Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells
- Autores
- Favilla, Pablo Cesar; Acosta, Jorge Javier; Schvezov, Carlos Enrique; Sercovich, J. R.; Collet Lacoste, J. R.
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The aim of this work is to present the results of the synthesis of Pt nanoparticles using the modified polyol method, using carbon black powder Vulcan XC-72R as a support. Two different techniques were used to synthesize the catalysts: (a) fixing the initial concentration of the precursor (2 mM in H2PtCl6) while adding the required amount of support to obtain different nominal loads of platinum; (b) changing the initial concentration of the precursor to obtain altogether 10 wt% nominal load of platinum. Catalysts were characterized using X-ray diffraction, transmission electron microscopy and cyclic voltammetry. The particles obtained ranged in sizes between 2.2 and 6.2 nm. These sizes were controlled by the initial concentration of the precursor. It has been found that the concentration of nanoparticles formed during synthesis was the same regardless of (a) the initial concentration of the precursor and (b) the amount of carbon support. In order to explain experimental results a new and simple statistical and geometrical treatment is used.
Fil: Favilla, Pablo Cesar. Universidad Nacional de Misiones; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Acosta, Jorge Javier. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina
Fil: Schvezov, Carlos Enrique. Universidad Nacional de Misiones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Sercovich, J. R.. H2-TEC; Argentina
Fil: Collet Lacoste, J. R.. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina - Materia
-
Catalyst support
Particle formation
Electrochemistry
Nanostructure - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/9094
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Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cellsFavilla, Pablo CesarAcosta, Jorge JavierSchvezov, Carlos EnriqueSercovich, J. R.Collet Lacoste, J. R.Catalyst supportParticle formationElectrochemistryNanostructurehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The aim of this work is to present the results of the synthesis of Pt nanoparticles using the modified polyol method, using carbon black powder Vulcan XC-72R as a support. Two different techniques were used to synthesize the catalysts: (a) fixing the initial concentration of the precursor (2 mM in H2PtCl6) while adding the required amount of support to obtain different nominal loads of platinum; (b) changing the initial concentration of the precursor to obtain altogether 10 wt% nominal load of platinum. Catalysts were characterized using X-ray diffraction, transmission electron microscopy and cyclic voltammetry. The particles obtained ranged in sizes between 2.2 and 6.2 nm. These sizes were controlled by the initial concentration of the precursor. It has been found that the concentration of nanoparticles formed during synthesis was the same regardless of (a) the initial concentration of the precursor and (b) the amount of carbon support. In order to explain experimental results a new and simple statistical and geometrical treatment is used.Fil: Favilla, Pablo Cesar. Universidad Nacional de Misiones; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Acosta, Jorge Javier. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; ArgentinaFil: Schvezov, Carlos Enrique. Universidad Nacional de Misiones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Sercovich, J. R.. H2-TEC; ArgentinaFil: Collet Lacoste, J. R.. Comisión Nacional de Energía Atómica, Buenos Aires; ArgentinaElsevier2013-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/9094Favilla, Pablo Cesar; Acosta, Jorge Javier; Schvezov, Carlos Enrique; Sercovich, J. R.; Collet Lacoste, J. R.; Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells; Elsevier; Chemical Engineering Science; 101; 5-2013; 27-340009-2509enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2013.05.067info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0009250913004089info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:58:26Zoai:ri.conicet.gov.ar:11336/9094instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:58:26.43CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells |
title |
Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells |
spellingShingle |
Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells Favilla, Pablo Cesar Catalyst support Particle formation Electrochemistry Nanostructure |
title_short |
Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells |
title_full |
Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells |
title_fullStr |
Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells |
title_full_unstemmed |
Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells |
title_sort |
Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells |
dc.creator.none.fl_str_mv |
Favilla, Pablo Cesar Acosta, Jorge Javier Schvezov, Carlos Enrique Sercovich, J. R. Collet Lacoste, J. R. |
author |
Favilla, Pablo Cesar |
author_facet |
Favilla, Pablo Cesar Acosta, Jorge Javier Schvezov, Carlos Enrique Sercovich, J. R. Collet Lacoste, J. R. |
author_role |
author |
author2 |
Acosta, Jorge Javier Schvezov, Carlos Enrique Sercovich, J. R. Collet Lacoste, J. R. |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Catalyst support Particle formation Electrochemistry Nanostructure |
topic |
Catalyst support Particle formation Electrochemistry Nanostructure |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The aim of this work is to present the results of the synthesis of Pt nanoparticles using the modified polyol method, using carbon black powder Vulcan XC-72R as a support. Two different techniques were used to synthesize the catalysts: (a) fixing the initial concentration of the precursor (2 mM in H2PtCl6) while adding the required amount of support to obtain different nominal loads of platinum; (b) changing the initial concentration of the precursor to obtain altogether 10 wt% nominal load of platinum. Catalysts were characterized using X-ray diffraction, transmission electron microscopy and cyclic voltammetry. The particles obtained ranged in sizes between 2.2 and 6.2 nm. These sizes were controlled by the initial concentration of the precursor. It has been found that the concentration of nanoparticles formed during synthesis was the same regardless of (a) the initial concentration of the precursor and (b) the amount of carbon support. In order to explain experimental results a new and simple statistical and geometrical treatment is used. Fil: Favilla, Pablo Cesar. Universidad Nacional de Misiones; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Acosta, Jorge Javier. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina Fil: Schvezov, Carlos Enrique. Universidad Nacional de Misiones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Sercovich, J. R.. H2-TEC; Argentina Fil: Collet Lacoste, J. R.. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina |
description |
The aim of this work is to present the results of the synthesis of Pt nanoparticles using the modified polyol method, using carbon black powder Vulcan XC-72R as a support. Two different techniques were used to synthesize the catalysts: (a) fixing the initial concentration of the precursor (2 mM in H2PtCl6) while adding the required amount of support to obtain different nominal loads of platinum; (b) changing the initial concentration of the precursor to obtain altogether 10 wt% nominal load of platinum. Catalysts were characterized using X-ray diffraction, transmission electron microscopy and cyclic voltammetry. The particles obtained ranged in sizes between 2.2 and 6.2 nm. These sizes were controlled by the initial concentration of the precursor. It has been found that the concentration of nanoparticles formed during synthesis was the same regardless of (a) the initial concentration of the precursor and (b) the amount of carbon support. In order to explain experimental results a new and simple statistical and geometrical treatment is used. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/9094 Favilla, Pablo Cesar; Acosta, Jorge Javier; Schvezov, Carlos Enrique; Sercovich, J. R.; Collet Lacoste, J. R.; Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells; Elsevier; Chemical Engineering Science; 101; 5-2013; 27-34 0009-2509 |
url |
http://hdl.handle.net/11336/9094 |
identifier_str_mv |
Favilla, Pablo Cesar; Acosta, Jorge Javier; Schvezov, Carlos Enrique; Sercovich, J. R.; Collet Lacoste, J. R.; Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells; Elsevier; Chemical Engineering Science; 101; 5-2013; 27-34 0009-2509 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2013.05.067 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0009250913004089 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613741211025408 |
score |
13.070432 |