Pyrolysis of soybean waste: a route to biocarbon for pesticides capture

Autores
Ceballos, Noelia Marcela; Boneau, Gonzalo D.; Rimondino, Guido Noé; Malanca, Fabio Ernesto; Peláez, Walter José
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This study explores the potential use of biomass residues from soybean pressing via static pyrolysis to produce carbonaceous materials for pesticide adsorption. It emphasizes concerns regarding the environmental impact of agroindustrial waste and the persistent nature of pesticides in soil and water systems. Aims: To investigate the efficacy of biochar obtained from soybean waste in adsorbing pesticides. Specifically, to analyze the gas products generated during pyrolysis and characterize the obtained carbonaceous material for its adsorption capabilities. Methods: Soybean residue underwent static pyrolysis at various temperatures and durations. Gas analysis utilizing FTIR spectroscopy identified the gaseous products generated during the pyrolysis process. The obtained biochar underwent successive washes and characterization through FTIR spectra comparison with commercial activated carbon. Through absorption assays, using UV-VIS spectroscopy, investigations were conducted on the solid biocarbon fractions to evaluate their capacity for absorbing pesticides. Results: Gas Analysis: The study revealed the production of volatile organic compounds (VOCs) and highlighted the prevalence of mono-carbon compounds with increased temperature and pyrolysis time. The analysis demonstrated consistent carbon mass percentages across different reaction conditions. Characterization of Biochar: Comparison with activated carbon indicated structural similarities with eightened intensity in certain bands, suggesting the presence of incomplete cellulose cracking in the obtained biochar. Regarding the Chlorothalonil, Atrazine and DIcamba remotion, notably, the concentration of Chlorothalonil in a 7:3 water:acetonitrile solution decreases by 77 % through adsorption on the carbons. Discussion: The investigation examined the adsorption efficiency of the biochar for Chlorothalonil, Atrazine, and Dicamba from aqueous solutions. Chlorothalonil exhibited substantial retention by the biochar, while Atrazine showed comparatively lower adsorption effectiveness. Remarkably, Dicamba did not demonstrate retention by either the biochar or activated carbon. Conclusion: The study underscores the potential of pyrolyzed soybean waste for pesticide adsorption, particularly highlighting Chlorothalonil's strong affinity with the carbonaceous structure. Further research is needed to optimize adsorption properties and explores potential enhancements of these materials throughadditional treatment methods, offering promising avenues for environmental remediation.
Fil: Ceballos, Noelia Marcela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Boneau, Gonzalo D.. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina
Fil: Rimondino, Guido Noé. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Malanca, Fabio Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Peláez, Walter José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
PYROLYSIS
MESOPOROUS CARBONS
CHLOROTHALONIL
ATRAZINE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/256338
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Pyrolysis of soybean waste: a route to biocarbon for pesticides captureCeballos, Noelia MarcelaBoneau, Gonzalo D.Rimondino, Guido NoéMalanca, Fabio ErnestoPeláez, Walter JoséPYROLYSISMESOPOROUS CARBONSCHLOROTHALONILATRAZINEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This study explores the potential use of biomass residues from soybean pressing via static pyrolysis to produce carbonaceous materials for pesticide adsorption. It emphasizes concerns regarding the environmental impact of agroindustrial waste and the persistent nature of pesticides in soil and water systems. Aims: To investigate the efficacy of biochar obtained from soybean waste in adsorbing pesticides. Specifically, to analyze the gas products generated during pyrolysis and characterize the obtained carbonaceous material for its adsorption capabilities. Methods: Soybean residue underwent static pyrolysis at various temperatures and durations. Gas analysis utilizing FTIR spectroscopy identified the gaseous products generated during the pyrolysis process. The obtained biochar underwent successive washes and characterization through FTIR spectra comparison with commercial activated carbon. Through absorption assays, using UV-VIS spectroscopy, investigations were conducted on the solid biocarbon fractions to evaluate their capacity for absorbing pesticides. Results: Gas Analysis: The study revealed the production of volatile organic compounds (VOCs) and highlighted the prevalence of mono-carbon compounds with increased temperature and pyrolysis time. The analysis demonstrated consistent carbon mass percentages across different reaction conditions. Characterization of Biochar: Comparison with activated carbon indicated structural similarities with eightened intensity in certain bands, suggesting the presence of incomplete cellulose cracking in the obtained biochar. Regarding the Chlorothalonil, Atrazine and DIcamba remotion, notably, the concentration of Chlorothalonil in a 7:3 water:acetonitrile solution decreases by 77 % through adsorption on the carbons. Discussion: The investigation examined the adsorption efficiency of the biochar for Chlorothalonil, Atrazine, and Dicamba from aqueous solutions. Chlorothalonil exhibited substantial retention by the biochar, while Atrazine showed comparatively lower adsorption effectiveness. Remarkably, Dicamba did not demonstrate retention by either the biochar or activated carbon. Conclusion: The study underscores the potential of pyrolyzed soybean waste for pesticide adsorption, particularly highlighting Chlorothalonil's strong affinity with the carbonaceous structure. Further research is needed to optimize adsorption properties and explores potential enhancements of these materials throughadditional treatment methods, offering promising avenues for environmental remediation.Fil: Ceballos, Noelia Marcela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Boneau, Gonzalo D.. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; ArgentinaFil: Rimondino, Guido Noé. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Malanca, Fabio Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Peláez, Walter José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaUniversidad de Vassouras2023-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/256338Ceballos, Noelia Marcela; Boneau, Gonzalo D.; Rimondino, Guido Noé; Malanca, Fabio Ernesto; Peláez, Walter José; Pyrolysis of soybean waste: a route to biocarbon for pesticides capture; Universidad de Vassouras; Southern Journal of Sciences; 31; 36; 11-2023; 1-82764-5967CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sjofsciences.com/server/jornal/2023v2/CEBALLOS_pgs_01_08.pdfinfo:eu-repo/semantics/altIdentifier/doi/ 10.48141/SBJCHEM.v31.n36.2023_CEBALLOS_pgs_01_08.pdfinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:02:19Zoai:ri.conicet.gov.ar:11336/256338instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:02:20.097CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Pyrolysis of soybean waste: a route to biocarbon for pesticides capture
title Pyrolysis of soybean waste: a route to biocarbon for pesticides capture
spellingShingle Pyrolysis of soybean waste: a route to biocarbon for pesticides capture
Ceballos, Noelia Marcela
PYROLYSIS
MESOPOROUS CARBONS
CHLOROTHALONIL
ATRAZINE
title_short Pyrolysis of soybean waste: a route to biocarbon for pesticides capture
title_full Pyrolysis of soybean waste: a route to biocarbon for pesticides capture
title_fullStr Pyrolysis of soybean waste: a route to biocarbon for pesticides capture
title_full_unstemmed Pyrolysis of soybean waste: a route to biocarbon for pesticides capture
title_sort Pyrolysis of soybean waste: a route to biocarbon for pesticides capture
dc.creator.none.fl_str_mv Ceballos, Noelia Marcela
Boneau, Gonzalo D.
Rimondino, Guido Noé
Malanca, Fabio Ernesto
Peláez, Walter José
author Ceballos, Noelia Marcela
author_facet Ceballos, Noelia Marcela
Boneau, Gonzalo D.
Rimondino, Guido Noé
Malanca, Fabio Ernesto
Peláez, Walter José
author_role author
author2 Boneau, Gonzalo D.
Rimondino, Guido Noé
Malanca, Fabio Ernesto
Peláez, Walter José
author2_role author
author
author
author
dc.subject.none.fl_str_mv PYROLYSIS
MESOPOROUS CARBONS
CHLOROTHALONIL
ATRAZINE
topic PYROLYSIS
MESOPOROUS CARBONS
CHLOROTHALONIL
ATRAZINE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This study explores the potential use of biomass residues from soybean pressing via static pyrolysis to produce carbonaceous materials for pesticide adsorption. It emphasizes concerns regarding the environmental impact of agroindustrial waste and the persistent nature of pesticides in soil and water systems. Aims: To investigate the efficacy of biochar obtained from soybean waste in adsorbing pesticides. Specifically, to analyze the gas products generated during pyrolysis and characterize the obtained carbonaceous material for its adsorption capabilities. Methods: Soybean residue underwent static pyrolysis at various temperatures and durations. Gas analysis utilizing FTIR spectroscopy identified the gaseous products generated during the pyrolysis process. The obtained biochar underwent successive washes and characterization through FTIR spectra comparison with commercial activated carbon. Through absorption assays, using UV-VIS spectroscopy, investigations were conducted on the solid biocarbon fractions to evaluate their capacity for absorbing pesticides. Results: Gas Analysis: The study revealed the production of volatile organic compounds (VOCs) and highlighted the prevalence of mono-carbon compounds with increased temperature and pyrolysis time. The analysis demonstrated consistent carbon mass percentages across different reaction conditions. Characterization of Biochar: Comparison with activated carbon indicated structural similarities with eightened intensity in certain bands, suggesting the presence of incomplete cellulose cracking in the obtained biochar. Regarding the Chlorothalonil, Atrazine and DIcamba remotion, notably, the concentration of Chlorothalonil in a 7:3 water:acetonitrile solution decreases by 77 % through adsorption on the carbons. Discussion: The investigation examined the adsorption efficiency of the biochar for Chlorothalonil, Atrazine, and Dicamba from aqueous solutions. Chlorothalonil exhibited substantial retention by the biochar, while Atrazine showed comparatively lower adsorption effectiveness. Remarkably, Dicamba did not demonstrate retention by either the biochar or activated carbon. Conclusion: The study underscores the potential of pyrolyzed soybean waste for pesticide adsorption, particularly highlighting Chlorothalonil's strong affinity with the carbonaceous structure. Further research is needed to optimize adsorption properties and explores potential enhancements of these materials throughadditional treatment methods, offering promising avenues for environmental remediation.
Fil: Ceballos, Noelia Marcela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Boneau, Gonzalo D.. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina
Fil: Rimondino, Guido Noé. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Malanca, Fabio Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Peláez, Walter José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description This study explores the potential use of biomass residues from soybean pressing via static pyrolysis to produce carbonaceous materials for pesticide adsorption. It emphasizes concerns regarding the environmental impact of agroindustrial waste and the persistent nature of pesticides in soil and water systems. Aims: To investigate the efficacy of biochar obtained from soybean waste in adsorbing pesticides. Specifically, to analyze the gas products generated during pyrolysis and characterize the obtained carbonaceous material for its adsorption capabilities. Methods: Soybean residue underwent static pyrolysis at various temperatures and durations. Gas analysis utilizing FTIR spectroscopy identified the gaseous products generated during the pyrolysis process. The obtained biochar underwent successive washes and characterization through FTIR spectra comparison with commercial activated carbon. Through absorption assays, using UV-VIS spectroscopy, investigations were conducted on the solid biocarbon fractions to evaluate their capacity for absorbing pesticides. Results: Gas Analysis: The study revealed the production of volatile organic compounds (VOCs) and highlighted the prevalence of mono-carbon compounds with increased temperature and pyrolysis time. The analysis demonstrated consistent carbon mass percentages across different reaction conditions. Characterization of Biochar: Comparison with activated carbon indicated structural similarities with eightened intensity in certain bands, suggesting the presence of incomplete cellulose cracking in the obtained biochar. Regarding the Chlorothalonil, Atrazine and DIcamba remotion, notably, the concentration of Chlorothalonil in a 7:3 water:acetonitrile solution decreases by 77 % through adsorption on the carbons. Discussion: The investigation examined the adsorption efficiency of the biochar for Chlorothalonil, Atrazine, and Dicamba from aqueous solutions. Chlorothalonil exhibited substantial retention by the biochar, while Atrazine showed comparatively lower adsorption effectiveness. Remarkably, Dicamba did not demonstrate retention by either the biochar or activated carbon. Conclusion: The study underscores the potential of pyrolyzed soybean waste for pesticide adsorption, particularly highlighting Chlorothalonil's strong affinity with the carbonaceous structure. Further research is needed to optimize adsorption properties and explores potential enhancements of these materials throughadditional treatment methods, offering promising avenues for environmental remediation.
publishDate 2023
dc.date.none.fl_str_mv 2023-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/256338
Ceballos, Noelia Marcela; Boneau, Gonzalo D.; Rimondino, Guido Noé; Malanca, Fabio Ernesto; Peláez, Walter José; Pyrolysis of soybean waste: a route to biocarbon for pesticides capture; Universidad de Vassouras; Southern Journal of Sciences; 31; 36; 11-2023; 1-8
2764-5967
CONICET Digital
CONICET
url http://hdl.handle.net/11336/256338
identifier_str_mv Ceballos, Noelia Marcela; Boneau, Gonzalo D.; Rimondino, Guido Noé; Malanca, Fabio Ernesto; Peláez, Walter José; Pyrolysis of soybean waste: a route to biocarbon for pesticides capture; Universidad de Vassouras; Southern Journal of Sciences; 31; 36; 11-2023; 1-8
2764-5967
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sjofsciences.com/server/jornal/2023v2/CEBALLOS_pgs_01_08.pdf
info:eu-repo/semantics/altIdentifier/doi/ 10.48141/SBJCHEM.v31.n36.2023_CEBALLOS_pgs_01_08.pdf
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Universidad de Vassouras
publisher.none.fl_str_mv Universidad de Vassouras
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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