Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis

Autores
Babay, Paola Alejandra; Gettar, Raquel T.; Silva, María Fernanda; Thiele, Björn; Batistoni, Daniel Alberto
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Capillary electrophoresis based on non-aqueous solvent background electrolytes was employed, with single and multiple wavelength UV detection, to evaluate discrimination among oligomer components of mixtures of non-ionic, long chain nonylphenol ethoxylates (NPnEO, with n = number of ethoxy units) and their lipophilic degradation products. The tested organic solvents included acetonitrile, methanol, ethanol, 1- and 2-propanol, 1-butanol and tetrahydrofurane in the presence of sodium acetate. A rational variation of composition of background electrolyte solvent mixtures allowed to modify the mobility of electroosmotic flow and the type and degree of interactions between the ionic additive (sodium acetate) and the components of the analyte mixtures. The physicochemical properties of the solvents, such as dielectric constant, viscosity and electron donor–acceptor ability regarding the additive, were considered to improve the resolution of lipophilic compounds with less than three ethoxy groups and the discrimination attainable for longer chain oligomers. The studied methodologies also allowed discerning between surfactants of similar (nominal) ethoxy chain lengths. This was demonstrated by the different peak distribution patterns observed for NPnEO compounds with n = 7.5 and 10, respectively.
Fil: Babay, Paola Alejandra. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Gettar, Raquel T.. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Silva, María Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina
Fil: Thiele, Björn. Helmholtz Gemeinschaft. Forschungszentrum Jülich; Alemania
Fil: Batistoni, Daniel Alberto. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Materia
CATIONIC COMPLEXES
HETEROCONJUGATION
LIPOPHILIC METABOLITES
NON-AQUEOUS CAPILLARY ELECTROPHORESIS
NONYLPHENOL ETHOXYLATES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/147640
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/147640
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresisBabay, Paola AlejandraGettar, Raquel T.Silva, María FernandaThiele, BjörnBatistoni, Daniel AlbertoCATIONIC COMPLEXESHETEROCONJUGATIONLIPOPHILIC METABOLITESNON-AQUEOUS CAPILLARY ELECTROPHORESISNONYLPHENOL ETHOXYLATEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Capillary electrophoresis based on non-aqueous solvent background electrolytes was employed, with single and multiple wavelength UV detection, to evaluate discrimination among oligomer components of mixtures of non-ionic, long chain nonylphenol ethoxylates (NPnEO, with n = number of ethoxy units) and their lipophilic degradation products. The tested organic solvents included acetonitrile, methanol, ethanol, 1- and 2-propanol, 1-butanol and tetrahydrofurane in the presence of sodium acetate. A rational variation of composition of background electrolyte solvent mixtures allowed to modify the mobility of electroosmotic flow and the type and degree of interactions between the ionic additive (sodium acetate) and the components of the analyte mixtures. The physicochemical properties of the solvents, such as dielectric constant, viscosity and electron donor–acceptor ability regarding the additive, were considered to improve the resolution of lipophilic compounds with less than three ethoxy groups and the discrimination attainable for longer chain oligomers. The studied methodologies also allowed discerning between surfactants of similar (nominal) ethoxy chain lengths. This was demonstrated by the different peak distribution patterns observed for NPnEO compounds with n = 7.5 and 10, respectively.Fil: Babay, Paola Alejandra. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaFil: Gettar, Raquel T.. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaFil: Silva, María Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; ArgentinaFil: Thiele, Björn. Helmholtz Gemeinschaft. Forschungszentrum Jülich; AlemaniaFil: Batistoni, Daniel Alberto. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaElsevier Science2006-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/147640Babay, Paola Alejandra; Gettar, Raquel T.; Silva, María Fernanda; Thiele, Björn; Batistoni, Daniel Alberto; Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis; Elsevier Science; Journal of Chromatography - A; 1116; 1-2; 5-2006; 277-2850021-9673CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.chroma.2006.03.004info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0021967306005188info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:04:21Zoai:ri.conicet.gov.ar:11336/147640instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:04:21.551CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis
title Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis
spellingShingle Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis
Babay, Paola Alejandra
CATIONIC COMPLEXES
HETEROCONJUGATION
LIPOPHILIC METABOLITES
NON-AQUEOUS CAPILLARY ELECTROPHORESIS
NONYLPHENOL ETHOXYLATES
title_short Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis
title_full Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis
title_fullStr Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis
title_full_unstemmed Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis
title_sort Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis
dc.creator.none.fl_str_mv Babay, Paola Alejandra
Gettar, Raquel T.
Silva, María Fernanda
Thiele, Björn
Batistoni, Daniel Alberto
author Babay, Paola Alejandra
author_facet Babay, Paola Alejandra
Gettar, Raquel T.
Silva, María Fernanda
Thiele, Björn
Batistoni, Daniel Alberto
author_role author
author2 Gettar, Raquel T.
Silva, María Fernanda
Thiele, Björn
Batistoni, Daniel Alberto
author2_role author
author
author
author
dc.subject.none.fl_str_mv CATIONIC COMPLEXES
HETEROCONJUGATION
LIPOPHILIC METABOLITES
NON-AQUEOUS CAPILLARY ELECTROPHORESIS
NONYLPHENOL ETHOXYLATES
topic CATIONIC COMPLEXES
HETEROCONJUGATION
LIPOPHILIC METABOLITES
NON-AQUEOUS CAPILLARY ELECTROPHORESIS
NONYLPHENOL ETHOXYLATES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Capillary electrophoresis based on non-aqueous solvent background electrolytes was employed, with single and multiple wavelength UV detection, to evaluate discrimination among oligomer components of mixtures of non-ionic, long chain nonylphenol ethoxylates (NPnEO, with n = number of ethoxy units) and their lipophilic degradation products. The tested organic solvents included acetonitrile, methanol, ethanol, 1- and 2-propanol, 1-butanol and tetrahydrofurane in the presence of sodium acetate. A rational variation of composition of background electrolyte solvent mixtures allowed to modify the mobility of electroosmotic flow and the type and degree of interactions between the ionic additive (sodium acetate) and the components of the analyte mixtures. The physicochemical properties of the solvents, such as dielectric constant, viscosity and electron donor–acceptor ability regarding the additive, were considered to improve the resolution of lipophilic compounds with less than three ethoxy groups and the discrimination attainable for longer chain oligomers. The studied methodologies also allowed discerning between surfactants of similar (nominal) ethoxy chain lengths. This was demonstrated by the different peak distribution patterns observed for NPnEO compounds with n = 7.5 and 10, respectively.
Fil: Babay, Paola Alejandra. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Gettar, Raquel T.. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Silva, María Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina
Fil: Thiele, Björn. Helmholtz Gemeinschaft. Forschungszentrum Jülich; Alemania
Fil: Batistoni, Daniel Alberto. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
description Capillary electrophoresis based on non-aqueous solvent background electrolytes was employed, with single and multiple wavelength UV detection, to evaluate discrimination among oligomer components of mixtures of non-ionic, long chain nonylphenol ethoxylates (NPnEO, with n = number of ethoxy units) and their lipophilic degradation products. The tested organic solvents included acetonitrile, methanol, ethanol, 1- and 2-propanol, 1-butanol and tetrahydrofurane in the presence of sodium acetate. A rational variation of composition of background electrolyte solvent mixtures allowed to modify the mobility of electroosmotic flow and the type and degree of interactions between the ionic additive (sodium acetate) and the components of the analyte mixtures. The physicochemical properties of the solvents, such as dielectric constant, viscosity and electron donor–acceptor ability regarding the additive, were considered to improve the resolution of lipophilic compounds with less than three ethoxy groups and the discrimination attainable for longer chain oligomers. The studied methodologies also allowed discerning between surfactants of similar (nominal) ethoxy chain lengths. This was demonstrated by the different peak distribution patterns observed for NPnEO compounds with n = 7.5 and 10, respectively.
publishDate 2006
dc.date.none.fl_str_mv 2006-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/147640
Babay, Paola Alejandra; Gettar, Raquel T.; Silva, María Fernanda; Thiele, Björn; Batistoni, Daniel Alberto; Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis; Elsevier Science; Journal of Chromatography - A; 1116; 1-2; 5-2006; 277-285
0021-9673
CONICET Digital
CONICET
url http://hdl.handle.net/11336/147640
identifier_str_mv Babay, Paola Alejandra; Gettar, Raquel T.; Silva, María Fernanda; Thiele, Björn; Batistoni, Daniel Alberto; Separation of nonylphenol ethoxylates and nonylphenol by non-aqueous capillary electrophoresis; Elsevier Science; Journal of Chromatography - A; 1116; 1-2; 5-2006; 277-285
0021-9673
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chroma.2006.03.004
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0021967306005188
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083186927337472
score 13.22299

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