Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells

Autores
Favilla, Pablo Cesar; Acosta, Jorge Javier; Schvezov, Carlos Enrique; Sercovich, J. R.; Collet Lacoste, J. R.
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this work is to present the results of the synthesis of Pt nanoparticles using the modified polyol method, using carbon black powder Vulcan XC-72R as a support. Two different techniques were used to synthesize the catalysts: (a) fixing the initial concentration of the precursor (2 mM in H2PtCl6) while adding the required amount of support to obtain different nominal loads of platinum; (b) changing the initial concentration of the precursor to obtain altogether 10 wt% nominal load of platinum. Catalysts were characterized using X-ray diffraction, transmission electron microscopy and cyclic voltammetry. The particles obtained ranged in sizes between 2.2 and 6.2 nm. These sizes were controlled by the initial concentration of the precursor. It has been found that the concentration of nanoparticles formed during synthesis was the same regardless of (a) the initial concentration of the precursor and (b) the amount of carbon support. In order to explain experimental results a new and simple statistical and geometrical treatment is used.
Fil: Favilla, Pablo Cesar. Universidad Nacional de Misiones; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Acosta, Jorge Javier. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina
Fil: Schvezov, Carlos Enrique. Universidad Nacional de Misiones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Sercovich, J. R.. H2-TEC; Argentina
Fil: Collet Lacoste, J. R.. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina
Materia
Catalyst support
Particle formation
Electrochemistry
Nanostructure
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/9094
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/9094
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cellsFavilla, Pablo CesarAcosta, Jorge JavierSchvezov, Carlos EnriqueSercovich, J. R.Collet Lacoste, J. R.Catalyst supportParticle formationElectrochemistryNanostructurehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The aim of this work is to present the results of the synthesis of Pt nanoparticles using the modified polyol method, using carbon black powder Vulcan XC-72R as a support. Two different techniques were used to synthesize the catalysts: (a) fixing the initial concentration of the precursor (2 mM in H2PtCl6) while adding the required amount of support to obtain different nominal loads of platinum; (b) changing the initial concentration of the precursor to obtain altogether 10 wt% nominal load of platinum. Catalysts were characterized using X-ray diffraction, transmission electron microscopy and cyclic voltammetry. The particles obtained ranged in sizes between 2.2 and 6.2 nm. These sizes were controlled by the initial concentration of the precursor. It has been found that the concentration of nanoparticles formed during synthesis was the same regardless of (a) the initial concentration of the precursor and (b) the amount of carbon support. In order to explain experimental results a new and simple statistical and geometrical treatment is used.Fil: Favilla, Pablo Cesar. Universidad Nacional de Misiones; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Acosta, Jorge Javier. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; ArgentinaFil: Schvezov, Carlos Enrique. Universidad Nacional de Misiones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Sercovich, J. R.. H2-TEC; ArgentinaFil: Collet Lacoste, J. R.. Comisión Nacional de Energía Atómica, Buenos Aires; ArgentinaElsevier2013-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/9094Favilla, Pablo Cesar; Acosta, Jorge Javier; Schvezov, Carlos Enrique; Sercovich, J. R.; Collet Lacoste, J. R.; Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells; Elsevier; Chemical Engineering Science; 101; 5-2013; 27-340009-2509enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2013.05.067info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0009250913004089info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:27:44Zoai:ri.conicet.gov.ar:11336/9094instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:27:44.403CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells
title Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells
spellingShingle Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells
Favilla, Pablo Cesar
Catalyst support
Particle formation
Electrochemistry
Nanostructure
title_short Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells
title_full Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells
title_fullStr Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells
title_full_unstemmed Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells
title_sort Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells
dc.creator.none.fl_str_mv Favilla, Pablo Cesar
Acosta, Jorge Javier
Schvezov, Carlos Enrique
Sercovich, J. R.
Collet Lacoste, J. R.
author Favilla, Pablo Cesar
author_facet Favilla, Pablo Cesar
Acosta, Jorge Javier
Schvezov, Carlos Enrique
Sercovich, J. R.
Collet Lacoste, J. R.
author_role author
author2 Acosta, Jorge Javier
Schvezov, Carlos Enrique
Sercovich, J. R.
Collet Lacoste, J. R.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Catalyst support
Particle formation
Electrochemistry
Nanostructure
topic Catalyst support
Particle formation
Electrochemistry
Nanostructure
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The aim of this work is to present the results of the synthesis of Pt nanoparticles using the modified polyol method, using carbon black powder Vulcan XC-72R as a support. Two different techniques were used to synthesize the catalysts: (a) fixing the initial concentration of the precursor (2 mM in H2PtCl6) while adding the required amount of support to obtain different nominal loads of platinum; (b) changing the initial concentration of the precursor to obtain altogether 10 wt% nominal load of platinum. Catalysts were characterized using X-ray diffraction, transmission electron microscopy and cyclic voltammetry. The particles obtained ranged in sizes between 2.2 and 6.2 nm. These sizes were controlled by the initial concentration of the precursor. It has been found that the concentration of nanoparticles formed during synthesis was the same regardless of (a) the initial concentration of the precursor and (b) the amount of carbon support. In order to explain experimental results a new and simple statistical and geometrical treatment is used.
Fil: Favilla, Pablo Cesar. Universidad Nacional de Misiones; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Acosta, Jorge Javier. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina
Fil: Schvezov, Carlos Enrique. Universidad Nacional de Misiones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Sercovich, J. R.. H2-TEC; Argentina
Fil: Collet Lacoste, J. R.. Comisión Nacional de Energía Atómica, Buenos Aires; Argentina
description The aim of this work is to present the results of the synthesis of Pt nanoparticles using the modified polyol method, using carbon black powder Vulcan XC-72R as a support. Two different techniques were used to synthesize the catalysts: (a) fixing the initial concentration of the precursor (2 mM in H2PtCl6) while adding the required amount of support to obtain different nominal loads of platinum; (b) changing the initial concentration of the precursor to obtain altogether 10 wt% nominal load of platinum. Catalysts were characterized using X-ray diffraction, transmission electron microscopy and cyclic voltammetry. The particles obtained ranged in sizes between 2.2 and 6.2 nm. These sizes were controlled by the initial concentration of the precursor. It has been found that the concentration of nanoparticles formed during synthesis was the same regardless of (a) the initial concentration of the precursor and (b) the amount of carbon support. In order to explain experimental results a new and simple statistical and geometrical treatment is used.
publishDate 2013
dc.date.none.fl_str_mv 2013-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/9094
Favilla, Pablo Cesar; Acosta, Jorge Javier; Schvezov, Carlos Enrique; Sercovich, J. R.; Collet Lacoste, J. R.; Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells; Elsevier; Chemical Engineering Science; 101; 5-2013; 27-34
0009-2509
url http://hdl.handle.net/11336/9094
identifier_str_mv Favilla, Pablo Cesar; Acosta, Jorge Javier; Schvezov, Carlos Enrique; Sercovich, J. R.; Collet Lacoste, J. R.; Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells; Elsevier; Chemical Engineering Science; 101; 5-2013; 27-34
0009-2509
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2013.05.067
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0009250913004089
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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