy storage−relevant materials. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/239414 Akdemir, Meryem S.; Simian, Marina; Theato, Patrick; Mutlu, Hatice; Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 224; 3; 12-2022; 1-10 1022-1352 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/239414 |
identifier_str_mv |
Akdemir, Meryem S.; Simian, Marina; Theato, Patrick; Mutlu, Hatice; Synthesis of Novel (bis‐)1,5‐Disubstituted‐1 H ‐tetrazole‐Decorated Monomers and Their Respective Polymers via Thiol‐ene Polymerization; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 224; 3; 12-2022; 1-10 1022-1352 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/macp.202200371 info:eu-repo/semantics/altIdentifier/doi/10.1002/macp.202200371 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley VCH Verlag |
publisher.none.fl_str_mv |
Wiley VCH Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613692769959936 |
score |
13.070432 |