Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates

Autores
Arturi, Tatiana Sonia; Zaritzky, Noemi Elisabet; Contreras, Edgardo Martin
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Polyethoxylated nonylphenols (NPEOx) are widely used in various domestic and industrial applications. These commercial products are mixtures of oligomers that affect aquatic ecosystems, acting as endocrine disruptors. In the present work a simple high-performance liquid chromatography-ultraviolet method to quantify single oligomers of nonylphenol ethoxylates was developed. The following NPEOx commercial mixtures were analyzed: Igepal CO-520, Igepal CO-630, and Igepal CO-720. Obtained results demonstrate that the absorbance of each oligomer was not a function of the ethoxyl chain length. This result allowed the comparison between experimental molecular distribution functions of NPEOx mixtures with molecular distributions predicted by the Poisson's equation. In all cases, good agreement was obtained. The method was validated by quantifying NPEOx samples with different molecular size distributions.
Fil: Arturi, Tatiana Sonia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
Fil: Zaritzky, Noemi Elisabet. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Fil: Contreras, Edgardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Materia
Hplc-Uv
Nonylphenol Ethoxylates
Molecular Size Distribution
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2715
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/2715
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylatesArturi, Tatiana SoniaZaritzky, Noemi ElisabetContreras, Edgardo MartinHplc-UvNonylphenol EthoxylatesMolecular Size Distributionhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Polyethoxylated nonylphenols (NPEOx) are widely used in various domestic and industrial applications. These commercial products are mixtures of oligomers that affect aquatic ecosystems, acting as endocrine disruptors. In the present work a simple high-performance liquid chromatography-ultraviolet method to quantify single oligomers of nonylphenol ethoxylates was developed. The following NPEOx commercial mixtures were analyzed: Igepal CO-520, Igepal CO-630, and Igepal CO-720. Obtained results demonstrate that the absorbance of each oligomer was not a function of the ethoxyl chain length. This result allowed the comparison between experimental molecular distribution functions of NPEOx mixtures with molecular distributions predicted by the Poisson's equation. In all cases, good agreement was obtained. The method was validated by quantifying NPEOx samples with different molecular size distributions.Fil: Arturi, Tatiana Sonia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaFil: Zaritzky, Noemi Elisabet. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; ArgentinaFil: Contreras, Edgardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; ArgentinaAmerican Chemical Society2014-01-30info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2715Arturi, Tatiana Sonia; Zaritzky, Noemi Elisabet; Contreras, Edgardo Martin; Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates; American Chemical Society; Industrial & Engineering Chemical Research; 53; 4; 30-1-2014; 1327-13330888-5885enginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie403550ninfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie403550ninfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:14:09Zoai:ri.conicet.gov.ar:11336/2715instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:14:10.021CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates
title Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates
spellingShingle Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates
Arturi, Tatiana Sonia
Hplc-Uv
Nonylphenol Ethoxylates
Molecular Size Distribution
title_short Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates
title_full Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates
title_fullStr Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates
title_full_unstemmed Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates
title_sort Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates
dc.creator.none.fl_str_mv Arturi, Tatiana Sonia
Zaritzky, Noemi Elisabet
Contreras, Edgardo Martin
author Arturi, Tatiana Sonia
author_facet Arturi, Tatiana Sonia
Zaritzky, Noemi Elisabet
Contreras, Edgardo Martin
author_role author
author2 Zaritzky, Noemi Elisabet
Contreras, Edgardo Martin
author2_role author
author
dc.subject.none.fl_str_mv Hplc-Uv
Nonylphenol Ethoxylates
Molecular Size Distribution
topic Hplc-Uv
Nonylphenol Ethoxylates
Molecular Size Distribution
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Polyethoxylated nonylphenols (NPEOx) are widely used in various domestic and industrial applications. These commercial products are mixtures of oligomers that affect aquatic ecosystems, acting as endocrine disruptors. In the present work a simple high-performance liquid chromatography-ultraviolet method to quantify single oligomers of nonylphenol ethoxylates was developed. The following NPEOx commercial mixtures were analyzed: Igepal CO-520, Igepal CO-630, and Igepal CO-720. Obtained results demonstrate that the absorbance of each oligomer was not a function of the ethoxyl chain length. This result allowed the comparison between experimental molecular distribution functions of NPEOx mixtures with molecular distributions predicted by the Poisson's equation. In all cases, good agreement was obtained. The method was validated by quantifying NPEOx samples with different molecular size distributions.
Fil: Arturi, Tatiana Sonia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
Fil: Zaritzky, Noemi Elisabet. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Fil: Contreras, Edgardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
description Polyethoxylated nonylphenols (NPEOx) are widely used in various domestic and industrial applications. These commercial products are mixtures of oligomers that affect aquatic ecosystems, acting as endocrine disruptors. In the present work a simple high-performance liquid chromatography-ultraviolet method to quantify single oligomers of nonylphenol ethoxylates was developed. The following NPEOx commercial mixtures were analyzed: Igepal CO-520, Igepal CO-630, and Igepal CO-720. Obtained results demonstrate that the absorbance of each oligomer was not a function of the ethoxyl chain length. This result allowed the comparison between experimental molecular distribution functions of NPEOx mixtures with molecular distributions predicted by the Poisson's equation. In all cases, good agreement was obtained. The method was validated by quantifying NPEOx samples with different molecular size distributions.
publishDate 2014
dc.date.none.fl_str_mv 2014-01-30
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2715
Arturi, Tatiana Sonia; Zaritzky, Noemi Elisabet; Contreras, Edgardo Martin; Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates; American Chemical Society; Industrial & Engineering Chemical Research; 53; 4; 30-1-2014; 1327-1333
0888-5885
url http://hdl.handle.net/11336/2715
identifier_str_mv Arturi, Tatiana Sonia; Zaritzky, Noemi Elisabet; Contreras, Edgardo Martin; Simple high-performance liquid chromatography-ultraviolet method to quantify the molecular size distribution of nonylphenol ethoxylates; American Chemical Society; Industrial & Engineering Chemical Research; 53; 4; 30-1-2014; 1327-1333
0888-5885
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie403550n
info:eu-repo/semantics/altIdentifier/doi/10.1021/ie403550n
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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