Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures

Autores
Torres, Karina Andrea; Espinosa, Hector Jose Maria
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This contribution explores the influence of curved unstable distillation boundaries on the performance of batch distillations in ternary mixtures and its incorporation into a conceptual modeling framework under the assumption of a batch rectifier with an infinite number of stages. First, the concept of preferred separation in batch distillation is presented. Calculation of "pitchfork" distillation boundaries is then determined using a robust predictor-corrector algorithm based on improved memory method with the purpose of estimating the maximum feasible distillate composition in the preferred separation line. Four highly nonideal systems are studied. Finally, the model is extended to allow simulation of the operation at different reflux policies. Results of a complete simulation performed with the enhanced conceptual model are shown for the system octane/2-ethoxyethanol/ethylbenzene.
Fil: Torres, Karina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; Argentina
Fil: Espinosa, Hector Jose Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; Argentina
Materia
Batch Distillation
Design
Distillation Boundaries
Pitchfork Bifurcation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/70195
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixturesTorres, Karina AndreaEspinosa, Hector Jose MariaBatch DistillationDesignDistillation BoundariesPitchfork Bifurcationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This contribution explores the influence of curved unstable distillation boundaries on the performance of batch distillations in ternary mixtures and its incorporation into a conceptual modeling framework under the assumption of a batch rectifier with an infinite number of stages. First, the concept of preferred separation in batch distillation is presented. Calculation of "pitchfork" distillation boundaries is then determined using a robust predictor-corrector algorithm based on improved memory method with the purpose of estimating the maximum feasible distillate composition in the preferred separation line. Four highly nonideal systems are studied. Finally, the model is extended to allow simulation of the operation at different reflux policies. Results of a complete simulation performed with the enhanced conceptual model are shown for the system octane/2-ethoxyethanol/ethylbenzene.Fil: Torres, Karina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; ArgentinaFil: Espinosa, Hector Jose Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; ArgentinaAmerican Chemical Society2012-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70195Torres, Karina Andrea; Espinosa, Hector Jose Maria; Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures; American Chemical Society; Industrial & Engineering Chemical Research; 51; 47; 11-2012; 15448-154550888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie301933zinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:59:02Zoai:ri.conicet.gov.ar:11336/70195instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:59:02.313CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures
title Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures
spellingShingle Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures
Torres, Karina Andrea
Batch Distillation
Design
Distillation Boundaries
Pitchfork Bifurcation
title_short Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures
title_full Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures
title_fullStr Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures
title_full_unstemmed Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures
title_sort Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures
dc.creator.none.fl_str_mv Torres, Karina Andrea
Espinosa, Hector Jose Maria
author Torres, Karina Andrea
author_facet Torres, Karina Andrea
Espinosa, Hector Jose Maria
author_role author
author2 Espinosa, Hector Jose Maria
author2_role author
dc.subject.none.fl_str_mv Batch Distillation
Design
Distillation Boundaries
Pitchfork Bifurcation
topic Batch Distillation
Design
Distillation Boundaries
Pitchfork Bifurcation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This contribution explores the influence of curved unstable distillation boundaries on the performance of batch distillations in ternary mixtures and its incorporation into a conceptual modeling framework under the assumption of a batch rectifier with an infinite number of stages. First, the concept of preferred separation in batch distillation is presented. Calculation of "pitchfork" distillation boundaries is then determined using a robust predictor-corrector algorithm based on improved memory method with the purpose of estimating the maximum feasible distillate composition in the preferred separation line. Four highly nonideal systems are studied. Finally, the model is extended to allow simulation of the operation at different reflux policies. Results of a complete simulation performed with the enhanced conceptual model are shown for the system octane/2-ethoxyethanol/ethylbenzene.
Fil: Torres, Karina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; Argentina
Fil: Espinosa, Hector Jose Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; Argentina
description This contribution explores the influence of curved unstable distillation boundaries on the performance of batch distillations in ternary mixtures and its incorporation into a conceptual modeling framework under the assumption of a batch rectifier with an infinite number of stages. First, the concept of preferred separation in batch distillation is presented. Calculation of "pitchfork" distillation boundaries is then determined using a robust predictor-corrector algorithm based on improved memory method with the purpose of estimating the maximum feasible distillate composition in the preferred separation line. Four highly nonideal systems are studied. Finally, the model is extended to allow simulation of the operation at different reflux policies. Results of a complete simulation performed with the enhanced conceptual model are shown for the system octane/2-ethoxyethanol/ethylbenzene.
publishDate 2012
dc.date.none.fl_str_mv 2012-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/70195
Torres, Karina Andrea; Espinosa, Hector Jose Maria; Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures; American Chemical Society; Industrial & Engineering Chemical Research; 51; 47; 11-2012; 15448-15455
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/70195
identifier_str_mv Torres, Karina Andrea; Espinosa, Hector Jose Maria; Incorporating pinch distillation boundaries into the conceptual modeling of batch distillations: Ternary mixtures; American Chemical Society; Industrial & Engineering Chemical Research; 51; 47; 11-2012; 15448-15455
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ie301933z
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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