Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes

Autores
Torres Sciancalepore, Rodrigo Agustin; Nassini, Daniela; Asensio, Daniela Anabel; Bohé, Ana; Rodriguez, Rosa Ana; Fouga, Gastón Galo
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this work was to study the potential synergistic effects of the mixing factor on the kinetics parameters and products obtained through co-pyrolysis of two wastes from Rosa rubiginosa rosehip, and further co- gasification with CO2 of the remaining biochar. Thermogravimetric analysis showed that 6 different processes occur by slow pyrolysis (heating rates of 5, 10, and 20 ◦C/min), associated with the decomposition of hemi- celluloses, cellulose, lignin, and CaCO3 from the ashes. Isoconversional methods determined activation energies of 84.68?223.42, 230.11?270.85, 187.58?303.37, and 400.11?421.71 kJ/mol for hemicellulose, cellulose, lignin, and CaCO3 decomposition, respectively. In most cases, the activation energy from co-pyrolysis was higher for the blends than for the pure wastes, which means that the blends are less reactive to pyrolysis. Gas and tar analyses showed that the blend with 75 % husk waste and 25 % seed waste produced the most hydrogen (5.639 mmol/g biomass), while the blend with 25 % husk waste and 75 % seed waste produced the most carbon monoxide (3.642 mmol/g biomass). The biochar produced by the blends and pure wastes were thermally treated with CO2 to compare reactivity to gasification. It was concluded that the addition of husk waste to the blend increases the reactivity of the biochar obtained, mainly due to its higher ash content.
Fil: Torres Sciancalepore, Rodrigo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Nassini, Daniela. Departamento de Fisicoquimica y Control de Calidad ; Gerencia Complejo Tecnologico Pilcaniyeu ; Comision Nacional de Energia Atomica; . Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Asensio, Daniela Anabel. Departamento de Fisicoquimica y Control de Calidad ; Gerencia Complejo Tecnologico Pilcaniyeu ; Comision Nacional de Energia Atomica;
Fil: Bohé, Ana. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Rodriguez, Rosa Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Fouga, Gastón Galo. Departamento de Fisicoquimica y Control de Calidad ; Gerencia Complejo Tecnologico Pilcaniyeu ; Comision Nacional de Energia Atomica;
Materia
SLOW PYROLYSIS
CO-PYROLYSIS
ROSEHIP WASTE
SYNERGISTIC EFFECTS
BIOMASS BLEND
KINETIC PARAMETERS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/241195
Acceder
id CONICETDig_bcf5514afd9587adbe6a17fbe5c0adb3
oai_identifier_str oai:ri.conicet.gov.ar:11336/241195
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastesTorres Sciancalepore, Rodrigo AgustinNassini, DanielaAsensio, Daniela AnabelBohé, AnaRodriguez, Rosa AnaFouga, Gastón GaloSLOW PYROLYSISCO-PYROLYSISROSEHIP WASTESYNERGISTIC EFFECTSBIOMASS BLENDKINETIC PARAMETERShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The aim of this work was to study the potential synergistic effects of the mixing factor on the kinetics parameters and products obtained through co-pyrolysis of two wastes from Rosa rubiginosa rosehip, and further co- gasification with CO2 of the remaining biochar. Thermogravimetric analysis showed that 6 different processes occur by slow pyrolysis (heating rates of 5, 10, and 20 ◦C/min), associated with the decomposition of hemi- celluloses, cellulose, lignin, and CaCO3 from the ashes. Isoconversional methods determined activation energies of 84.68?223.42, 230.11?270.85, 187.58?303.37, and 400.11?421.71 kJ/mol for hemicellulose, cellulose, lignin, and CaCO3 decomposition, respectively. In most cases, the activation energy from co-pyrolysis was higher for the blends than for the pure wastes, which means that the blends are less reactive to pyrolysis. Gas and tar analyses showed that the blend with 75 % husk waste and 25 % seed waste produced the most hydrogen (5.639 mmol/g biomass), while the blend with 25 % husk waste and 75 % seed waste produced the most carbon monoxide (3.642 mmol/g biomass). The biochar produced by the blends and pure wastes were thermally treated with CO2 to compare reactivity to gasification. It was concluded that the addition of husk waste to the blend increases the reactivity of the biochar obtained, mainly due to its higher ash content.Fil: Torres Sciancalepore, Rodrigo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Nassini, Daniela. Departamento de Fisicoquimica y Control de Calidad ; Gerencia Complejo Tecnologico Pilcaniyeu ; Comision Nacional de Energia Atomica; . Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Asensio, Daniela Anabel. Departamento de Fisicoquimica y Control de Calidad ; Gerencia Complejo Tecnologico Pilcaniyeu ; Comision Nacional de Energia Atomica;Fil: Bohé, Ana. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Rodriguez, Rosa Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Fouga, Gastón Galo. Departamento de Fisicoquimica y Control de Calidad ; Gerencia Complejo Tecnologico Pilcaniyeu ; Comision Nacional de Energia Atomica;Pergamon-Elsevier Science Ltd2024-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/241195Torres Sciancalepore, Rodrigo Agustin; Nassini, Daniela; Asensio, Daniela Anabel; Bohé, Ana; Rodriguez, Rosa Ana; et al.; Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes; Pergamon-Elsevier Science Ltd; Energy Conservation and Management; 302; 2-2024; 1-160196-8904CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/journal/energy-conversion-and-managementinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.enconman.2024.118095info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:50:00Zoai:ri.conicet.gov.ar:11336/241195instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:50:00.672CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes
title Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes
spellingShingle Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes
Torres Sciancalepore, Rodrigo Agustin
SLOW PYROLYSIS
CO-PYROLYSIS
ROSEHIP WASTE
SYNERGISTIC EFFECTS
BIOMASS BLEND
KINETIC PARAMETERS
title_short Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes
title_full Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes
title_fullStr Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes
title_full_unstemmed Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes
title_sort Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes
dc.creator.none.fl_str_mv Torres Sciancalepore, Rodrigo Agustin
Nassini, Daniela
Asensio, Daniela Anabel
Bohé, Ana
Rodriguez, Rosa Ana
Fouga, Gastón Galo
author Torres Sciancalepore, Rodrigo Agustin
author_facet Torres Sciancalepore, Rodrigo Agustin
Nassini, Daniela
Asensio, Daniela Anabel
Bohé, Ana
Rodriguez, Rosa Ana
Fouga, Gastón Galo
author_role author
author2 Nassini, Daniela
Asensio, Daniela Anabel
Bohé, Ana
Rodriguez, Rosa Ana
Fouga, Gastón Galo
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv SLOW PYROLYSIS
CO-PYROLYSIS
ROSEHIP WASTE
SYNERGISTIC EFFECTS
BIOMASS BLEND
KINETIC PARAMETERS
topic SLOW PYROLYSIS
CO-PYROLYSIS
ROSEHIP WASTE
SYNERGISTIC EFFECTS
BIOMASS BLEND
KINETIC PARAMETERS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The aim of this work was to study the potential synergistic effects of the mixing factor on the kinetics parameters and products obtained through co-pyrolysis of two wastes from Rosa rubiginosa rosehip, and further co- gasification with CO2 of the remaining biochar. Thermogravimetric analysis showed that 6 different processes occur by slow pyrolysis (heating rates of 5, 10, and 20 ◦C/min), associated with the decomposition of hemi- celluloses, cellulose, lignin, and CaCO3 from the ashes. Isoconversional methods determined activation energies of 84.68?223.42, 230.11?270.85, 187.58?303.37, and 400.11?421.71 kJ/mol for hemicellulose, cellulose, lignin, and CaCO3 decomposition, respectively. In most cases, the activation energy from co-pyrolysis was higher for the blends than for the pure wastes, which means that the blends are less reactive to pyrolysis. Gas and tar analyses showed that the blend with 75 % husk waste and 25 % seed waste produced the most hydrogen (5.639 mmol/g biomass), while the blend with 25 % husk waste and 75 % seed waste produced the most carbon monoxide (3.642 mmol/g biomass). The biochar produced by the blends and pure wastes were thermally treated with CO2 to compare reactivity to gasification. It was concluded that the addition of husk waste to the blend increases the reactivity of the biochar obtained, mainly due to its higher ash content.
Fil: Torres Sciancalepore, Rodrigo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Nassini, Daniela. Departamento de Fisicoquimica y Control de Calidad ; Gerencia Complejo Tecnologico Pilcaniyeu ; Comision Nacional de Energia Atomica; . Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Asensio, Daniela Anabel. Departamento de Fisicoquimica y Control de Calidad ; Gerencia Complejo Tecnologico Pilcaniyeu ; Comision Nacional de Energia Atomica;
Fil: Bohé, Ana. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Rodriguez, Rosa Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Fouga, Gastón Galo. Departamento de Fisicoquimica y Control de Calidad ; Gerencia Complejo Tecnologico Pilcaniyeu ; Comision Nacional de Energia Atomica;
description The aim of this work was to study the potential synergistic effects of the mixing factor on the kinetics parameters and products obtained through co-pyrolysis of two wastes from Rosa rubiginosa rosehip, and further co- gasification with CO2 of the remaining biochar. Thermogravimetric analysis showed that 6 different processes occur by slow pyrolysis (heating rates of 5, 10, and 20 ◦C/min), associated with the decomposition of hemi- celluloses, cellulose, lignin, and CaCO3 from the ashes. Isoconversional methods determined activation energies of 84.68?223.42, 230.11?270.85, 187.58?303.37, and 400.11?421.71 kJ/mol for hemicellulose, cellulose, lignin, and CaCO3 decomposition, respectively. In most cases, the activation energy from co-pyrolysis was higher for the blends than for the pure wastes, which means that the blends are less reactive to pyrolysis. Gas and tar analyses showed that the blend with 75 % husk waste and 25 % seed waste produced the most hydrogen (5.639 mmol/g biomass), while the blend with 25 % husk waste and 75 % seed waste produced the most carbon monoxide (3.642 mmol/g biomass). The biochar produced by the blends and pure wastes were thermally treated with CO2 to compare reactivity to gasification. It was concluded that the addition of husk waste to the blend increases the reactivity of the biochar obtained, mainly due to its higher ash content.
publishDate 2024
dc.date.none.fl_str_mv 2024-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/241195
Torres Sciancalepore, Rodrigo Agustin; Nassini, Daniela; Asensio, Daniela Anabel; Bohé, Ana; Rodriguez, Rosa Ana; et al.; Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes; Pergamon-Elsevier Science Ltd; Energy Conservation and Management; 302; 2-2024; 1-16
0196-8904
CONICET Digital
CONICET
url http://hdl.handle.net/11336/241195
identifier_str_mv Torres Sciancalepore, Rodrigo Agustin; Nassini, Daniela; Asensio, Daniela Anabel; Bohé, Ana; Rodriguez, Rosa Ana; et al.; Synergistic effects of the mixing factor on the kinetics and products obtained by co-pyrolysis of Rosa rubiginosa rosehip seed and husk wastes; Pergamon-Elsevier Science Ltd; Energy Conservation and Management; 302; 2-2024; 1-16
0196-8904
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/journal/energy-conversion-and-management
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.enconman.2024.118095
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613543830224896
score 13.070432

Publicaciones similares